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2-alkylation (17) 17
indoles (11) 11
chemistry, multidisciplinary (9) 9
alkylation (8) 8
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-goniomitine (1) 1
-kopsihainanine (1) 1
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JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, ISSN 0037-9980, 06/2019, Volume 77, Issue 6, pp. 608 - 609
Catellani reaction enables multi-functionalization of aromatic rings. Originally, Catellani reaction starts from oxidative addition of aryl halide to... 
2-ALKYLATION | CHEMISTRY, ORGANIC | INDOLES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2013, Volume 135, Issue 2, pp. 616 - 619
An unexpected C–H activation/C–C cross-coupling reaction has been found to occur between pyridine N-oxides and general nonactivated secondary and even tertiary... 
FUNCTIONALIZATION | HALIDES | DIRECT ARYLATION | SUZUKI CROSS-COUPLINGS | ARYL BOND FORMATION | LIGANDS | 2-ALKYLATION | CHLORIDES | CHEMISTRY, MULTIDISCIPLINARY | HECK-TYPE REACTIONS | DISCOVERY | Thermal properties | Spin coupling | Pyridine | Analysis | Palladium | Catalysis | Chemical properties
Journal Article
Nature, ISSN 0028-0836, 03/2015, Volume 519, Issue 7543, pp. 334 - 338
Journal Article
Organic Letters, ISSN 1523-7060, 02/2016, Volume 18, Issue 4, pp. 852 - 855
Pyrrole has been employed for the first time as a directing group in the Pd­(II)-catalyzed ortho-functionalization of C­(sp2)–H bonds. A variety of substituted... 
HALIDES | C-H ALKYLATION | SUBSTITUTION | BENZAMIDES | ARENES | 2-ALKYLATION | PALLADIUM-CATALYZED ARYLATION | CHEMISTRY, ORGANIC | BOND ACTIVATION | INDOLES | ALKALOIDS
Journal Article
Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 2, pp. 345 - 348
A palladium-catalyzed, norbornene-mediated ortho- and ipso-C–N bond-forming Catellani reaction is reported. This reaction proceeds through a sequential... 
DOMINO REACTION | FUNCTIONALIZATION | REGIOSPECIFIC SYNTHESIS | ANILINES | 2-ALKYLATION | CHEMISTRY, ORGANIC | CASCADE | ARYL IODIDES | PD/NORBORNENE | H ARYLATION | INDOLES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2017, Volume 56, Issue 28, pp. 8183 - 8186
Palladium(II)‐catalyzed meta‐C−H arylation and alkylation of benzylsulfonamide using 2‐carbomethoxynorbornene (NBE‐CO2Me) as a transient mediator are realized... 
alkylation | palladium | sulfur | C−H activation | synthetic methods | AROMATIC FUNCTIONALIZATION | ACTIVATION | ARENES | PD/NORBORNENE | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | OLEFINATION | NORBORNENE | 2-ALKYLATION | LIGAND | SELECTIVITY | BORYLATION | Palladium catalysts | Alkaloids | Palladium | Sulfonamides | Sodium | Catalysts | Styrenes | Esters | Ligands | Sulfonates | Group dynamics | Alkylation
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2014, Volume 356, Issue 5, pp. 929 - 933
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2019, Volume 2019, Issue 31-32, pp. 5156 - 5160
C2 allylation of indole derivatives is a challenging but important transformation given the biological relevance of the products. Herein we report a selective... 
Heterocycles | Boron reagents | Synthetic methods | Indoles | Physical and Theoretical Chemistry | Allylation | Organic Chemistry | ARENES | TRYPROSTATIN | CHEMISTRY, ORGANIC | H ALLYLATION | FUNCTIONALIZATION | ALCOHOLS | 2-ALKYLATION | ACETATES | ALKALOIDS | Communications | Communication
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 40, pp. 11813 - 11816
In the presence of a catalyst system consisting of Pd(OAc)2, PCy3, and Zn(OAc)2, the reaction of alkynyl aryl ethers with bicycloalkenes, α,ß‐unsaturated... 
CH activation | palladium | annulation | alkynes | CC coupling | C-C coupling | C-H activation | MECHANISM | ALKYLATION | ARYLATION | ARYL ETHERS | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | 2-ALKYLATION | DIBENZOXANTHENE | PALLADIUM-CATALYZED CYCLOADDITION | DERIVATIVES | Palladium catalysts | Usage | Palladium | Oxidoreductases | Hydrogen | Acetates | Hydrogen storage | Catalysts | Aromatic compounds | Dehydrogenation | Cleavage | Activation | Ethers | Bonding
Journal Article
by Yuan, YZ and Song, S and Jiao, N
ACTA CHIMICA SINICA, ISSN 0567-7351, 12/2015, Volume 73, Issue 12, pp. 1231 - 1234
In recent years, remarkable progress has been achieved in Pd-catalyzed meta-C(sp(2))-H bond activation with directing groups. Based on remote activation... 
Catellani reaction | norbornene | ARYLATION | C-H OLEFINATION | remote direction | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | FUNCTIONALIZATION | AMINATION | U-SHAPED TEMPLATE | 2-ALKYLATION | palladium | meta-C-H bond activation | DERIVATIVES
Journal Article
Catalysts, ISSN 2073-4344, 06/2016, Volume 6, Issue 6, p. 89
Rh(III)-catalyzed regioselective alkylation of indoles with diazo compounds as a highly efficient and atom-economic protocol for the synthesis of alkyl... 
Diazo compound | Indoles | Rhodium | C–H alkylation | indoles | ACTIVATION | diazo compound | CATALYZED REACTIONS | ACIDS | ARENES | BONDS | 2-ALKYLATION | CHEMISTRY, PHYSICAL | C2-SELECTIVE CARBENOID FUNCTIONALIZATION | rhodium | C-H alkylation
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 12/2014, Volume 356, Issue 18, pp. 3871 - 3880
The Brønsted acid‐mediated alkylation and alkenylation of indoles were efficiently achieved by means of 3‐(dimethylamino)acrylonitrile. Regulating the acidity... 
alkenylation | alkylation | 3‐(dimethylamino)acrylonitrile | indoles | Brønsted acids | Indoles | Alkenylation | 3-(dimethylamino)acrylonitrile | Alkylation | PRACTICAL SYNTHESIS | CHEMISTRY, ORGANIC | ALDEHYDES | C-H ACTIVATION | FUNCTIONALIZATION | ALKENES | OLEFINATION | 2-ALKYLATION | C2-ALKENYLATION | BOND ACTIVATION | CHEMISTRY, APPLIED | Bronsted acids | DERIVATIVES
Journal Article
Journal of Flow Chemistry, ISSN 2062-249X, 06/2016, Volume 6, Issue 2, pp. 117 - 122
A novel method for C-H functionalization of heteroaromatic rings by using continuous-flow reactors is reported. Direct alkylation reactions were investigated... 
Nickel catalysis | C-H activation | Catalytic alkylation | Flow chemistry | PALLADIUM | METHANOL | ARYLATION | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | nickel catalysis | catalytic alkylation | ALCOHOLS | 2-ALKYLATION | ATOM-ECONOMY | flow chemistry
Journal Article
ChemistrySelect, ISSN 2365-6549, 09/2018, Volume 3, Issue 36, pp. 10164 - 10168
The C−H functionalization of heterocycles has attracted extensive attention recently due to the ubiquity of substituted heterocycles in natural products,... 
C−H functionalization | pyridine | alkylation | indole | Catellani reaction | Alkenylation | C-H functionalization | PD/NORBORNENE | CHEMISTRY, MULTIDISCIPLINARY | MEDICINAL CHEMISTRY | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | HETEROCYCLES | 2-ALKYLATION | FLUORINE | ARYL IODIDES | ORTHO-ARYLATION | HECK REACTION
Journal Article
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