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chemistry, organic (14) 14
acetate catalyzed reaction (7) 7
acetate (6) 6
acetate-catalyzed reaction (6) 6
kinetic (6) 6
organic (6) 6
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alpha-diazoacetophenone derivatives (4) 4
dipolar-cycloaddition (4) 4
pcl (4) 4
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resolution (4) 4
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vinyl (4) 4
vinyl acetate (4) 4
acetylation (3) 3
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studies (3) 3
1,3-dipolar cycloaddition (2) 2
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alpha-diazocarbonyl compounds (2) 2
amides (2) 2
analysis of optical resolution data (2) 2
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aspidosperma alkaloids (2) 2
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indole (2) 2
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isopropenyl acetate (2) 2
isothiocyanates (2) 2
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kopsifoline (2) 2
materials science, paper & wood (2) 2
metallo carbenoids (2) 2
organic solvent (2) 2
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research (2) 2
thiocarbonyl ylides (2) 2
ylide formation-cycloaddition (2) 2
1,3-dipole (1) 1
1,3-oxathiole (1) 1
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1,5- electrocyclization (1) 1
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1-alkanol (1) 1
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<2,3>-sigmatropic rearrangement (1) 1
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The Journal of Organic Chemistry, ISSN 0022-3263, 12/2015, Volume 80, Issue 23, pp. 11877 - 11887
endo-Tricyclo­[3.2.1.02,4]­oct-8-ylidene is a foiled carbene reaction intermediate. It was generated by thermolyzing Δ3-1,3,4-oxadiazoline precursors dissolved... 
NUCLEOPHILIC CARBENES | 2-NORBORNYL CATION | ACETATE CATALYZED REACTION | ENOL ESTER EPOXIDES | NEGATIVE ACTIVATION-ENERGIES | 1,3-DIPOLAR CYCLOADDITION | INSERTION REACTIONS | CHEMISTRY, ORGANIC | YLIDE FORMATION-CYCLOADDITION | DENSITY-FUNCTIONAL THEORY | C-H BONDS | Chemical properties | Stereochemistry | Research | Carbenes | Ylides
Journal Article
Journal of Wood Science, ISSN 1435-0211, 8/2012, Volume 58, Issue 4, pp. 336 - 341
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 8/2004, Volume 77, Issue 8, pp. 1555 - 1567
Lithium acetate (AcOLi)-catalyzed aldol reactions between trimethylsilyl enolates and aldehydes proceed smoothly in anhydrous DMF or pyridine to afford the... 
KETENE SILYL ACETALS | BINAP | ACIDITIES | ORGANIC-REACTIONS | COMPLEXES | CARBONYL-COMPOUNDS | SYSTEMS | DIAQUA | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2007, Volume 48, Issue 34, pp. 5938 - 5941
The Rh(II)-catalyzed reaction of the E-isomer of 2-diazo-3,6-dioxo-6-phenyl-hex-enoic acid methyl ester was carried out in the presence of various carbonyl... 
CYCLOADDITION REACTIONS | ACETATE CATALYZED REACTION | METALLO CARBENOIDS | CYCLO-ADDITION REACTION | CONVERGENT APPROACH | CHEMISTRY, ORGANIC | ALPHA-DIAZOACETOPHENONE DERIVATIVES | DIPOLAR-CYCLOADDITION | RING-SYSTEM | TAXANE DITERPENES | CARBONYL YLIDES
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 03/2015, Volume 119, Issue 12, pp. 3141 - 3146
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 03/2011, Volume 15, Issue 5, pp. 675 - 693
The reactive thiocarbonyl ylides belong to the less well-known class of the so-called 'sulfur-centered 1,3-dipoles'. Only in recent years have the [2+3]... 
Electrocyclizations | Sulfur heterocycles | Thiocarbonyl ylides | ALPHA-DIAZOCARBONYL COMPOUNDS | 1,3-DIPOLAR CYCLOADDITIONS | ORGANIC SULFUR | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | 1,3-OXATHIOLE | ACETATE-CATALYZED REACTION | PHENYL AZIDE | DERIVATIVES | RING-CLOSURE | AROMATIC THIOKETONES
Journal Article
Tetrahedron, ISSN 0040-4020, 2007, Volume 63, Issue 26, pp. 5962 - 5976
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2012, Volume 53, Issue 24, pp. 3095 - 3099
(a) [3+2]-Cycloaddition; (b) –N2, [1,5]-electrocyclization; (c) –N2, Wolff rearrangement; [4+2]-cycloaddition. Acyclic 2-diazo-1,3-dicarbonyl compounds react... 
Thioketones | Thiadiazoline | Cycloaddition | 2-Diazo-1,3-diazocarbonyl compounds | 2-Oxoketenes | Thiocarbonyl ylides | 1,5-Electrocyclization | Oxathioles | Pyrandiones | 1,5- Electrocyclization | CHEMISTRY, ORGANIC | ACETATE-CATALYZED REACTION | Dipoles | Aromatic compounds | Cascades | Decomposition reactions | Tetrahedrons | Dimers | Bonding
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2003, Volume 44, Issue 22, pp. 4175 - 4177
The reaction of thioamides with DMAD gave the pyrrole derivatives in good yield and the thiophene derivatives as a byproduct. These were formed by 1,3-dipolar... 
ISOTHIOCYANATES | CHEMISTRY, ORGANIC | ALPHA-DIAZOCARBONYL COMPOUNDS | PRODUCTS | ACETATE-CATALYZED REACTION
Journal Article
SYNLETT, ISSN 0936-5214, 03/2007, Issue 5, pp. 775 - 779
Journal Article
Wood Research, ISSN 1336-4561, 2015, Volume 60, Issue 2, pp. 247 - 254
Journal Article
Journal of the Chemical Society. Perkin Transactions 1, ISSN 1472-7781, 2002, Volume 2, Issue 21, pp. 2414 - 2417
Treatment of 3-methylamino-3-methylsulfanyl-1-phenylpropenethione 1 with excess (2.5 equiv.) alpha-diazo carbonyl compounds such as alpha-diazoketones and... 
ISOTHIOCYANATES | 1,3-THIAZOLE-5(4H)-THIONES | CARBENOIDS | CYCLOADDITIONS | CHEMISTRY, ORGANIC | THIOCARBONYL-YLIDES | GENERATION | CYCLIZATION | ACETATE-CATALYZED REACTION | DIAZOCARBONYL COMPOUNDS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 08/1993, Volume 58, Issue 17, pp. 4646 - 4655
The rhodium(II) carboxylate catalyzed decomposition of several alpha-diazo esters and amides has been studied. A series of 5-keto-1-diazo acetates were... 
DIAZOACETOPHENONE DERIVATIVES | 1,3-DIPOLAR CYCLOADDITIONS | ALKYNE INSERTION REACTIONS | CYCLO-ADDITION REACTION | CHEMISTRY, ORGANIC | NUCLEAR MAGNETIC-RESONANCE | OXONIUM YLIDES | <2,3>-SIGMATROPIC REARRANGEMENT | INTRAMOLECULAR ADDITION | C-H INSERTION | ACETATE-CATALYZED REACTION | Esters | Amides | Research
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 05/1997, Volume 38, Issue 19, pp. 3319 - 3322
Carbonyl ylide dipoles derived from diazoacetyl esters underwent 4π-electrocyclization to furnish bicyclic epoxides. Reaction of related α-diazoketo amides... 
ROUTE | K EE CHEMISTRY, ORGANIC | ACETATE CATALYZED REACTION | CONVERGENT APPROACH | CHEMISTRY, ORGANIC | YLIDE FORMATION | GENERATION | ALPHA-DIAZOACETOPHENONE DERIVATIVES | DIPOLAR-CYCLOADDITION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/1971, Volume 93, Issue 16, pp. 3853 - 3859
Journal Article
Synthetic Communications, ISSN 0039-7911, 03/2019, Volume 49, Issue 5, pp. 662 - 671
A straightforward and efficient method has been developed for the synthesis of 2-cyanoacrylamide from 2-methylenemalononitriles through monohydration. A series... 
Methylenemalononitriles | mild condition | palladium acetate catalyzed | 2-cyanoacrylamides | monohydration | KNOEVENAGEL | ACID | CONVERSION | HYDROLYSIS | CHEMISTRY, ORGANIC | CASCADE SYNTHESIS | RUTHENIUM | HYDRATION | NITRILES | EFFICIENT | AMIDES
Journal Article
by Zhang, J and Wang, BY and Liu, YS and Cao, S
CHINESE JOURNAL OF ORGANIC CHEMISTRY, ISSN 0253-2786, 01/2019, Volume 39, Issue 1, pp. 249 - 256
An efficient method for the synthesis of various Z-fluorostyrene derivatives via nickel-catalyzed cross-coupling of gem-difluorostyrenes with organozinc... 
gem-difluorostyrenes | nickel-catalyzed | ACIDS | SECONDARY | CHEMISTRY, ORGANIC | TERTIARY | HYDRODEFLUORINATION | 2-FLUOROALLYLIC ACETATES | PRIMARY ALKYL | organozinc reagents | ALPHA-FLUOROALKENYLATION | DIFLUOROALKENES | monofluoroalkenes | SELECTIVE SYNTHESIS
Journal Article
Journal of Oleo Science, ISSN 1345-8957, 2002, Volume 51, Issue 10, pp. 643 - 653
The optical resolution data were analyzed for Pseudomonas cepacia lipase (PCL) catalyzed transesterification between vinyl acetate and 2-alkanol in organic... 
Journal Article
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