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European Journal of Organic Chemistry, ISSN 1434-193X, 10/2017, Volume 2017, Issue 39, pp. 5821 - 5851
Direct difunctionalization of simple alkenes, the incorporation of two functional groups onto a carbon–carbon double bond, is of particular interest to the... 
Alkenes | Difunctionalization | Reaction mechanisms | Intramolecular | Radicals | Intermolecular | ROOM-TEMPERATURE | ACTIVATED ALKENES | COPPER-CATALYZED TRIFLUOROMETHYLATION | CARBONYL ALKYL BROMIDES | BETA-KETOSULFONES | CHEMISTRY, ORGANIC | KORNBLUM-DELAMARE REARRANGEMENT | C-H BONDS | METAL-FREE | AEROBIC OXYSULFONYLATION | UNACTIVATED ALKENES | Olefins
Journal Article
Synthesis, ISSN 0039-7881, 12/2019, Volume 51, Issue 24, pp. 4507 - 4530
Journal Article
RSC Advances, 12/2014, Volume 5, Issue 6, pp. 4416 - 4419
A simple and convenient approach for the construction of beta -iodovinyl sulfones has been developed via direct difunctionalization of alkynes with sulfinic... 
Construction | Additives | Catalysts | Sulfones | Alkynes | Iodine
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2016, Volume 22, Issue 41, pp. 14489 - 14493
Difunctionalization of activated alkenes, a powerful strategy in chemical synthesis, has been accomplished for direct synthesis of a series of β‐keto sulfides... 
aerobic oxidation | alkenes | ketones | water | sulfides | Sulfides | Synthesis (chemistry) | Purification | Alkenes | Catalysts | Strategy | Transformations | Sulfones
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2008, Volume 6, Issue 22, pp. 4083 - 4088
Alkene difunctionalization, the addition of two functional groups across a double bond, exemplifies a class of reactions with significant synthetic potential.... 
AEROBIC DIALKOXYLATION | ALLYLIC ALCOHOLS | ASYMMETRIC DIAMINATION | 2-ALKOXYTETRAHYDROFURANS | CONJUGATED DIENES | CHEMISTRY, ORGANIC | O BOND FORMATION | TERMINAL OLEFINS | C-H ACTIVATION | CYCLIZATION | VINYL ETHERS
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 10/2014, Volume 12, Issue 39, pp. 7678 - 7681
A novel iron-catalyzed direct difunctionalization of alkenes with sulfinic acids and dioxygen for the synthesis of beta-ketosulfones has been developed under... 
AEROBIC DIFUNCTIONALIZATION | SULFONYLHYDRAZIDES | ARYLSULFONYLATION | CHEMISTRY, ORGANIC | SINGLET OXYGEN | GENERATION | OXYSULFONYLATION | RADICAL-ADDITION | KETO SULFONES | DERIVATIVES | ALLYLIC SULFONYLATION
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 10/2014, Volume 12, Issue 39, pp. 7678 - 7681
A novel iron-catalyzed direct difunctionalization of alkenes with sulfinic acids and dioxygen for the synthesis of β-ketosulfones has been developed under mild... 
Alkenes - chemistry | Green Chemistry Technology | Sulfones - chemistry | Iron - chemistry | Oxygen - chemistry | Sulfinic Acids - chemistry | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2012, Volume 51, Issue 28, pp. 7031 - 7034
Internal affairs: The first general palladium‐catalyzed intermolecular diamination of internal alkenes employs different nitrogen sources, which add to the... 
oxidation | palladium | amination | homogeneous catalysis | alkenes | ORGANIC-SYNTHESIS | STYRENES | AEROBIC OXIDATIVE AMINATION | ASYMMETRIC CHLOROHYDRIN SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | ALCOHOLS | HYDROGEN-TRANSFER | DIAMINATION | OLEFINS | AMINOHYDROXYLATION | Diamines | Ligands | Synthesis | Alkenes
Journal Article
by Sun, Z and Ji, HH and Shao, Y and He, KX and Zhang, YX and Yuan, Y and Jia, XD
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 10/2019, Volume 84, Issue 19, pp. 12292 - 12300
Difunctionalization of the saturated C-N bond of 1,2,3,4-tetrahydroisoquinolines and N,N'-diarylimidazolidines was achieved using TBN as the metal-free... 
ALKENES | PRIMARY ALLYLIC AMINES | AMINALS | STRATEGY | RING-OPENING REACTIONS | ARENES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | INDOLE SYNTHESIS | AEROBIC OXYNITRATION | NITRATION
Journal Article
RSC Advances, ISSN 2046-2069, 2015, Volume 5, Issue 6, pp. 4416 - 4419
simple and convenient approach for the construction of beta-iodovinyl sulfones has been developed via direct difunctionalization of alkynes with sulfinic acids... 
BETA-IODOVINYL SULFONES | AEROBIC DIFUNCTIONALIZATION | ALKENES | VINYL SULFONES | CHLORIDES | SULFONYLHYDRAZIDES | TERMINAL ALKYNES | STEREOSELECTIVE-SYNTHESIS | INHIBITORS | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2009, Volume 48, Issue 17, pp. 3146 - 3149
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2017, Volume 23, Issue 40, pp. 9477 - 9480
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 10/2016, Volume 22, Issue 41, pp. 14489 - 14493
Difunctionalization of activated alkenes, a powerful strategy in chemical synthesis, has been accomplished for direct synthesis of a series of -keto sulfides... 
DIOXYGEN ACTIVATION | OXIDATION | ORGANIC-SYNTHESIS | TERMINAL ALKYNES | aerobic oxidation | alkenes | ketones | water | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | METAL-FREE SYNTHESIS | SULFOXIDES | BOND | DERIVATIVES | sulfides | MOLECULAR-OXYGEN | Sulfides | Ketones | Olefins | Organosulfur compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2013, Volume 135, Issue 49, pp. 18327 - 18330
A new strategy was developed for intercepting the palladium–alkyl species generated in Heck reaction via nucleophilic addition prior to the step of migratory... 
ALKENES | C-O | AEROBIC DIALKOXYLATION | MIGRATORY INSERTION | ARYLATION | DIAMINATION | OLEFINS | N BOND FORMATION | ARYL | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | Alcohols - chemistry | Ethers - chemistry | Animals | Catalysis | Acetals - chemistry | Palladium - chemistry | Palladium catalysts | Chemical properties | Research | Organic compounds
Journal Article
by Yang, H and Wei, G and Jiang, ZY
ACS CATALYSIS, ISSN 2155-5435, 10/2019, Volume 9, Issue 10, pp. 9599 - 9599
An access to isoxazolidines featuring visible-light induced aerobic difunctionalization of alkenes is reported. alpha-Amino radicals generated via oxidative... 
FUNCTIONALIZATION | NITRONES | isoxazolidines | ARYLATION | alkene difunctionalization | CHEMISTRY, PHYSICAL | photoredox catalysis | glycines | aerobic | 1,3-DIPOLAR CYCLOADDITION REACTIONS
Journal Article
Green Chemistry, ISSN 1463-9262, 2015, Volume 17, Issue 6, pp. 3515 - 3520
The visible-light-induced straightforward synthesis of 5-aryl-2-imino-1,3-oxathiolanes from styrenes and ammonium thiocyanate is reported. The protocol... 
Journal Article
Green Chemistry, ISSN 1463-9262, 06/2015, Volume 17, Issue 6, pp. 3515 - 3520
The visible-light-induced straightforward synthesis of 5-aryl-2-imino-1,3-oxathiolanes from styrenes and ammonium thiocyanate is reported. The protocol... 
OXIDATION | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | CONVERSION | OXYGENATION | EOSIN Y | PHOTOCATALYSIS | SYNTHETIC APPLICATIONS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | AEROBIC OXYSULFONYLATION | METAL-FREE | PHOTOREDOX CATALYSIS | Thiocyanates | Formations | Synthesis | Catalysts | Styrenes | Reagents
Journal Article