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aerobic dialkoxylation (28) 28
chemistry, organic (17) 17
catalysis (14) 14
index medicus (11) 11
chemistry, multidisciplinary (10) 10
chemical properties (9) 9
olefins (9) 9
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molecular structure (5) 5
stereoisomerism (5) 5
stereoselective-synthesis (5) 5
aminoacetoxylation (4) 4
asymmetric diamination (4) 4
carboamination (4) 4
complexes (4) 4
diamination (4) 4
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2-allylphenols (3) 3
allylic alcohols (3) 3
organic chemistry (3) 3
organic-synthesis (3) 3
oxidation (3) 3
quinone (3) 3
structure (3) 3
terminal olefins (3) 3
1,3-dienes (2) 2
[ chim.orga ] chemical sciences/organic chemistry (2) 2
activation (2) 2
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heck reaction (2) 2
heterocycles (2) 2
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hydrogen-peroxide (2) 2
indolequinones - chemistry (2) 2
letter (2) 2
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1,3-diene synthesis (1) 1
1,6-addition (1) 1
1,6‐addition (1) 1
1st total-synthesis (1) 1
2+2+2 cyclization (1) 1
2-alkoxytetrahydrofurans (1) 1
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7-cyano-7-ethoxycarbonyl-1,4-benzoquinone methide (1) 1
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Organic Letters, ISSN 1523-7060, 12/2015, Volume 17, Issue 24, pp. 6058 - 6061
The first catalytic asymmetric intermolecular alcohol conjugate addition to o-quinone methides (o-QMs) is disclosed. Due to reversible C–O bond formation and... 
BRONSTED ACID | DIRECTING GROUP | CATALYSIS | ACTIVATION | OXY-MICHAEL ADDITION | ENANTIOSELECTIVE SYNTHESIS | DIASTEREOSELECTIVE SYNTHESIS | AEROBIC DIALKOXYLATION | CHEMISTRY, ORGANIC | IN-SITU | CONJUGATE ADDITION
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2008, Volume 6, Issue 22, pp. 4083 - 4088
Alkene difunctionalization, the addition of two functional groups across a double bond, exemplifies a class of reactions with significant synthetic potential.... 
AEROBIC DIALKOXYLATION | ALLYLIC ALCOHOLS | ASYMMETRIC DIAMINATION | 2-ALKOXYTETRAHYDROFURANS | CONJUGATED DIENES | CHEMISTRY, ORGANIC | O BOND FORMATION | TERMINAL OLEFINS | C-H ACTIVATION | CYCLIZATION | VINYL ETHERS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2011, Volume 76, Issue 22, pp. 9210 - 9215
Journal Article
ChemCatChem, ISSN 1867-3880, 05/2015, Volume 7, Issue 10, pp. 1524 - 1526
A new sheriff in town:­ para‐Quinone methides (p‐QMs) have been successfully used in asymmetric organocatalysis. Particularly, the asymmetric 1,6‐addition of... 
organocatalysis | quinone methide | 1,6‐addition | asymmetric catalysis | reaction intermediate | Reaction intermediate | Quinone methide | Asymmetric catalysis | Organocatalysis | 1,6-addition | ANNULATIONS | STYRENES | PHENOL | AEROBIC DIALKOXYLATION | ALKYLATION | CHEMISTRY, PHYSICAL | ACTIVATION STRATEGY | BIOSYNTHESIS | 6-addition | Quinone | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2007, Volume 129, Issue 47, pp. 14542 - 14543
The sequential transfer of two sulfonamides to internal alkenes affords the construction of vicinal diamines. In the presence of a palladium catalyst, the... 
HETEROCYCLES | AEROBIC DIALKOXYLATION | CONJUGATED DIENES | COMPLEXES | DIAMINATION | REACTIVITY | AMINOACETOXYLATION | OLEFINS | CIS-AMINOPALLADATION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | Palladium catalysts | Usage | Chemical properties | Structure | Heterocyclic compounds | Olefins
Journal Article
Organic Letters, ISSN 1523-7060, 06/2018, Volume 20, Issue 12, pp. 3601 - 3604
A new catalyst-free protocol for aminomethylamination of o-hydroxystyrenes with simple aminals is described. This direct and operationally simple method... 
DIFUNCTIONALIZATION | FUNCTIONALIZATION | CYCLOADDITION | ASYMMETRIC-SYNTHESIS | HYDROGENATION | ENANTIOSELECTIVE SYNTHESIS | AEROBIC DIALKOXYLATION | N BOND ACTIVATION | CHEMISTRY, ORGANIC | AMINOALKENES | POVAROV REACTION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2013, Volume 135, Issue 49, pp. 18327 - 18330
A new strategy was developed for intercepting the palladium–alkyl species generated in Heck reaction via nucleophilic addition prior to the step of migratory... 
ALKENES | C-O | AEROBIC DIALKOXYLATION | MIGRATORY INSERTION | ARYLATION | DIAMINATION | OLEFINS | N BOND FORMATION | ARYL | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | Alcohols - chemistry | Ethers - chemistry | Animals | Catalysis | Acetals - chemistry | Palladium - chemistry | Palladium catalysts | Chemical properties | Research | Organic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2009, Volume 131, Issue 11, pp. 3846 - 3847
A new palladium-catalyzed diacetoxylation of alkenes using oxygen as the sole oxidant to afford diacetates was developed. High levels of diastereoselectivity... 
OXIDATIVE CARBONYLATION | O BOND | AEROBIC DIALKOXYLATION | ELECTRON-WITHDRAWING GROUPS | ASYMMETRIC DIHYDROXYLATION | CONJUGATED DIENES | STEREOCHEMISTRY | AMINOACETOXYLATION | CIS-DIHYDROXYLATION | OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | Palladium catalysts | Oxidation-reduction reaction | Chemical properties | Olefins | Analysis
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 08/2013, Volume 355, Issue 11‐12, pp. 2222 - 2226
Journal Article
Organic Letters, ISSN 1523-7060, 05/2015, Volume 17, Issue 10, pp. 2558 - 2561
Doubly intermolecular alkene diamination is achieved with electron;rich, terminal alkenes through the use of a hypervalent iodine (PhI(OAc)(2)) reagent,... 
DIFUNCTIONALIZATION | INTRAMOLECULAR DIAMINATION | AEROBIC DIALKOXYLATION | ASYMMETRIC DIAMINATION | AMIDE | CHEMISTRY, ORGANIC | METAL-FREE DIAMINATION | PALLADIUM-CATALYZED DIAMINATION | IODINE(III) REAGENTS | VICINAL DIAMINATION | AMINOHYDROXYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2010, Volume 132, Issue 18, pp. 6284 - 6285
This paper describes a palladium-catalyzed oxime assisted intramolecular dioxygenation of alkenes by using 1 atm of air as the sole oxidant under extremely... 
TURNOVER | CARBON | ACID | AEROBIC DIALKOXYLATION | CONJUGATED DIENES | AMINOACETOXYLATION | C-H OXIDATION | BOND FORMATION | CIS-AMINOPALLADATION | CHEMISTRY, MULTIDISCIPLINARY | MOLECULAR-OXYGEN | Palladium catalysts | Oxidation-reduction reaction | Chemical properties | Olefins | Analysis
Journal Article
Organic Letters, ISSN 1523-7060, 08/2016, Volume 18, Issue 15, pp. 3698 - 3701
A four-step total synthesis of paeoveitol (1), a recently disclosed norditerpene natural product from Paeonia vetchii, is reported. This highly concise... 
ORGANIC-SYNTHESIS | ORTHO-QUINONE METHIDES | AEROBIC DIALKOXYLATION | STEREOCONTROLLED TOTAL-SYNTHESIS | CHEMISTRY, ORGANIC | ENDIANDRIC ACID CASCADE | BIOMIMETIC APPROACH | PAEONIA-VEITCHII | MONOTERPENE GLYCOSIDES | PAEONIFLORIN | ELECTROCYCLIZATIONS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2011, Volume 133, Issue 15, pp. 5784 - 5787
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2009, Volume 131, Issue 47, pp. 17074 - 17075
Journal Article
Organic Letters, ISSN 1523-7060, 08/2012, Volume 14, Issue 16, pp. 4074 - 4077
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2012, Volume 51, Issue 23, pp. 5696 - 5700
Journal Article
Journal Article
Organic Letters, ISSN 1523-7060, 04/2013, Volume 15, Issue 8, pp. 1838 - 1841
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 06/2010, Volume 12, Issue 12, pp. 2848 - 2851
Evaluation of the scope of a Pd-II-catalyzed oxidative 1,1-diarylation reaction of terminal olefins using aryl stannanes is reported. The reaction is shown to... 
ALCOHOL OXIDATION | AEROBIC DIALKOXYLATION | ALLYLIC ALCOHOLS | ASYMMETRIC DIAMINATION | CONJUGATED DIENES | PD(II) CATALYSIS | CHEMISTRY, ORGANIC | PALLADIUM CATALYST | O BOND FORMATION | HECK REACTION | C-H ACTIVATION
Journal Article
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