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Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 36, pp. 10613 - 10617
The direct CH annulation of anilines or related compounds with internal alkynes provides straightforward access to 2,3‐disubstituted indole products. However,... 
CH activation | indoles | nitrones | alkynes | rhodium | C-H activation | Organic chemistry | Synthesis | Aromatic compounds | Group theory | Chemical reactions | Transformations | Indoles | Alkynes
Journal Article
Current Opinion in Chemical Biology, ISSN 1367-5931, 08/2014, Volume 21, pp. 81 - 88
•Strain-promoted alkyne-nitrone cycloadditions (SPANCs) are rapid and efficient bioorthogonal reactions.•Endocyclic nitrones are water stable and preferred... 
CELLS | 1,3-DIPOLAR CYCLOADDITIONS | GENETIC-CODE | BIOPHYSICS | AMINO-ACIDS | BIOCHEMISTRY & MOLECULAR BIOLOGY | IN-VIVO | ESCHERICHIA-COLI | SOLID-PHASE | LIVING SYSTEMS | COPPER | FREE CLICK CHEMISTRY | Staining and Labeling - methods | Alkynes - chemistry | Kinetics | Nitrogen Oxides - chemistry | Cycloaddition Reaction - methods | Proteins
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 12/2016, Volume 358, Issue 23, pp. 3748 - 3752
The first copper(I)‐catalyzed asymmetric 1,3‐dipolar [3+4] cycloaddition of nitrones with azoalkenes has been developed, affording a variety of biologically... 
nitrones | asymmetric catalysis | 1,3-dipolar [3+4] cycloaddition | azoalkenes | ENOL ETHERS | CATALYZED 4+3 CYCLOADDITION | CHEMISTRY, ORGANIC | 3-dipolar [3+4] cycloaddition | YLIDES | AZOMETHINE IMINES | CATIONS | ESTERS | BEARING | CHEMISTRY, APPLIED | DERIVATIVES | ACCESS | Copper | Catalysis | Synthesis (chemistry) | Cycloaddition | Derivatives | Asymmetry
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2017, Volume 23, Issue 51, pp. 12450 - 12455
1,3‐Dipolar cycloaddition is a commonly exploited method to access 5‐membered chemical entities with a variety of peripheral functionalities and their... 
indium | isoxazolidine | bishydroxamic acid | asymmetric catalysis | cycloaddition reactions | DIELS-ALDER | AMINO-ALCOHOLS | LEWIS-ACID | HOMOALLYLIC ALCOHOLS | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE EPOXIDATION | ALPHA-N-3 AMIDE | MANNICH-TYPE REACTION | ALDOL REACTION | CHIRAL COMPLEXES | METAL-COMPLEXES
Journal Article
Organic Letters, ISSN 1523-7060, 02/2015, Volume 17, Issue 4, pp. 994 - 997
Aryl-aldehydes containing ortho-substituted α,β-unsaturated carboxylic acid derivatives react with hydroxylamine to afford reactive N-hydroxy-carbinolamine... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 32, pp. 9183 - 9186
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 13, pp. 4381 - 4385
An approach to cyclic nitrones from N‐hydroxylactam derivatives is documented. The nucleophilic addition of an organolithium reagent to an N‐OSEM... 
amides | nitrones | total synthesis | nucleophilic addition | synthetic methods | Lithium compounds | Synthesis | Organic compounds | Substitutes | Amides | Oxidation | Derivatives | Reagents
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 840 - 843
A method for the addition of fluorinated groups to nitrones using an iridium photocatalyst and ascorbic acid as a stoichiometric reducing agent is described.... 
MEDICINAL CHEMISTRY | HYDRAZONES | VISIBLE-LIGHT | REAGENTS | COMPLEXES | LIGHT PHOTOREDOX CATALYSIS | CHEMISTRY, ORGANIC | FLUORINE | RADICALS | PERFLUOROALKYLATION REACTIONS | TRIFLUOROMETHYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2007, Volume 129, Issue 41, pp. 12356 - 12357
A new type of reagent, γ-methylidene-δ-valerolactones, has been devised, which acts as a four-carbon unit in a palladium-catalyzed cycloaddition reaction... 
REARRANGEMENT | REAGENTS | ALKYLATION | ALLYLATION | TRIMETHYLENEMETHANE | INTERMEDIATE | OLEFINS | GENERATION | CHEMISTRY, MULTIDISCIPLINARY | CONJUGATE ADDITION | AZOMETHINE IMINES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2016, Volume 138, Issue 16, pp. 5246 - 5249
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 15, pp. 4571 - 4574
Various benzoxazonines were synthesized through a formal [7 + 2] cycloaddition of arynes with N-vinyl-α,β-unsaturated nitrones under mild conditions.... 
ASYMMETRIC 1,3-DIPOLAR CYCLOADDITION | ISOXAZOLIDINES | HETEROCYCLES | ETHYL CYCLOPROPYLIDENEACETATE | VINYL NITRONES | MEDIATED SYNTHESIS | CONSTRUCTION | AZOMETHINE YLIDES | CHEMISTRY, ORGANIC | PHENANTHRIDINONE | IN-SITU GENERATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2013, Volume 355, Issue 8, pp. 1523 - 1528
Some readily available Boc‐protected 2‐(3‐methoxy‐1‐propynyl)anilines and nitrones in platinum‐catalyzed reactions deliver [1,2]oxazino[5,4‐b]indoles. Twelve... 
amines | indoles | platinum | nitrones | alkynes | MIGRATION | PHENOL SYNTHESIS | 2-(1-ALKYNYL)-2-ALKEN-1-ONES | GOLD-CATALYSIS | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | CYCLOPROPANES | HIGHLY EFFICIENT | 1,3-DIPOLAR CYCLOADDITION | CHEMISTRY, APPLIED | DERIVATIVES | TRANSFORMATIONS | Cycloaddition | Trapping | Synthesis | Esters | Indoles | Catalysis | Carbenes
Journal Article