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aldimines (594) 594
chemistry, organic (586) 586
chemistry, multidisciplinary (293) 293
imines (259) 259
aldehydes (225) 225
catalysis (180) 180
derivatives (180) 180
amines (130) 130
asymmetric-synthesis (124) 124
index medicus (116) 116
n-sulfonyl aldimines (115) 115
aldimine (110) 110
chemistry, inorganic & nuclear (90) 90
chemistry (77) 77
ketones (77) 77
schiff bases (74) 74
complexes (72) 72
synthesis (69) 69
molecular structure (68) 68
reagents (68) 68
stereoisomerism (67) 67
enantioselective synthesis (63) 63
catalysts (61) 61
activation (56) 56
alkylation (56) 56
alcohols (55) 55
esters (55) 55
cyclization (54) 54
carbonyl-compounds (53) 53
imines - chemistry (53) 53
ligands (53) 53
allylation (52) 52
chemical properties (50) 50
acids (49) 49
analysis (49) 49
organic-synthesis (49) 49
chemistry, physical (48) 48
conjugate addition (48) 48
efficient (45) 45
asymmetric catalysis (44) 44
organometallic reagents (43) 43
letter (40) 40
stereoselective-synthesis (40) 40
biochemistry & molecular biology (38) 38
c-h bond (38) 38
chemistry, applied (38) 38
enantiomers (38) 38
arylboronic acids (37) 37
efficient synthesis (37) 37
organic chemistry (36) 36
acid (35) 35
functionalization (35) 35
water (35) 35
cycloaddition (33) 33
ketimines (33) 33
additions (32) 32
enantioselective addition (31) 31
mannich reaction (31) 31
one-pot synthesis (31) 31
oxidation (31) 31
sulfonyl aldimines (31) 31
arylation (30) 30
inhibitors (30) 30
organocatalysis (30) 30
aqueous-media (29) 29
asymmetric synthesis (29) 29
research (29) 29
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azaarenes (27) 27
c-h functionalization (27) 27
catalyst (27) 27
heterocycles (27) 27
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amides (25) 25
friedel-crafts reaction (25) 25
tetrahedrons (25) 25
zinc (25) 25
2-methyl azaarenes (24) 24
facile synthesis (24) 24
indoles (24) 24
ketoimines (24) 24
rhodium (24) 24
aldimine zinc-complexes (23) 23
alkaloids (23) 23
diels-alder reactions (23) 23
imine (23) 23
michael addition (23) 23
nucleophilic-addition (23) 23
palladium (23) 23
reactivity (23) 23
structure (23) 23
amines - chemistry (22) 22
ligand (22) 22
mannich-type reaction (22) 22
models, molecular (22) 22
alpha,beta-unsaturated aldimine (21) 21
alpha-amino-acids (21) 21
asymmetry (21) 21
condensation (21) 21
construction (21) 21
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Angewandte Chemie - International Edition, ISSN 1433-7851, 02/2011, Volume 50, Issue 9, pp. 2115 - 2119
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2019, Volume 25, Issue 40, pp. 9415 - 9418
The selective addition of organomagnesium reagents to 2,4,6‐trichlorophenyl isocyanide leading to magnesiated aldimines is reported. These aldimines react with... 
organomagnesium halides | Weinreb amides | magnesium aldimines | isocyanides | 1,2-diketones | REAGENTS | LITHIUM ALDIMINES | DIRECT INSERTION | CHEMISTRY, MULTIDISCIPLINARY | ZINC | LICL-MEDIATED PREPARATION | MULTICOMPONENT REACTIONS | METALLO ALDIMINES | ARYL | Amides | Carbonates | Ketones | Halides | Carbonyl compounds | Synthesis | Reagents | Magnesium | Derivatives | Carbonyls
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2012, Volume 48, Issue 31, pp. 3769 - 3771
Organocatalytic nucleophilic pinacolboryl addition from in situ generated MeO- -> B(2)pin(2) to C=N double bond can be performed enantioselectively with the... 
ALCOHOLS | ACTIVATION | ALDIMINES | BASES | INHIBITORS | DIBORATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2008, Volume 14, Issue 16, pp. 4796 - 4798
The first catalytic asymmetric three‐component allylation of aldimines has been developed. In the presence of L‐ramipril acid‐oriented N,N′‐dioxide–ScIII... 
amines | aldimines | asymmetric catalysis | allylation | Amines | Aldimines | Asymmetric catalysis | Allylation
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 8, pp. 1918 - 1922
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 05/2013, Volume 49, Issue 39, pp. 4421 - 4423
We report the first catalytic asymmetric cyanation of N-Boc ketoimines, which enables highly enantioselective synthesis of oxindole based α-amino nitriles. An... 
Journal Article
Chemical Communications, ISSN 1359-7345, 05/2013, Volume 49, Issue 39, pp. 4421 - 4423
We report the first catalytic asymmetric cyanation of N-Boc ketoimines, which enables highly enantioselective synthesis of oxindole based alpha-amino nitriles.... 
ALPHA-AMINATION | ALDIMINES | 2,2'-BIPHENOL | ACTIVATION | WITTIG REACTION | CATALYST | KETIMINES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE STRECKER REACTION | MICHAEL ADDITION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2007, Volume 129, Issue 17, pp. 5336 - 5337
A new type of C 2-symmetric chiral diene ligand bearing a simple bicyclic [3.3.0] backbone was discovered. (3aS,6aS)-3,6-diphenyl-1,3a,4,6a-tetrahydropentalene... 
HIGH-PERFORMANCE | ISOINDOLINONES | ALDIMINES | ASYMMETRIC 1,4-ADDITION | KINETIC RESOLUTION | OLEFINS | RHODIUM COMPLEXES | ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2014, Volume 16, Issue 12, pp. 3396 - 3399
A copper-catalyzed free-radical cascade cyclization of isocyanides with simple alkanes and alcohols was developed, which allowed convenient access to various... 
PHENANTHRIDINE DERIVATIVES | ONE-POT SYNTHESIS | HETEROCYCLE SYNTHESIS | TRANSITION-METAL | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | UNACTIVATED C(SP)-H | N-SULFONYL ALDIMINES | OXIDATIVE CYCLIZATION | CATALYZED DIRECT ALKENYLATION | C-H BONDS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 08/2017, Volume 82, Issue 16, pp. 8752 - 8760
Asymmetric addition of indoles to cyclic α-diaryl-substituted N-acyl imines, which are generated in situ from 3-aryl 3-hydroxy­isoindolinones, is described.... 
PHOSPHORIC-ACID | AMINO-ACIDS | ALKYLATION | COMPLEXES | 3-ARYL-3-HYDROXYISOINDOLIN-1-ONES | CHEMISTRY, ORGANIC | 3-HYDROXYISOINDOLINONES | ASYMMETRIC ARYLATION | SULFONYL ALDIMINES | KETIMINES | DERIVATIVES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2017, Volume 2017, Issue 23, pp. 3373 - 3380
The reactivity of α‐nitro ketones with trifluoromethyl aldimines has been studied for the first time. Whereas under nitro‐Mannich conditions only the facial... 
Addition | Ketones | Nitro ketones | Stereoselctivity | Green chemistry | Aldimines | Organocatalysis | HYDRAZONES | IMINES | AZA-HENRY REACTIONS | CHEMISTRY, ORGANIC | ALDEHYDES | TRIFLUOROMETHYL ALDIMINES | SOLVENTLESS CONDITIONS | AMINO-ACID | DIARYLPROLINOL | STEREOSELECTIVE-SYNTHESIS | DERIVATIVES
Journal Article
Organic Letters, ISSN 1523-7060, 05/2016, Volume 18, Issue 10, pp. 2339 - 2342
A scandium-triflate-catalyzed arylative desulfonation of diarylmethyl phenyl sulfones with arenes and heteroarenes was established. A variety of both sulfone... 
UNSYMMETRICAL TRIARYLMETHANES | ALDIMINES | DESIGN | METHANES | SEQUENTIAL ARYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | FLUORESCEIN | DERIVATIVES | THIOPHENE | PROBES
Journal Article
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 14, pp. 3715 - 3718
The Pd-catalyzed desulfonative cross-coupling reaction of benzylic sulfone derivatives with 1,3-oxazoles via a deprotonative pathway has been developed. Broad... 
DIARYLMETHANES | HALIDES | UNSYMMETRICAL TRIARYLMETHANES | ALDIMINES | DIARYL | PHENYL SULFONE | SEQUENTIAL ARYLATION | ARENES | CHEMISTRY, ORGANIC | DIARYLMETHYLAMINES
Journal Article
Tetrahedron, ISSN 0040-4020, 01/2018, Volume 74, Issue 4, pp. 506 - 511
Stereoselective allylation of N-p-methoxyphenyl (PMP)-substituted α-hydroxy aldimines is described. Several Lewis acids (BF3·OEt2, SnCl4, TiCl4, ZnCl2, and... 
Vicinal amino alcohol | α-Hydroxy aldimines | Stereoselective allylation | (‒)-β-Conhydrine | ORGANIC-SYNTHESIS | ACIDS | NATURAL-PRODUCTS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | alpha-Hydroxy aldimines | (-)-beta-Conhydrine | GARNERS ALDEHYDE | KETONES | VICINAL AMINO-ALCOHOLS | ADDITION-REACTIONS | DIASTEREOSELECTIVE REDUCTION | CONCISE SYNTHESIS
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 15, pp. 2787 - 2791
Homoleptic lanthanide complexes coordinated by a Me-substituted Cp ligand [(MeCp)(3)Ln] demonstrate unprecedentedly high efficiency in catalyzing the... 
SELECTIVE HYDROBORATION | KETONES | ALDIMINES | ISOPRENE | EPSILON-CAPROLACTONE | REACTIVITY | CHEMISTRY, ORGANIC | STRUCTURAL-CHARACTERIZATION | ALDEHYDES | POLYMERIZATION | HYDRIDE
Journal Article
Organic Letters, ISSN 1523-7060, 04/2014, Volume 16, Issue 7, pp. 1972 - 1975
A highly selective N-sulfinylimidate aldolization has been developed under mildly basic conditions leading to diastereopure products of high synthetic... 
CHEMISTRY, ORGANIC | DERIVATIVES | ALDIMINES | Chemical Sciences
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 55, pp. 7764 - 7767
In this communication, a new photocatalytic strategy for the addition of alkyl-radical derivatives to N-sulfinimines with complete diastereo-selectivity and... 
ALCOHOLS | KETONES | ALDIMINES | CYCLIZATIONS | IMINES | NITROGEN | ALDEHYDES | ADDITIONS | BOND | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 07/2017, Volume 53, Issue 55, pp. 7764 - 7767
In this communication, a new photocatalytic strategy for the addition of alkyl-radical derivatives to N-sulfinimines with complete diastereoselectivity and... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2004, Volume 126, Issue 42, pp. 13584 - 13585
Asymmetric synthesis of diarylmethylamines with high enantioselectivity (95−99% ee) was realized by use of a new C 2-symmetric diene ligand,... 
ALDIMINES | CARBON BOND | KINETIC RESOLUTION | IMINES | 1,4-ADDITION | DIARYLMETHYLAMINES | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS
Journal Article
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