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Accounts of Chemical Research, ISSN 0001-4842, 08/2017, Volume 50, Issue 8, pp. 1997 - 2006
Since the pioneering work by Thiele and Chichibabin, who synthesized the first diradicals bridged by phenylene and biphenylene groups in 1904 and 1907,... 
SPIN STATES | RADICAL-CATION | 1,3,2-DITHIAZOLYL RADICALS | PHASE-TRANSITION | WEAKLY COORDINATING ANIONS | 3-ELECTRON SIGMA-BOND | CRYSTAL-STRUCTURES | MAGNETIC BISTABILITY | CHEMISTRY, MULTIDISCIPLINARY | EXCITED TRIPLET-STATE | SINGLET
Journal Article
Chemical science, ISSN 2041-6520, 01/2015, Volume 6, Issue 1, pp. 497 - 504
One-electron oxidation of two series of diaryldichalcogenides (C F E) ( ) and (2,6-Mes C H E) ( ) was studied (E = S, Se, Te). The reaction of and with AsF and... 
Journal Article
Chemical Communications, ISSN 1359-7345, 05/2015, Volume 51, Issue 40, pp. 8410 - 8413
A highly air-sensitive seventeen-electron half-sandwich radical, [(C6Me6)Cr(CO)(3)](+), which has been long sought over 40 years, was isolated and structurally... 
OXIDATION | ELECTROCHEMISTRY | DICATION | METAL-CENTERED RADICALS | LIGAND SUBSTITUTION | COMPLEXES | WEAKLY COORDINATING ANIONS | 3-ELECTRON SIGMA-BOND | DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | CATIONS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 19, pp. 6172 - 6175
Solid-state NMR spectra of new P–Se heterocycles based on peri-substituted naphthalene motifs show the presence of unusual J couplings between Se and P. These... 
NMR-SPECTROSCOPY | PHOSPHINES | 3-ELECTRON SIGMA-BOND | NAPHTHALENE | DFT CALCULATIONS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE | MAS NMR | INSIGHTS | Density functionals | Nuclear magnetic resonance spectroscopy | Usage | Chemical properties | Heterocyclic compounds
Journal Article
Chemical Science, ISSN 2041-6520, 01/2015, Volume 6, Issue 1, pp. 497 - 504
One-electron oxidation of two series of diaryldichalcogenides (C6F5E)(2) (13a-c) and (2,6-Mes(2)C(6)H(3)E)(2) (16a-c) was studied (E = S, Se, Te). The reaction... 
CRYSTAL-STRUCTURE | 3-ELECTRON SIGMA-BOND | SPECTROSCOPIC CHARACTERIZATION | CHEMISTRY | DIPHENYL DISULFIDE | THIANTHRENE | MAIN-GROUP ELEMENTS | PENTASIL ZEOLITE | TRIVALENT CARBON | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE | Diffraction | Mathematical analysis | Electronics | Density functional theory | Cleavage | Cations | Bonding | Radicals
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2016, Volume 55, Issue 3, pp. 1008 - 1010
The facile synthesis of a new highly aliphatic solvent-soluble Li+ salt of the perhalogenated weakly coordinating anion [Al­(OC­(CCl3)­(CF3)2)4]− and its... 
DICATION | STARTING MATERIALS | CRYSTAL-STRUCTURE | COMPLEXES | 3-ELECTRON SIGMA-BOND | RADICAL CATIONS | CHEMISTRY | LIGAND | SUPERWEAK ANIONS | SPIN-DENSITY DISTRIBUTIONS | CHEMISTRY, INORGANIC & NUCLEAR | Aluminum compounds | Usage | Chemical properties | Chemical synthesis | Lithium compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2015, Volume 54, Issue 31, pp. 9084 - 9087
Metalloradical species [Co2Fv(CO)4].+ (1.+, Fv=fulvalenediyl) and [Co2Cp2(CO)4].+ (2.+, Cp=η5‐C5H5), formed by one‐electron oxidations of piano‐stool cobalt... 
metalloradicals | metal–metal bonds | cations | X‐ray diffraction | unsupported bonds | metal-metal bonds | X-ray diffraction | OXIDATION | HIGHLY POLAR METAL | STABILIZATION | COMPOUND | RADICAL CATIONS | HETERODIMETALLIC COMPLEXES | CENTERS | CHEMISTRY, MULTIDISCIPLINARY | LIGANDS | DIMER | 3-ELECTRON SIGMA-BOND | Solid state | Anions | Accessibility | Crystals | Cations | Metal carbonyls | Bonding | Radicals
Journal Article
International Journal of Quantum Chemistry, ISSN 0020-7608, 07/2016, Volume 116, Issue 14, pp. 1090 - 1096
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 2015, Volume 137, Issue 15, pp. 4993 - 5011
The diamagnetic compounds Cp'2Ni2E2 (1: E = S, 2: E = Se, 3: E = Te; Cp'\n= 1,2,3,4,-tetraisopropylcyclopentadienyl), first reported by Sitzmann\nand... 
RAY-ABSORPTION SPECTROSCOPY | TRANSITION-METAL-COMPLEXES | DISULFIDE RADICAL-ANIONS | 3-ELECTRON SIGMA-BOND | SULFIDE NANOCRYSTALS | CRYSTAL-STRUCTURES | ORGANIC SULFIDES | DENSITY-FUNCTIONAL THEORY | TRANSFER CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | AQUEOUS-SOLUTION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/1992, Volume 114, Issue 18, pp. 7107 - 7115
N,N'-Polymethylene-syn-1,6:8,13-diimino[14]annulenes, 1-7, in which the number, m, of CH2 groups varies from 1 to 7, and... 
OXIDATION | SPACE | DICATION | ELECTRON-SPIN-RESONANCE | ANNULENES | RING BICYCLIC COMPOUNDS | 3-ELECTRON SIGMA-BOND | CHEMISTRY | SYN-1,6-8,13-DIIMINO ANNULENES | MOLECULES
Journal Article
The Journal of Physical Chemistry, ISSN 0022-3654, 04/1993, Volume 97, Issue 17, pp. 4373 - 4380
The IR spectra of six C2h isotopomers of the butadiene cation radical were measured in argon matrices. Forty-three of the 72 IR active fundamentals were... 
GLASSY MATRIX | MASS-SELECTED IONS | TRIPLET-STATE | RESOLVED RESONANCE RAMAN | 3-ELECTRON SIGMA-BOND | CHEMISTRY, PHYSICAL | INFRARED-SPECTROSCOPY | K EI CHEMISTRY, PHYSICAL | VIBRATIONAL-SPECTRA | POLYATOMIC TRANSIENT MOLECULES | ELECTRONIC-ENERGY LEVELS | EXCITED-STATES
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 11/1997, Volume 101, Issue 48, pp. 8979 - 8986
The elementary steps of an electron photodetachment triggered by the UV excitation of pure liquid dimethyl sulfide, (CH3)2S, have been investigated by... 
DIMETHYL SULFIDE | 2-PHOTON DISSOCIATION | KINETICS | AB-INITIO | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | ULTRAVIOLET-ABSORPTION SPECTRA | ATOMS | EXCESS ELECTRON | 3-ELECTRON BOND | PHOTOELECTRON-SPECTROSCOPY
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 01/2016, Volume 49, Issue 1, pp. 27 - 34
First proposed in a classic Linus Pauling paper, the two-center/three-electron (2c/3e) σ half-bond challenges the extremes of what may or may not be considered... 
QUANDARY | RESONANCE | LIGANDS | COMPLEXES | RADICAL CATIONS | DIMERS | 3-ELECTRON BOND | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE | Computational chemistry | Usage | Transition metal compounds | Electron paramagnetic resonance spectroscopy | Chemical bonds | Oxidation-reduction reaction | Research | Chemical properties
Journal Article
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