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chemistry, organic (119) 119
chemistry, multidisciplinary (109) 109
catalysis (106) 106
aerobic oxidation (99) 99
aerobic oxidative amination (85) 85
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palladium (65) 65
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1. Full Text Synthesis of Quinazolinones, Imidazo[1,2‐c]quinazolines and Imidazo[4,5‐c]quinolines through Tandem Reductive Amination of Aryl Halides and Oxidative Amination of C(sp3)–H Bonds
by Nandwana, Nitesh Kumar and Dhiman, Shiv and Saini, Hitesh Kumar and Kumar, Indresh and Kumar, Anil
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2017, Volume 2017, Issue 3, pp. 514 - 522
A tandem multicomponent approach has been described for the synthesis of quinazolinones, imidazo[1,2‐c]quinazolines and imidazo[4,5‐c]quinolines. The reaction... 
Fused‐ring systems | Synthetic methods | Multicomponent reactions | Nitrogen heterocycles | Copper | Homogeneous catalysis | Fused-ring systems | SODIUM-AZIDE | CASCADE REACTIONS | ONE-POT | CHEMISTRY, ORGANIC | DIRECT AEROBIC CARBONYLATION | METHYLENE SOURCE | ALPHA-METHYLATION | CARBON SOURCE | SYNERGISTIC CATALYSIS | DIMETHYL-SULFOXIDE | FUSED QUINAZOLINES | Cytokinins
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2. Full Text Dioxygen-Coupled Oxidative Amination of Styrene
by Timokhin, Vitaliy I and Anastasi, Natia R and Stahl, Shannon S
Journal of the American Chemical Society, ISSN 0002-7863, 10/2003, Volume 125, Issue 43, pp. 12996 - 12997
Dioxygen-coupled oxidative amination of olefins is an attractive, but challenging, catalytic transformation. The present work describes the first general... 
ALCOHOLS | CATALYSIS | INSERTION | PALLADIUM(II)-CATALYZED CYCLIZATION | ACRYLONITRILE | VINYLARENES | AEROBIC OXIDATION | OLEFINS | HYDROAMINATION | CHEMISTRY, MULTIDISCIPLINARY | MOLECULAR-OXYGEN | Alkenes - chemistry | Styrene - chemistry | Amines - chemical synthesis | Amination | Oxidation-Reduction | Oxygen - chemistry | Oxidation-reduction reaction | Usage | Research | Styrene
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3. Full Text Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications
by Park, Yoonsu and Kim, Youyoung and Chang, Sukbok
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9247 - 9301
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient synthetic approach to construct N-functionalized molecules. Over... 
INTRAMOLECULAR C(SP)-H AMINATION | NITROGEN-CONTAINING HETEROCYCLES | UNACTIVATED C(SP)-H BONDS | AEROBIC OXIDATIVE AMINATION | VISIBLE-LIGHT PHOTOREDOX | O-BENZOYL-HYDROXYLAMINES | NITRENE TRANSFER-REACTIONS | BENZYLIC METHYLENE GROUPS | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | N BOND-FORMATION
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4. Full Text Copper(II)‐Catalyzed Aerobic Oxidative Coupling between Chalcone and 2‐Aminopyridine via CH Amination: An Expedient Synthesis of 3‐Aroylimidazo[1,2‐a]pyridines
by Monir, Kamarul and Kumar Bagdi, Avik and Mishra, Subhajit and Majee, Adinath and Hajra, Alakananda
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2014, Volume 356, Issue 5, pp. 1105 - 1112
A simple and efficient protocol has been developed for the synthesis of 3‐aroylimidazopyridines via copper(II) acetate‐catalyzed aerobic oxidative amination. A... 
chalcones | regioselectivity | 3‐aroylimidazo[1,2‐a]pyridines | copper(II) acetate | aerobic oxidative amination | 3-aroylimidazo[1,2-a]pyridines | Joining | Libraries | Synthesis | Catalysis | Accessibility | Methodology
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5. Full Text Palladium-Catalyzed Oxidative Amination of Alkenes:  Improved Catalyst Reoxidation Enables the Use of Alkene as the Limiting Reagent
by Rogers, Michelle M and Kotov, Vasily and Chatwichien, Jaruwan and Stahl, Shannon S
Organic Letters, ISSN 1523-7060, 10/2007, Volume 9, Issue 21, pp. 4331 - 4334
Palladium-catalyzed methods for intermolecular aerobic oxidative amination of alkenes have been identified that are compatible with the use of alkene as the... 
PYRROLIDINES | INTERMOLECULAR HYDROAMINATION | AZIRIDINATION | VINYLARENES | CHEMISTRY, ORGANIC | ANTI-MARKOVNIKOV HYDROAMINATION | AEROBIC OXIDATION | CIS-AMINOPALLADATION | CARBOAMINATION | PRECURSORS | HYDROHYDRAZINATION | Alkenes - chemistry | Combinatorial Chemistry Techniques | Amination | Oxidation-Reduction | Indicators and Reagents | Catalysis | Alkenes - chemical synthesis | Palladium - chemistry
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6. Full Text Copper-Catalyzed sp(3) C-H Amination
by Gephart, RT and Warren, TH
ORGANOMETALLICS, ISSN 0276-7333, 11/2012, Volume 31, Issue 22, pp. 7728 - 7752
Among the transition metals, copper based catalyst systems enable the widest range of N-containing reagents in C-H amination to allow for the direct... 
MECHANISTIC ASPECTS | NITRENE TRANSFER | INTERMOLECULAR AMINATION | AEROBIC OXIDATIVE AMINATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | ALLYLIC AMINATION | ALKENE AZIRIDINATION | N BOND FORMATION | ARYL AZIDES | CUPROUS CHLORIDE | CHEMISTRY, INORGANIC & NUCLEAR
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7. Full Text Recent advances in transition metal-catalyzed sp(3) C-H amination adjacent to double bonds and carbonyl groups
by Ramirez, TA and Zhao, BG and Shi, Y
CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2012, Volume 41, Issue 2, pp. 931 - 942
Transition metal-catalyzed C-H amination at positions adjacent to double bonds and carbonyl groups is discussed in this critical review. While the focus will... 
MECHANISTIC ASPECTS | ASSISTED INTRAMOLECULAR AMINATION | ASYMMETRIC-SYNTHESIS | AEROBIC OXIDATIVE AMINATION | NITROGEN-ATOM-TRANSFER | MANGANESE PORPHYRINS | CARBENE TRANSFORMATIONS | ALPHA-AMINO-ACIDS | ALLYLIC AMINATION | TERMINAL OLEFINS | CHEMISTRY, MULTIDISCIPLINARY
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8. Full Text Catalytic CH Amination with Aromatic Amines
by Gephart, Raymond T and Huang, Daria L and Aguila, Mae Joanne B and Schmidt, Graham and Shahu, Andi and Warren, Timothy H
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2012, Volume 51, Issue 26, pp. 6488 - 6492
Aniline joins the club: A β‐diketiminato copper(I) catalyst enables CH amination of anilines employing low catalyst loadings to preclude oxidation to the... 
copper | amination | anilines | CH functionalization | synthetic methods | C-H functionalization | INTERMOLECULAR AMINATION | AEROBIC OXIDATIVE AMINATION | COMPLEXES | ENANTIOSELECTIVE INTRAMOLECULAR AMIDATION | ALLYLIC AMINATION | CUPROUS CHLORIDE | CHEMISTRY, MULTIDISCIPLINARY | AZO-COMPOUNDS | BONDS | C?H functionalization | ARYL AZIDES | H AMINATION | Amines - chemistry | Amination | Oxidation-Reduction | Molecular Structure | Catalysis | Hydrogen - chemistry | Carbon - chemistry | Amines | Catalysts | Aniline | Formations | Oxidation | Clubs
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9. Full Text Iodine(III)-Mediated Intermolecular Allylic Amination under Metal-Free Conditions
by Souto, José A and Zian, Debora and Muñiz, Kilian
Journal of the American Chemical Society, ISSN 0002-7863, 05/2012, Volume 134, Issue 17, pp. 7242 - 7245
A new approach to direct intermolecular allylic amination has been developed using metal-free conditions at room temperature. The reaction employs a... 
FUNCTIONALIZATION | AEROBIC OXIDATIVE AMINATION | HYPERVALENT IODINE | POLYVALENT IODINE COMPOUNDS | MEDIATED AZIRIDINATION | AMBIENT-TEMPERATURE | N BOND FORMATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | TERMINAL ALKENES | Chemical bonds | Iodine compounds | Allylic compounds | Amines | Chemical properties | Analysis
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10. Full Text Diversification of a β-lactam pharmacophore via allylic C–H amination: accelerating effect of Lewis acid co-catalyst
by Qi, Xiangbing (Ben) and Rice, Grant T and Lall, Manjinder S and Plummer, Mark S and White, M. Christina
Tetrahedron, ISSN 0040-4020, 2010, Volume 66, Issue 26, pp. 4816 - 4826
This report describes the use of Pd(II)/bis-sulfoxide catalyzed intra- and intermolecular allylic C–H amination reactions to rapidly diversify structures... 
FUNCTIONALIZATION | ALCOHOLS | ALKENES | EPOXIDES | AEROBIC OXIDATIVE AMINATION | STRATEGY | CHEMISTRY, ORGANIC | OXYFUNCTIONALIZATION | HYDROCARBON OXIDATION | TERMINAL OLEFINS | SELECTIVITY
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11. Full Text Acid/Base‐Co‐catalyzed Direct Oxidative α‐Amination of Cyclic Ketones: Using Molecular Oxygen as the Oxidant
by Li, Yi‐Jin and Zhang, Lu and Yan, Na and Meng, Xiang‐He and Zhao, Yu‐Long
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2018, Volume 360, Issue 3, pp. 455 - 461
A novel acid/base‐co‐catalyzed direct intermolecular α‐amination of various cyclic ketones has been developed for the first time. The reaction employs... 
organocatalysis | cyclic ketones | dehydrogenation | aerobic oxidation | α-amination | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALDEHYDES | FUNCTIONALIZATION | alpha-amination | ASYMMETRIC AMINATION | COUPLING REACTIONS | AMINO-ACIDS | ALDOL REACTION | BONDS | H AMINATION | CHEMISTRY, APPLIED | DERIVATIVES
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12. Full Text Scope and Mechanism of Allylic C-H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)(2) Catalyst System: Insights into the Effect of Naphthoquinone
by Yin, GY and Wu, YC and Liu, GS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 09/2010, Volume 132, Issue 34, pp. 11978 - 11987
Palladium-catalyzed oxidative amination of unactivated alkyl olefins has been developed to produce linear (E)-allylimides with high regioselectivity. This... 
CROSS-COUPLING REACTIONS | STABLE ORGANOPALLADIUM(IV) COMPLEXES | AEROBIC OXIDATIVE AMINATION | AMBIENT-TEMPERATURE | N BOND FORMATION | DEFICIENT OLEFIN LIGAND | (PI-ALLYL)PALLADIUM INTERMEDIATE | REDUCTIVE ELIMINATION | NUCLEOPHILIC-ATTACK | CHEMISTRY, MULTIDISCIPLINARY | ARYL CHLORIDES | Palladium catalysts | Amines | Olefins | Analysis | Quinone | Chemical properties | Catalysis | Structure
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13. Full Text Copper( II)-Catalyzed Aerobic Oxidative Coupling between Chalcone and 2-Aminopyridine via C HAmination:AnExpedientSynthesis of 3-AroylimidazoACHTUNGTRENUNG[ 1,2-a] pyridines
by Monir, K and Bagdi, AK and Mishra, S and Majee, A and Hajra, A
ADVANCED SYNTHESIS & CATALYSIS, ISSN 1615-4150, 03/2014, Volume 356, Issue 5, pp. 1105 - 1112
A simple and efficient protocol has been developed for the synthesis of 3-aroylimidazopyridines via copper(II) acetate-catalyzed aerobic oxidative amination. A... 
chalcones | regioselectivity | ANTIVIRAL AGENTS | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | copper(II) acetate | CATALYZED DIRECT AMINATION | 2-a]pyridines | BETA-KETO-ESTERS | DIRECT ACCESS | SINGLE-ELECTRON | aerobic oxidative amination | FUNCTIONALIZATION | H ACTIVATION REACTIONS | 3-aroylimidazo | N BOND FORMATION | CHEMISTRY, APPLIED
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14. Full Text Palladium-catalyzed allylic C-H amination of alkenes with N-fluorodibenzenesulfonimide: Water plays an important role
by Xiong, Tao and Li, Yan and Mao, Lujia and Zhang, Qian
Chemical Communications, ISSN 1359-7345, 02/2012, Volume 48, Issue 16, pp. 2246 - 2248
A new palladium-catalyzed highly regioselective allylic C-H amination of alkenes with NFSI in the presence of a catalytic amount of water was developed and... 
ACTIVATION | AEROBIC OXIDATIVE AMINATION | MECHANISM | COMPLEXES | AMIDATION | AMINOACETOXYLATION | BOND FORMATION | CARBAZOLES | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | Alkenes - chemistry | Amination | Sulfonamides - chemistry | Allyl Compounds - chemistry | Water - chemistry | Catalysis | Palladium - chemistry | Alkenes | Catalysts
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15. Full Text Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications
by McDonald, Richard I and Liu, Guosheng and Stahl, Shannon S
Chemical Reviews, ISSN 0009-2665, 04/2011, Volume 111, Issue 4, pp. 2981 - 3019
AEROBIC ALCOHOL OXIDATIONS | PALLADIUM-PROMOTED AMINATION | N-HETEROCYCLIC CARBENE | HECK-TYPE REACTION | WACKER-TYPE CYCLIZATION | PYRIDINE-OXAZOLINE COMPLEXES | INTRAMOLECULAR OXIDATIVE AMINATION | ASYMMETRIC CHLOROHYDRIN SYNTHESIS | C-H ACTIVATION | PD(II)-SPIRO BIS(ISOXAZOLINE) CATALYST | CHEMISTRY, MULTIDISCIPLINARY | Alkenes - chemistry | Catalysis | Stereoisomerism | Palladium - chemistry | Analysis | Palladium | Chemical properties | Ring formation (Chemistry) | Structure | Alcohols
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16. Full Text Pd(II)-Catalyzed Allylic C–H Amination for the Preparation of 1,2- and 1,3-Cyclic Ureas
by Nishikawa, Yasuhiro and Kimura, Seikou and Kato, Yuri and Yamazaki, Natsuka and Hara, Osamu
Organic Letters, ISSN 1523-7060, 02/2015, Volume 17, Issue 4, pp. 888 - 891
A general synthesis of 1,2- and 1,3-cyclic ureas is accomplished by intramolecular allylic C–H amination employing Pd(TFA)2/bis-sulfoxide as a catalyst. By... 
CHEMOSELECTIVE AMINATION | ALKENES | DESIGN | AEROBIC OXIDATIVE AMINATION | STRATEGY | DIAMINATION | CHEMISTRY, ORGANIC | OLEFINS | DERIVATIVES | METABOLITE | CYCLIZATION | Amination | Stereoisomerism | Urea - analogs & derivatives | Molecular Structure | Catalysis | Urea - chemical synthesis | Palladium - chemistry | Urea - chemistry
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17. Full Text Regioselective Metal-Free Aza-Heck Reactions of Terminal Alkenes Catalyzed by Phosphine Selenides
by Zheng, Tianyi and Tabor, John R and Stein, Zackary L and Michael, Forrest E
Organic Letters, ISSN 1523-7060, 11/2018, Volume 20, Issue 21, pp. 6975 - 6978
Phosphine selenides are introduced as an alternate class of selenium-based catalysts for the aza-Heck reaction of alkenes. Using these catalysts, a range of... 
PALLADIUM | AEROBIC OXIDATIVE AMINATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | OLEFINS | C-H AMINATION | UNACTIVATED ALKENES
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18. Full Text Pd(0)-Catalyzed Sequential C–N Bond Formation via Allylic and Aromatic C–H Amination of α‑Methylstyrenes with Diaziridinone
by Ramirez, Thomas A and Wang, Qian and Zhu, Yingguang and Zheng, Huaiji and Peng, Xingao and Cornwall, Richard G and Shi, Yian
Organic Letters, ISSN 1523-7060, 08/2013, Volume 15, Issue 16, pp. 4210 - 4213
A novel Pd(0)-catalyzed sequential C–N bond formation process via allylic and aromatic C–H amination of α-methylstyrenes with di-tert-butyldiaziridinone,... 
PALLADIUM | ACTIVATION | ASYMMETRIC-SYNTHESIS | CARBON | AEROBIC OXIDATIVE AMINATION | DIAMINATION | REACTIVITY | AMIDATION | CHEMISTRY, ORGANIC | TERMINAL ALKENES | PD(II)-CATALYZED AMINATION | Styrenes - chemistry | Amination | Hydrogen Bonding | Indoles - chemical synthesis | Molecular Structure | Catalysis | Aziridines - chemistry | Indoles - chemistry | Palladium - chemistry
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19. Full Text Synthesis of imidazo[1,5-a]pyridines via I-2-mediated sp(3) C-H amination
by Hu, ZY and Hou, J and Liu, J and Yu, WQ and Chang, JB
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 08/2018, Volume 16, Issue 31, pp. 5653 - 5660
A transition-metal-free sp(3) C-H amination reaction has been established for imidazo[1,5-a] pyridine synthesis employing molecular iodine from 2-pyridyl... 
C(SP)-H BONDS | PYRIDOTRIAZOLES | AEROBIC OXIDATIVE AMINATION | ONE-POT SYNTHESIS | AMINO-ACIDS | LARGE STOKES SHIFT | CHEMISTRY, ORGANIC | METAL-ORGANIC FRAMEWORK | CATALYZED DENITROGENATIVE TRANSANNULATION | FLUORESCENT-PROBE | LIVING CELLS
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20. Full Text Electrocatalytic Minisci Acylation Reaction of N‑Heteroarenes Mediated by NH4I
by Wang, Qing-Qing and Xu, Kun and Jiang, Yang-Ye and Liu, Yong-Guo and Sun, Bao-Guo and Zeng, Cheng-Chu
Organic Letters, ISSN 1523-7060, 10/2017, Volume 19, Issue 20, pp. 5517 - 5520
An electrochemical C–H acylation of electron-deficient N-heteroarenes with α-keto acids is reported. This first electrochemical Minisci acylation reaction... 
SODIUM SULFINATES SYNTHESIS | ACIDS | HOMOLYTIC ACYLATION | CHEMISTRY, ORGANIC | AEROBIC OXIDATION | IODINE | IONIC LIQUID | METAL | C-H FUNCTIONALIZATION | OXIDATIVE AMINATION | ORGANIC ELECTROSYNTHESIS
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