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Tetrahedron, ISSN 0040-4020, 09/2014, Volume 70, Issue 38, pp. 6879 - 6884
Journal Article
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1434-193X, 09/2019, Volume 2019, Issue 34, pp. 5925 - 5933
A catalyst- and additive-free simple and straightforward method for regioselective direct sp2 C-H acetoxylation reaction of aldehyde hydrazones has been... 
C-H ACETOXYLATION | C(SP)-H ACETOXYLATION | TRISODIUM CITRATE DIHYDRATE | CATALYST-FREE | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | DIRECTING-GROUP | POT MULTICOMPONENT REACTION | C-H activation | Acetoxylation | GREEN SYNTHESIS | HYDRAZONE TAUTOMERISM | Hypervalent iodine compounds | Synthetic methods | ALIPHATIC CARBOXYLIC-ACIDS
Journal Article
by Gong, W and Zhang, GF and Liu, T and Giri, R and Yu, JQ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2014, Volume 136, Issue 48, pp. 16940 - 16946
Although the syntheses of novel and diverse peptides rely mainly on traditional coupling using unnatural amino acids, postsynthetic modification of peptides... 
POSTSYNTHETIC MODIFICATION | ACTIVATION | PEPTIDES | ACETOXYLATION | ACIDS | ALKYLATION | ARYLATION | FUTURE | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 02/2015, Volume 21, Issue 8, pp. 3264 - 3270
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2012, Volume 134, Issue 1, pp. 7 - 10
A method for five- and six-membered heterocycle formation by palladium-catalyzed C–H/N–H coupling is presented. The method employs a picolinamide directing... 
FUNCTIONALIZATION | PALLADIUM | ROUTE | AMINATION | ACTIVATION | ACETOXYLATION | AMIDATION | N BOND FORMATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED ARYLATION
Journal Article
Chinese Journal of Organic Chemistry, ISSN 0253-2786, 04/2015, Volume 35, Issue 4, pp. 813 - 826
Journal Article
Organic Letters, ISSN 1523-7060, 04/2012, Volume 14, Issue 8, pp. 2164 - 2167
Thioethers have been proven to be reliable directing groups for palladium catalyzed alkenylation of arenes via C–H activation. Mechanistic investigation... 
FUNCTIONALIZATION | SULFOXIDES | ACID | OLEFINATION | ACETOXYLATION | COUPLING REACTIONS | ARYLATION | CHEMISTRY, ORGANIC | BOND ACTIVATION | ALKYL ARYL KETONES | MOLECULES
Journal Article
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, ISSN 1434-1948, 11/2018, Issue 43, pp. 4742 - 4746
An N-heterocyclic carbene palladium(II) complex containing two anthracene side arms was immobilized on the surface of reduced graphene oxide (rGO) by... 
C-H activation | ACETOXYLATION | NHC | RECYCLABLE CATALYST | Palladium(II) | Undirected acetoxylation | EFFICIENT | METAL-COMPLEXES | IMMOBILIZATION | N-heterocyclic carbenes | Reduced graphene oxide supported Pd-II | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
by Li, W and Sun, PP
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 09/2012, Volume 77, Issue 18, pp. 8362 - 8366
A Pd(OAc)(2)-catalyzed ortho-alkoxylation of arylnitrile was described. Using cyano as a directing group, the aromatic C-H bond can be functionalized... 
FUNCTIONALIZATION | CATALYSIS | ACETOXYLATION | OXYGENATION | ARYL HALIDES | ARENES | ARYLATION | CHEMISTRY, ORGANIC | N-METHOXYBENZAMIDES | CYANATION | DERIVATIVES
Journal Article
Advanced Synthesis and Catalysis, ISSN 1615-4150, 09/2018, Volume 360, Issue 17, pp. 3228 - 3232
Journal Article
ADVANCED SYNTHESIS & CATALYSIS, ISSN 1615-4150, 09/2018, Volume 360, Issue 17, pp. 3228 - 3232
A cobalt-catalyzed sp(2) C-H acetoxylation of amides having 8-aminoquinoline as a directing group has been achieved using manganese(III) acetate both as an... 
C(SP)-H BONDS | ACTIVATION | C(SP)-H ACETOXYLATION | DIRECT ARYLATION | 8-aminoquinoline | ALLYLATION | C-H bond activation | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | CYANATION | Cobalt | INDOLES | BIDENTATE-CHELATION ASSISTANCE | acetoxylation | AROMATIC AMIDES | manganese(III) acetate | CHEMISTRY, APPLIED
Journal Article
Organic Letters, ISSN 1523-7060, 09/2014, Volume 16, Issue 17, pp. 4646 - 4649
A novel oxidative decarboxylation of β,γ-unsaturated carboxylic acids mediated by hypervalent iodine(III) reagents is described. The decarboxylative C–O bond... 
MILD | ACETOXYLATION | DIAMINATION | DECOMPOSITION | CHEMISTRY, ORGANIC | ALPHA-AMINO-ACIDS | IONS | GENERATION | REARRANGEMENTS | EFFICIENT METHOD | LEAD
Journal Article
Organic Letters, ISSN 1523-7060, 12/2017, Volume 19, Issue 23, pp. 6280 - 6283
The direct Pd-catalyzed ortho C–H hydroxylation of benzaldehydes was achieved using 4-chloroanthranilic acid as the transient directing group,... 
ACTIVATION | ACETOXYLATION | OXIDATIVE FUNCTIONALIZATION | AMINES | OXYGENATIONS | AMIDATION | CHEMISTRY, ORGANIC | ALDEHYDES | LIGAND | C(SP)-H ARYLATION | C(SP)-H BOND HYDROXYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 08/2015, Volume 17, Issue 15, pp. 3730 - 3733
A wide range of benzo[c]cinnolines are prepared through a sequential C-C and C-N bond formation by means of an oxidative C-H functionalization. The reaction... 
3,4-DISUBSTITUTED CINNOLINES | FACILE SYNTHESIS | ACETOXYLATION | STRATEGY | AZOBENZENES | ARYLATION | CHEMISTRY, ORGANIC | DERIVATIVES | EFFICIENT | CYCLIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 08/2013, Volume 15, Issue 16, pp. 4098 - 4101
Direct benzylation of carboxylic acids with toluene has been developed via palladium-catalyzed C–H acyloxylation under 1 atm of oxygen. This reaction... 
ACETOXYLATION | OXIDATIVE FUNCTIONALIZATION | COUPLING REACTIONS | PHI(OAC) | COMPLEXES | ESTERIFICATION | CHEMISTRY, ORGANIC | BOND FORMATION | LACTONIZATION | ALKYLBENZENES | CARBON-HYDROGEN
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 12/2018, Volume 2018, Issue 44, pp. 6088 - 6091
A palladium‐catalyzed γ‐C(sp3)–H acetoxylation of triflyl‐protected amines has been achieved. The use of pyridine or 2‐alkoxyquinoline‐type ligands is key to... 
Ligand design | C–H activation | Palladium | Amines | Acetoxylation | DIRECTING GROUP | C-H ACETOXYLATION | ACTIVATION | PD(II)-CATALYZED OLEFINATION | ACIDS | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | UNACTIVATED C(SP)-H | REDUCTIVE ELIMINATION | CATALYZED ARYLATION | C-H activation
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 2013, Volume 4, Issue 9, pp. 3712 - 3716
Selective cyclization and substitution was achieved with designated 1,2,3-triazole acid auxiliary groups under Pd catalyzed C-H activation conditions. Both... 
FUNCTIONALIZATION | C(SP)-H BONDS | PALLADIUM | ACETOXYLATION | ALKYLATION | UNACTIVATED C(SP)-H | ORTHO-C(SP)-H BONDS | FORMING REDUCTIVE ELIMINATION | CATALYZED DIRECT ARYLATIONS | CHEMISTRY, MULTIDISCIPLINARY | ARYL CHLORIDES
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2017, Volume 53, Issue 64, pp. 9004 - 9007
A rapid, mild and metal-free intermolecular cyclopropanation between iodonium ylides and alkene-containing substrates mediated by PhI(OAc)(2)center dot Bu4NI... 
STYRENES | REAGENTS | ALPHA-ACETOXYLATION | PHENYLIODONIUM YLIDE | CHEMISTRY | IODINE | GENERATION | 1,1-CYCLOPROPANE DIESTERS | SALTS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2011, Volume 52, Issue 45, pp. 5926 - 5929
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2014, Volume 356, Issue 7, pp. 1544 - 1548
We report a new protocol for palladium‐catalyzed acetoxylation of the γ‐C(sp3)H bonds of N‐alkylpicolinamide substrates using PhI(OAc)2 oxidant. These... 
palladium | picolinamides | CH acetoxylation | C-H acetoxylation | C(SP)-H BONDS | ACID DERIVATIVES | ACTIVATION | NATURAL-PRODUCTS | CHEMISTRY, ORGANIC | ORTHO-C(SP)-H BONDS | CARBON-HYDROGEN BONDS | C-H BONDS | FUNCTIONALIZATION | COUPLING REACTIONS | CHEMISTRY, APPLIED
Journal Article
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