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Physica B: Physics of Condensed Matter, ISSN 0921-4526, 2006, Volume 385, pp. 231 - 233
A 4-coordinate H atom has been unambiguously located, by single-crystal neutron diffraction for the first time, in the center of the tetrahedral metal complex... 
Metal cluster | Yttrium | Neutron diffraction | 4-coordinate hydrogen | PHYSICS, CONDENSED MATTER | COMPLEX | yttrium | metal cluster | X-RAY | neutron diffraction | UNITS | HYDRIDE LIGAND | COBALT | Rare earth metals | Ethers
Journal Article
Nature Chemistry, ISSN 1755-4330, 04/2010, Volume 2, Issue 4, pp. 257 - 268
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2011, Volume 50, Issue 8, pp. 1857 - 1860
PNP downsizes hydride: Hydrogenolysis of dialkyl precursors results in trinuclear hexahydride complexes A (Me‐PNPiPr= {4‐Me‐2‐(iPr2P)‐C6H3}2N). Treatment with... 
hydrides | cationic complexes | N,P ligands | rare earths | (C5ME4SIME3)LNH UNITS | ALKYL | DIOXIDE | POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | METAL COMPLEXES | CARBON-MONOXIDE | HYDRIDE CLUSTER | SELECTIVE FORMATION | COPOLYMERIZATION | 4-COORDINATE HYDROGEN-ATOM
Journal Article
Nature Chemistry, ISSN 1755-4330, 10/2011, Volume 3, Issue 10, pp. 814 - 820
Journal Article
Organometallics, ISSN 0276-7333, 05/2011, Volume 30, Issue 9, pp. 2513 - 2524
The novel series of half-sandwich tetrahydrofuran (THF)-free yttrium bis(aminobenzyl) complexes [(C5Me4R)Y(CH2C6H4NMe2-o)2] (R = SiMe3 (1a), Me (1b), Et (1c),... 
(C5ME4SIME3)LNH UNITS | POLYHYDRIDO COMPLEXES | SI-C BONDS | AMINOBENZYL COMPLEXES | LANTHANIDE COMPLEXES | NEUTRON-DIFFRACTION | CHEMISTRY, ORGANIC | STRUCTURAL-CHARACTERIZATION | EARTH-METAL COMPLEXES | PERMETHYLYTTROCENE DERIVATIVES | 4-COORDINATE HYDROGEN-ATOM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 04/2013, Volume 32, Issue 7, pp. 2145 - 2151
A series of tetranuclear group 4 transition metal octahydride complexes [(C5Me4R)4M4(μ-H)8] (2-Zr, M = Zr, R = SiMe3; 2-Hf, M = Hf, R = SiMe3; 3, M = Zr, R =... 
TRANSITION-ELEMENTS | ENERGY-ADJUSTED PSEUDOPOTENTIALS | (C5ME4SIME3)LNH UNITS | CARBON-MONOXIDE | REACTIVITY | CHEMISTRY, ORGANIC | POLYMERIZATION | EARTH-METAL COMPLEXES | CLUSTER | 4-COORDINATE HYDROGEN-ATOM | HYDRIDE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2012, Volume 48, Issue 6, pp. 814 - 816
The first well defined cationic terminal hydrido rare earth complexes [NCN)LnH(THF)(3)][BPh4] were isolated from THF, which on recrystallization from... 
(C5ME4SIME3)LNH UNITS | ALKYL | CARBON-MONOXIDE | POLYMERIZATION | METAL POLYHYDRIDO COMPLEXES | CLUSTER | FULL-SIZE RANGE | SELECTIVE FORMATION | COPOLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | 4-COORDINATE HYDROGEN-ATOM | Rare earth metals | Dihydrides | Cationic | Recrystallization | Ligands | Terminals | Chlorobenzenes | Bearing
Journal Article
Organometallics, ISSN 0276-7333, 10/2013, Volume 32, Issue 20, pp. 5705 - 5708
The ferrocene-based bis(phosphinoamide) fc(NHP i Pr2)2 (where fc = 1,1′-ferrocenyl) has been synthesized and coordinated to scandium via alkane elimination.... 
CARBON BOND FORMATION | TITANIUM(IV) PHOSPHINOAMIDE | (C5ME4SIME3)LNH UNITS | POLYMERIZATION CATALYSTS | YTTRIUM COMPLEXES | CHEMISTRY, ORGANIC | AMIDO-CYCLOPENTADIENYL LIGAND | METAL POLYHYDRIDO COMPLEXES | 4-COORDINATE HYDROGEN-ATOM | C-H BONDS | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 6/2010, Volume 83, Issue 6, pp. 595 - 608
This article describes our recent studies on the synthesis and chemistry of mono(cyclopentadienyl)-ligated rare earth metal alkyl and hydride complexes. The... 
SYNDIOSPECIFIC STYRENE | BEARING MONO(CYCLOPENTADIENYL) LIGANDS | YTTRIUM COMPLEX | (C5ME4SIME3)LNH UNITS | POLYHYDRIDO COMPLEXES | EFFICIENT ROUTE | TERMINAL ALKYNES | STRUCTURAL-CHARACTERIZATION | AMINE N-H | CHEMISTRY, MULTIDISCIPLINARY | 4-COORDINATE HYDROGEN-ATOM | Rare earth metals | Catalysts | Olefins | Polymerization | Ligands | Terminals | Catalysis | Alkynes
Journal Article
Dalton Transactions, ISSN 1477-9226, 2010, Volume 39, Issue 29, pp. 6858 - 6863
The scandium dialkyl complex [Cp'Sc(CH2SiMe3)(2)(THF)] (1-Sc, Cp' = C5Me4SiMe3) reacts rapidly with ammonia at room temperature to afford selectively a... 
OLEFIN-POLYMERIZATION | (C5ME4SIME3)LNH UNITS | NEUTRON-DIFFRACTION | PRIMARY AMINES | ALLYLIC AMINATION | OXIDATIVE ADDITION | 4-COORDINATE HYDROGEN-ATOM | REDUCTIVE AMINATION | HYDRIDE COMPLEXES | PALLADIUM-CATALYZED AMINATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2014, Volume 53, Issue 28, pp. 7233 - 7237
Metal hydrides are of fundamental importance in chemistry, both as solid‐state materials and molecular compounds. The first low‐valent molecular metal cluster... 
aurophilicity | iron | cluster compounds | hydride ligands | carbonyl ligands | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | TRANSITION-METAL HYDRIDES | GOLD(I) COMPLEXES | NEUTRON-DIFFRACTION ANALYSIS | RARE-EARTH | X-RAY | LIGAND | 4-COORDINATE HYDROGEN-ATOM | THEORETICAL CHEMISTRY | Nuclear magnetic resonance spectroscopy | Clathrate compounds
Journal Article
Organometallics, ISSN 0276-7333, 04/2009, Volume 28, Issue 7, pp. 2244 - 2252
The reaction of half-sandwich rare earth metal bis(alkyl) complexes Cp′Ln(CH2SiMe3)2(THF) (Cp′ = η5-C5Me4SiMe3; Ln = Y, Lu) with 1 equiv of the binuclear... 
H BOND ACTIVATION | OLEFIN-POLYMERIZATION | (C5ME4SIME3)LNH UNITS | FLUXIONAL BEHAVIOR | CRYSTAL-STRUCTURE | LANTHANIDE COMPLEXES | NEUTRON-DIFFRACTION | CHEMISTRY, ORGANIC | YTTRIUM CLUSTER | HYDRIDE-LIGANDS | 4-COORDINATE HYDROGEN-ATOM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2008, Volume 130, Issue 13, pp. 4262 - 4276
Journal Article
Organometallics, ISSN 0276-7333, 09/1999, Volume 18, Issue 20, pp. 3965 - 3967
A novel ate tin hydride complex, Li+[n-Bu2SnI2H]- (I), was synthesized and characterized on the basis of its 119Sn NMR spectrum as a trigonal bipyramid (TBP)... 
KETONES | C-13 | CONJUGATE REDUCTION | CHEMISTRY, ORGANIC | EXCHANGE | 4-COORDINATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Applied Organometallic Chemistry, ISSN 0268-2605, 03/2019, Volume 33, Issue 3, pp. e4715 - n/a
Journal Article