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2-rhodaoxetanes (7) 7
oxidation (7) 7
chemistry, multidisciplinary (4) 4
reactivity (4) 4
rhodium (4) 4
chemistry, inorganic & nuclear (3) 3
metallacycles (3) 3
activation (2) 2
complexes (2) 2
iridium (2) 2
n ligands (2) 2
o-o activation (2) 2
olefin (2) 2
olefin epoxidation (2) 2
oxygenation (2) 2
alkene (1) 1
alkene ligands (1) 1
alkenes (1) 1
alkenes - chemistry (1) 1
alkynes (1) 1
atoms li (1) 1
azarhodacyclobutanes (1) 1
aziridines (1) 1
bond activation (1) 1
bonds (1) 1
carbon-dioxide (1) 1
catalysis (1) 1
chemistry, organic (1) 1
crystal-structure (1) 1
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density functional calculations (1) 1
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dioxygenation (1) 1
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formylmethyl complexes (1) 1
gaussian-basis sets (1) 1
gold (1) 1
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homogeneous catalysis (1) 1
hydroperoxo complexes (1) 1
isomers (1) 1
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n-ligands (1) 1
nitrene precursors (1) 1
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olefins (1) 1
organometallic compounds - chemical synthesis (1) 1
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oxygen (1) 1
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Angewandte Chemie International Edition, ISSN 1433-7851, 04/2012, Volume 51, Issue 15, pp. 3634 - 3637
AmAZAing metallacycles: Azarhodacyclobutane was prepared by oxidation of RhI–olefin complex 1 (see Scheme; Ts=p‐toluenesulfonyl). Both isomers 2 a and 2 b were... 
azarhodacyclobutanes | reactive intermediates | nitrene precursors | metallacycles | rhodium | ACTIVATION | COMPLEXES | 2-RHODAOXETANES | BONDS | REACTIVITY | AZIRIDINES | CHEMISTRY, MULTIDISCIPLINARY | Oxidation | NMR spectroscopy | Mass spectrometry | Isomers
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2005, Volume 44, Issue 42, pp. 6892 - 6895
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2005, Volume 44, Issue 21, pp. 3267 - 3271
Ready cleavage of dioxygen and its selective insertion into Rh–alkene bonds occurs in the presence of [{Rh(PhN3Ph)(C8H12)}n] (n=1 and 2). The structure of the... 
oxidation | N ligands | OO activation | metallacycles | rhodium | O-O activation | Oxidation | Rhodium | Metallacycles | CATALYSIS | SELECTIVE OXIDATION | O-2 | 2-RHODAOXETANES | REACTIVITY | OLEFIN | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organometallics, ISSN 0276-7333, 12/2009, Volume 28, Issue 24, pp. 6935 - 6943
The influence of ancillary ligands, Lewis acids, carbon substituents, and oxidants on the stability and reactivity of 2-platinaoxetanes was investigated... 
OXIDATION | ALKENE | ACTIVATION | MONONUCLEAR | PLATINUM(II) | OXO | 2-RHODAOXETANES | CHEMISTRY, ORGANIC | REDUCTIVE ELIMINATION | PHOSPHINE COMPLEXES | OLEFIN | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 03/2003, Volume 2003, Issue 6, pp. 1072 - 1087
The ethene complexes [MI(CH2CH2)]+ (M = Ir, Rh) can be oxygenated by molecular oxygen or air in the solid state, to form isolable unsubstituted... 
Formylmethyl complexes | N ligands | Rhodium | Metallacycles | Oxygenations | OXIDATION | OLEFIN EPOXIDATION | MECHANISM | MOLECULAR-STRUCTURE | COMPLEXES | formylmethyl complexes | oxygenations | CHEMISTRY, INORGANIC & NUCLEAR | OXYGEN | 2-RHODAOXETANES | DIOXYGENATION | BOND ACTIVATION | CARBON-DIOXIDE | metallacycles | rhodium
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 2004, Volume 2004, Issue 11, pp. 2385 - 2391
A DFT study of the oxidation of (tpa)M-I(C2H4)(+) and (dpa-R)M-I(cod)(+) complexes (M = Rh, Ir) by H2O2 indicates that the reaction starts with heterolytic... 
ENERGY | OLEFIN EPOXIDATION | oxidation | REACTIVITY | oxygenation | CHEMISTRY, INORGANIC & NUCLEAR | iridium | density functional calculations | DENSITY-FUNCTIONAL MODEL | ATOMS LI | TRANSITION-METAL | 2-RHODAOXETANES | HYDROPEROXO COMPLEXES | GAUSSIAN-BASIS SETS | rhodium | PEROXIDE
Journal Article
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