X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
chemistry, inorganic & nuclear (129) 129
chemistry, organic (60) 60
7-coordinate molybdenum (59) 59
tungsten (51) 51
molybdenum (45) 45
molecular-structure (37) 37
ligands (32) 32
7-coordinate complexes (30) 30
chemistry, multidisciplinary (26) 26
crystal-structure (26) 26
7-coordinate (24) 24
donor ligands (24) 24
ray crystal-structure (20) 20
crystal-structures (19) 19
crystallography (19) 19
spectral properties (19) 19
x-ray structure (19) 19
chemistry (18) 18
derivatives (18) 18
complexes (17) 17
higher coordinate cyanide (17) 17
7-coordinate niobium (15) 15
carbon-monoxide (15) 15
isocyanide complexes (14) 14
crystal structure (13) 13
tungsten complexes (13) 13
crystal structures (12) 12
metal-complexes (12) 12
alkyne complexes (11) 11
isocyanide ligands (11) 11
bis complexes (10) 10
carbonyl (10) 10
chemical properties (10) 10
crystal (10) 10
m = mo (10) 10
tantalum (10) 10
alkyne (9) 9
analysis (9) 9
catalysis (9) 9
coordination chemistry (9) 9
niobium (9) 9
ray crystal-structures (9) 9
tin (9) 9
7-coordinate mn complexes (8) 8
form (8) 8
polymerization (8) 8
carbyne complexes (7) 7
index medicus (7) 7
ligand (7) 7
methyl isocyanide (7) 7
seven-coordinate (7) 7
usage (7) 7
7-coordinate molybdenum-tin (6) 6
7-coordinate organotin (6) 6
carbon-monoxide ligands (6) 6
carbonyl-complexes (6) 6
chromium (6) 6
halide (6) 6
mechanism (6) 6
oxidation (6) 6
oxidation-reduction reaction (6) 6
reactivity (6) 6
research (6) 6
titanium (6) 6
transition-metal-complexes (6) 6
aminocarbyne complexes (5) 5
chemistry, physical (5) 5
electrochemistry (5) 5
manganese (5) 5
multiple bonds (5) 5
norbornadiene (5) 5
norbornene (5) 5
nuclear magnetic-resonance (5) 5
palladium (5) 5
phosphites (5) 5
photochemical-reaction (5) 5
sn-119 chemical-shifts (5) 5
spectroscopic properties (5) 5
spectroscopy (5) 5
substituted diethylaminocarbyne complexes (5) 5
tert-butyl isocyanide (5) 5
transition-metal complexes (5) 5
water exchange (5) 5
wi2 (5) 5
7-coordinate iron complex (4) 4
acetonitrile (4) 4
active-site (4) 4
carbyne (4) 4
coordination (4) 4
group-4 (4) 4
intermediate oxidation-states (4) 4
metal-carbyne complexes (4) 4
mo2 (4) 4
mocl (4) 4
molecular-structures (4) 4
monoxide ligands (4) 4
olefin metathesis (4) 4
oxidative addition (4) 4
oxidative stress (4) 4
phosphine (4) 4
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Inorganica Chimica Acta, ISSN 0020-1693, 02/2017, Volume 456, pp. 9 - 17
Molybdenum and tungsten heptacoordinated complexes [MI2(CO)3(pyrazole)2] have been synthesized and characterized. In solid state they present two possible... 
Fluxionality | Molybdenum | Isomers | Tungsten | Pyrazole | PYRAZOLE COMPLEXES | TRANSITION-METAL-COMPLEXES | MOLECULAR-STRUCTURE | HYDROGEN-BOND | C-13 NMR-SPECTRA | CHEMISTRY, INORGANIC & NUCLEAR | 7-COORDINATE COMPLEXES | RAY CRYSTAL-STRUCTURES | SET MODEL CHEMISTRY | X-RAY | DYNAMIC-BEHAVIOR | Structure | Crystals
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2018, Volume 57, Issue 17, pp. 10557 - 10567
The concept of random coordination ratios, RCRs, is advanced for lanthanide complexes. RCRs describe the relative probabilities of occurrence of subsets of... 
CIRCULARLY-POLARIZED LUMINESCENCE | GEOMETRIES | MECHANISM | 7-COORDINATE COMPLEXES | CRYSTAL-STRUCTURE | KINETICS | ISOMERIZATION | POLYAS THEOREM | CHEMISTRY | REARRANGEMENTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 5, pp. 1822 - 1825
η2-Iminoketenyl species have often been postulated as the intermediates in nucleophile-induced carbyne–isocyanide C–C coupling processes. However, such species... 
M(PHPCHCHPPH) M=MO | ELECTROPHILIC ADDITION | METHYL ISOCYANIDE | CARBON-MONOXIDE | TRANSITION-METAL | AMINOCARBYNE COUPLING REACTIONS | ALKYNE LIGANDS | STRUCTURAL-CHARACTERIZATION | CHEMISTRY, MULTIDISCIPLINARY | 7-COORDINATE MOLYBDENUM(II) | W SITES | Chemical bonds | Chemical reactions | Usage | Cyanides | Chemical properties | Analysis
Journal Article
Organometallics, ISSN 0276-7333, 09/2016, Volume 35, Issue 17, pp. 3032 - 3039
The reaction of hexacarbonyl group 6 complexes with the P­(CH)­P ligand N,N′-bis­(diisopropylphosphino)-N,N′-dimethyl-1,3-diaminobenzene was investigated. The... 
DENSITY FUNCTIONALS | CONTINUUM SOLVATION MODELS | MOLECULAR-ORBITAL METHODS | AGOSTIC INTERACTIONS | 7-COORDINATE COMPLEXES | EQUILIBRIUM GEOMETRIES | CHEMISTRY, ORGANIC | CATALYTIC APPLICATIONS | OXIDATIVE ADDITION | GAUSSIAN-BASIS SETS | METAL-COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2003, Volume 9, Issue 6, pp. 1281 - 1295
The stereochemistries of heptacoordinate transition‐metal complexes are analyzed by using continuous symmetry and shape measures of their coordination spheres.... 
coordination modes | metal complexes | continuous symmetry measures | structure correlations | symmetry maps | Continuous symmetry measures | Coordination modes | Structure correlations | Metal complexes | Symmetry maps | MECHANISM | ACTIVE-SITE | MOLYBDENUM | CRYSTAL-STRUCTURE | STEREOCHEMISTRY | COORDINATION | 7-COORDINATE | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | ENZYME | LIGANDS
Journal Article
Organometallics, ISSN 0276-7333, 08/2016, Volume 35, Issue 15, pp. 2532 - 2542
A synthetic procedure based on sequential C-directed C–H bond activation reactions is reported for the preparation of capped octahedral OsHC6 complexes.... 
HETEROCYCLIC CARBENE LIGAND | MOLYBDENUM(II) | MOLECULAR-ORBITAL METHODS | CRYSTAL-STRUCTURE | POP-PINCER OSMIUM | 7-COORDINATE COMPLEX | N-H | CHEMISTRY, ORGANIC | BASIS-SETS | PI-STACKING INTERACTIONS | METATHESIS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Molecular Structure, ISSN 0022-2860, 02/2016, Volume 1105, pp. 205 - 213
X-ray crystal structure determination, as well as IR and NMR spectroscopy of four novel triphenylarsine-substituted tetracarbonyl tungsten(0) Fischer carbene... 
Conformations | Triphenylarsine | Fischer carbene | DFT | Tungsten | MOLYBDENUM | CHEMISTRY, PHYSICAL | CRYSTAL-STRUCTURES | M=MO | NMR | SPECTROSCOPY | 7-COORDINATE COMPLEXES | SPECTRA | TRANS-INFLUENCE | Nuclear magnetic resonance spectroscopy | Arsenic compounds
Journal Article
Journal of Inorganic Biochemistry, ISSN 0162-0134, 2003, Volume 96, Issue 2, pp. 298 - 310
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2014, Volume 43, Issue 25, pp. 9557 - 9566
The reactions of the soft diphosphines o-C6H4(PMe2)(2), Me2P(CH2)(2)PMe2, Et2P(CH2)(2)PEt2 or o-C6H4(PPh2)(2) with NbF5 or TaF5 in anhydrous MeCN solution... 
PENTAHALIDES | TITANIUM(IV) | PHOSPHORUS | PHOSPHANE LIGANDS | DONOR LIGANDS | COORDINATION-COMPLEXES | BOND-CLEAVAGE | 7-COORDINATE | 6-COORDINATE | HALIDE-COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Synthesis | Chlorides | X-rays | Distortion | Infrared radiation | Fluorides | NMR spectroscopy | Crystal structure
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2016, Volume 22, Issue 27, pp. 9106 - 9110
A MHC6 complex of a platinum group metal with a capped octahedral arrangement of donor atoms around the metal center has been characterized. This osmium... 
N-heterocyclic carbene | osmium | hydride | capped octahedron | agostic interactions | NHC COMPLEXES | CRYSTAL-STRUCTURE | SPECTROSCOPIC PROPERTIES | 7-COORDINATE COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | LIGANDS PREPARATION | POLYHYDRIDE COMPLEXES | INTRAMOLECULAR C-H | OSMIUM COMPLEXES | IMIDAZOLIUM SALTS | Platinum
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2018, Volume 54, Issue 18, pp. 2292 - 2295
The reaction of [W(?CH)Br(CO)(2)(dcpe)] (dcpe = 1,2-bis(dicyclohexylphosphino)ethane) with (BuLi)-Bu-t and SiCl4 affords the trichlorosilyl ligated... 
SILYL COMPLEXES | TRANSITION-METAL-COMPLEXES | CARBON-MONOXIDE | MOLYBDENUM | CRYSTAL-STRUCTURE | CARBYNE LIGANDS | BONDS | TUNGSTEN(VI) NEOPENTYLIDYNE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | 7-COORDINATE NIOBIUM(I) | Homology | Ethane | Silicon tetrachloride
Journal Article
Chemical Communications, ISSN 1359-7345, 2007, Issue 26, pp. 2692 - 2694
The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile... 
CYCLOADDITION | MONONUCLEAR | SUBSTITUTION BEHAVIOR | LIGANDS | RU(II) COMPLEXES | RUTHENIUM(II) | DONOR | CLICK CHEMISTRY | 7-COORDINATE IRON(III) COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | METAL-COMPLEXES | Models, Molecular | Crystallography, X-Ray | Pyridines - chemistry | Spectrophotometry, Ultraviolet
Journal Article