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Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 85, pp. 12045 - 12048
Oxidation of distorted square-planar perfluoropinacolate Co compound [Co-II(pin(F))(2)](2-), 1, to [Co-III(pin(F))(2)](1-), 2, is reported. Rigidly... 
FUNCTIONALIZATION | ELECTRONIC-PROPERTIES | SPIN | COMPLEXES | SUSCEPTIBILITY | RECENT PROGRESS | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS | CHALLENGES | 4-COORDINATE
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 67, pp. 9304 - 9307
We present the first examples of the coexistence of field induced slow magnetic relaxation and spin-crossover observed in five-coordinate cobalt(II) complexes... 
SINGLE-MOLECULE MAGNET | FE(II) | BEHAVIOR | STATE | SYSTEMS | IRON(II) | BLOCKING | ANISOTROPY | CHEMISTRY, MULTIDISCIPLINARY | ION MAGNET | 4-COORDINATE
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 05/2016, Volume 138, Issue 20, pp. 6662 - 6669
In the absence of transition metal catalysts, the unsymmetrical diborane(4), pinB-BMes(2), reacted with alkynes to afford diborylalkenes. The isomer ratio of... 
ELECTRON-AFFINITY | 4-COORDINATE ORGANOBORON COMPOUNDS | UNSATURATED ORGANIC-COMPOUNDS | 2-PHOTON ABSORPTION | NONLINEAR-OPTICAL PROPERTIES | DIBORON TETRACHLORIDE | CRYSTAL-STRUCTURES | N-HETEROCYCLIC CARBENES | CONJUGATE ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY | QUINOLATE BLOCK-COPOLYMERS
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2017, Volume 53, Issue 62, pp. 8723 - 8726
An efficient thermally activated delayed fluorescence emitter based on an N-heteroarene acceptor bearing an intramolecularly coordinated boryl group was... 
LIGHT-EMITTING-DIODES | ELECTRON-AFFINITY | BORON COMPLEXES | 4-COORDINATE ORGANOBORON COMPOUNDS | SOLAR-CELLS | PERFORMANCE | EFFICIENT BLUE ELECTROLUMINESCENCE | EMITTERS | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | SCAFFOLD
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 17, pp. 4436 - 4439
Combining a three-coordinated boron (BMes(2)) moiety with a four-coordinated photochromic organoboron unit leads to a series of new diboron compounds that... 
DIARYLETHENE MOLECULES | 4-COORDINATE ORGANOBORON COMPOUNDS | N,C-CHELATE | RECOGNITION | AZO GROUP | BEHAVIOR | CHEMISTRY | CRYSTALS | CHEMISTRY, ORGANIC | LEWIS ACIDITY | CATIONIC BORANES
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 07/2019, Volume 48, Issue 28, pp. 10723 - 10732
The new bis-o-iminobenzosemiquinonate nickel and cobalt complexes (imSQ(t-Bu))(2)M (M = Ni (1), Co (2)), where imSQ is a radical anion of... 
NONINNOCENT LIGAND | SQUARE-PLANAR | TRANSITION-METAL-COMPLEXES | CRYSTAL-STRUCTURE | OXIDATION-STATES | ELECTRON-TRANSFER SERIES | COORDINATION | NICKEL(O)-BIS(CHELATES) | 4-COORDINATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 2017, Volume 36, Issue 6, pp. 1122 - 1132
A new zwitterionic nickel(II) catalyst that comprises a partially fluorinated tetrakis(aryl)borate center in a bidentate phosphine ligand and a cationic Ni... 
INSERTION | POLYMERIZATION CATALYSTS | CARBON-MONOXIDE | COMPLEXES | CHEMISTRY, ORGANIC | OLEFINS | ETHENE | DEACTIVATION | 4-COORDINATE | INSIGHTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Nature Chemistry, ISSN 1755-4330, 04/2010, Volume 2, Issue 4, pp. 257 - 268
Journal Article
Organometallics, ISSN 0276-7333, 09/2014, Volume 33, Issue 18, pp. 4931 - 4939
Eight new and stable triazaborine chromophores featuring various substituents as donor and acceptor moieties were prepared and investigated. An interpretation... 
4-COORDINATE ORGANOBORON COMPOUNDS | INHIBITION | FUNCTIONALIZED BORON | CHEMISTRY, ORGANIC | LUMINESCENT PROPERTIES | HETEROAROMATIC-COMPOUNDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 04/2016, Volume 55, Issue 8, pp. 3894 - 3906
Low-coordinate transition-metal complexes that undergo spin crossover remain rare. We report here a series of four-coordinate, pseudo-tetrahedral P3FeII-X... 
TRANSITION | IRON(II) COMPLEXES | PHOSPHINIMIDE COMPLEXES | LIGANDS | PHOSPHORANIMINATO COMPLEXES | ELECTRONIC CONTROL | NITRIDO COMPLEX | REACTIVITY | NITROGEN ATOM-TRANSFER | 4-COORDINATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 11, pp. 4580 - 4587
Luminescent B-N containing conjugated ladder compounds are prepared by directed electrophilic aromatic substitution. Negishi cross-coupling reaction of... 
BORON-COMPOUNDS | ARENE BORYLATION | B-N | CONJUGATED POLYMERS | FLUORESCENCE | N,C-CHELATE | AFFINITY | COMPLEXES | SYSTEMS | 4-COORDINATE ORGANOBORONS | CHEMISTRY, INORGANIC & NUCLEAR | Electronic structure | Aromatic compounds | Precursors | Toluene | Emissions control | Chemical reactions | Ladder compounds | Furnishings
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 09/2019, Volume 495, p. 118992
A series of four NNN-pyridine based ligands of the general form: pyCH N(R)CH py {R = propyl, butyl, cyclohexyl and phenyl; py = pyridine} were synthesised and... 
NNN ligands | Alkanes | Oxidation | Cobalt complexes | Alcohols | CRYSTAL-STRUCTURE | STRUCTURAL-CHARACTERIZATION | COPPER | CHEMISTRY, INORGANIC & NUCLEAR | MILD | LIGANDS | COBALT(II) COMPLEXES | CATALYSTS | C-H | 4-COORDINATE
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 07/2017, Volume 36, Issue 14, pp. 2527 - 2535
In this work we report on a preparative strategy that allows the facile tuning of the electron affinities of pi-conjugated organic n-type materials via... 
ELECTRON SIGMA-BOND | ORGANIC SOLAR-CELLS | ENERGY-LEVELS | CHEMISTRY, ORGANIC | N-HETEROACENES | 4-COORDINATE ORGANOBORONS | C-H BORYLATION | AMORPHOUS MOLECULAR MATERIALS | LEWIS ACIDITY | BAND-GAP | RATIONAL DESIGN | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 2019, Volume 43, Issue 3, pp. 1589 - 1596
A practical nickel catalyst system consisting of readily available components, trans-NiCl(Ph)(PPh3)(2)/[Iprmim]I/K3PO4 center dot 3H(2)O in toluene, has been... 
BORONIC ACIDS | METHANESULFONIC-ACID | EFFICIENT CATALYST | AMINATION | 4-COORDINATE ORGANOBORON COMPOUNDS | NI(II)-(SIGMA-ARYL) COMPLEX | C-N | PRE-CATALYST | 2-AMINOETHYL DIPHENYLBORINATE 2-APB | SUZUKI-MIYAURA REACTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2012, Volume 48, Issue 9, pp. 1266 - 1268
The use of a mixed phosphite/N-heterocyclic carbene bearing ruthenium precursor permits the synthesis and characterisation of unprecedented four-coordinate... 
HETEROCYCLES | LIGANDS | AGOSTIC INTERACTIONS | RING | REACTIVITY | STATE | CHEMISTRY, MULTIDISCIPLINARY | POLYMERIZATION ROMP | 4-COORDINATE | Ruthenium | Synthesis | Catalysts | Cationic | Precursors | Olefins | Catalysis | Carbenes
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 40, pp. 15779 - 15782
Treatment of the lithium salt of beta-ketimine with FeCl2(THF)(1.5) in the presence of LiN(SiMe3)(2) and water affords the multimetallic iron(II)-lithium... 
TRANSITION | IRON(III) | KETIMINATE LIGANDS SYNTHESIS | RING-OPENING POLYMERIZATION | BETA-KETOIMINATO COMPLEXES | 4-COORDINATE | CHEMISTRY, INORGANIC & NUCLEAR | Molecular structure | Molecular weight distribution | Initiators | Polymerization | Lithium | Formations | Conversion | Monomers
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 09/2014, Volume 43, Issue 35, pp. 13278 - 13292
Two different structure types were found for a series of mononuclear dinitrosyl complexes of the general formula [RuL2(NO)(2)X]BF4 (L = monodentate phosphane,... 
INFRARED-SPECTRA | NITROSYL | COMPLEX | SHAPE | LIGANDS | MOLECULAR-STRUCTURE | BENT | NITRIC-OXIDE | INTERCONVERSION | 4-COORDINATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 07/2008, Volume 27, Issue 13, pp. 2905 - 2907
The reactions of the bis(alkyl) complexes [Ap*Ln(CH2SiMe3)(2)(thf)] (Ln = Y, Lu) with both PhSiH3 and H-2 result in selective assembly of the novel trinuclear... 
CATALYZED-HYDROBORATION | (C5ME4SIME3)LNH UNITS | OLEFIN HYDROGENATION | HIGHLY REACTIVE ORGANOLANTHANIDES | CHEMISTRY | CHEMISTRY, ORGANIC | ORGANOYTTRIUM CATIONS | POLYMERIZATION | METAL POLYHYDRIDO COMPLEXES | 4-COORDINATE HYDROGEN-ATOM | YTTRIUM HYDRIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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