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aldimines (594) 594
chemistry, organic (581) 581
chemistry, multidisciplinary (295) 295
imines (259) 259
aldehydes (228) 228
catalysis (178) 178
derivatives (176) 176
amines (131) 131
asymmetric-synthesis (125) 125
index medicus (119) 119
n-sulfonyl aldimines (115) 115
aldimine (111) 111
chemistry, inorganic & nuclear (88) 88
chemistry (77) 77
ketones (76) 76
schiff bases (73) 73
complexes (71) 71
molecular structure (70) 70
synthesis (70) 70
reagents (67) 67
enantioselective synthesis (66) 66
stereoisomerism (66) 66
catalysts (62) 62
activation (58) 58
esters (56) 56
alkylation (55) 55
allylation (54) 54
carbonyl-compounds (53) 53
imines - chemistry (53) 53
ligands (53) 53
cyclization (52) 52
alcohols (51) 51
acids (48) 48
analysis (48) 48
chemical properties (48) 48
chemistry, physical (48) 48
efficient (48) 48
asymmetric catalysis (45) 45
conjugate addition (45) 45
organic-synthesis (44) 44
organometallic reagents (44) 44
chemistry, applied (40) 40
letter (40) 40
stereoselective-synthesis (40) 40
biochemistry & molecular biology (39) 39
c-h bond (38) 38
acid (37) 37
efficient synthesis (37) 37
enantiomers (37) 37
functionalization (36) 36
organic chemistry (36) 36
arylboronic acids (35) 35
ketimines (35) 35
cycloaddition (34) 34
water (34) 34
enantioselective addition (32) 32
arylation (31) 31
mannich reaction (31) 31
oxidation (31) 31
additions (30) 30
inhibitors (30) 30
sulfonyl aldimines (30) 30
aqueous-media (29) 29
organocatalysis (29) 29
azaarenes (28) 28
c-h functionalization (28) 28
one-pot synthesis (28) 28
research (28) 28
asymmetric synthesis (27) 27
mechanism (27) 27
c-h activation (26) 26
catalyst (26) 26
facile synthesis (26) 26
indoles (26) 26
zinc (26) 26
friedel-crafts reaction (25) 25
heterocycles (25) 25
ketoimines (25) 25
reactivity (25) 25
rhodium (25) 25
imine (24) 24
nucleophilic-addition (24) 24
tetrahedrons (24) 24
2-methyl azaarenes (23) 23
aldimine zinc-complexes (23) 23
amides (23) 23
michael addition (23) 23
reduction (23) 23
structure (23) 23
alkaloids (22) 22
amines - chemistry (22) 22
models, molecular (22) 22
palladium (22) 22
strecker reaction (22) 22
alkenes (21) 21
alpha-amino-acids (21) 21
condensation (21) 21
construction (21) 21
diels-alder reactions (21) 21
ligand (21) 21
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ACS Catalysis, ISSN 2155-5435, 10/2018, Volume 8, Issue 10, pp. 9125 - 9130
Previous studies of base metals for catalytic hydrogenation of nitriles to primary amines or secondary aldimines focus on designing complexes with elaborate... 
secondary aldimines | cobalt catalysts | nitriles | primary amines | hydrogenation | hydrogenative coupling | IMINES | COMPLEXES | CHEMISTRY, PHYSICAL | PNP-PINCER LIGANDS | ALDEHYDES | MILD | KETONES | C=O | METALS | CO2 HYDROGENATION
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2014, Volume 79, Issue 3, pp. 831 - 845
Journal Article
Synlett, ISSN 0936-5214, 01/2017, Volume 28, Issue 1, pp. 117 - 121
An aberrant reaction of Grignard reagents with N-alkylated indole-3-carboxaldehyde has been observed. Contrary to the usual formation of an alcohol, it... 
vibrindole | turbomycin | Grignard | ALDIMINES | TEMPERATURE IONIC LIQUIDS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | CATALYST | INDOLES | KETONES | MAGNESIUM | METHANES | AMINES | TRISINDOLYLMETHANES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2016, Volume 138, Issue 19, pp. 6194 - 6203
Mechanistic studies and expansion of the substrate scope of direct enantioselective alkynylation of α-ketiminoesters catalyzed by adaptable... 
LITHIUM ACETYLIDE | ALPHA,BETA-UNSATURATED THIOAMIDES | ASYMMETRIC CONJUGATE ADDITION | CYCLIC KETIMINES | TERMINAL ALKYNES | PROGRESS KINETIC-ANALYSIS | N-SULFONYL ALDIMINES | PROPARGYLIC AMINES | METAL CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | QUATERNARY CARBON CENTER
Journal Article
ACS Catalysis, ISSN 2155-5435, 2015, Volume 5, Issue 5, pp. 3054 - 3057
A low-valent cobalt catalyst generated from cobalt­(II) bromide, a diphosphine ligand, and zinc powder promotes intermolecular hydroacylation of olefins using... 
hydroacylation | aldimines | cobalt | C-H activation | alkenes | ALKENE | TRANSITION-METAL-COMPLEXES | ENANTIOSELECTIVE SYNTHESIS | INTRAMOLECULAR HYDROACYLATION | CHEMISTRY, PHYSICAL | SALICYLALDEHYDES | ALDEHYDES | ALKYNE HYDROACYLATION | HETEROCYCLES | BOND ACTIVATION | HYDROARYLATION
Journal Article
Green Chemistry, ISSN 1463-9262, 2014, Volume 16, Issue 5, pp. 2428 - 2431
A copper/Bronsted acid dual-catalyst promoted oxidative cross-dehydrogenative-coupling of alkylazaarenes and tertiary amines for C(sp(3))-C(sp(3)) bond... 
FUNCTIONALIZATION | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | ACTIVATION | TETRAHYDROISOQUINOLINES | H BOND | TERTIARY-AMINES | N-SULFONYL ALDIMINES | PYRIDINES | NUCLEOPHILIC-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | CONJUGATE ADDITION | MOLECULAR-OXYGEN
Journal Article
RSC Advances, ISSN 2046-2069, 07/2012, Volume 2, Issue 14, pp. 5968 - 5971
A novel protocol for the copper-catalysed direct C(sp(3))-H bond functionalisation of 2-alkyl azaarenes to C=O double bonds has been developed, which expands... 
FUNCTIONALIZATION | C-H BOND | DIRECT ARYLATION | OLEFINATION | STRATEGY | N-SULFONYL ALDIMINES | SITE-SELECTIVE SP | DIARYLATION | PYRIDINES | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 3, pp. 1082 - 1089
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 06/2017, Volume 53, Issue 53, pp. 7401 - 7404
In situ generated cationic zirconium complexes stabilized by amine-bridged bis(phenolato) ligands have been developed to catalyse C(sp )-H addition of alkyl... 
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2019, Volume 9, Issue 1, pp. 230 - 235
This work describes the palladium-catalyzed enantiotopic-group selective Suzuki-Miyaura cross-coupling of (diborylmethyl)silanes with aryl iodides. The... 
enantioselectivity | cross-coupling | palladium catalysis | rev-Josiphos | silicon | boron | REAGENT | ALDIMINES | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, PHYSICAL | ALDEHYDES | 1,1-DIBORYLALKANES | DIBORYLMETHANE | NUCLEOPHILIC SILICON | ALLYLIC SUBSTITUTION | STEREOCONTROLLED SYNTHESIS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2012, Volume 18, Issue 31, pp. 9511 - 9515
Acid test: With a Brønsted acid as the solvent, the rhodium‐catalyzed direct addition of aryl CH bonds to α,β‐unsaturated ketones was realized under mild... 
CH activation | proton transfer | ketones | conjugate addition | rhodium | C-H activation | ACTIVATION | INSERTION | DIRECT ARYLATION | ALDEHYDES | C?H activation | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | N-SULFONYL ALDIMINES | FRIEDEL-CRAFTS REACTION | DERIVATIVES | HYDROARYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 05/2012, Volume 14, Issue 9, pp. 2304 - 2307
Rhodium-catalyzed addition of benzamide C–H bonds to a range of aromatic N-sulfonyl aldimines has been developed and proceeds with high functional group... 
FUNCTIONALIZATION | MILD | ACTIVATION | ALDIMINES | C-H BOND | ARYLATION | CHEMISTRY, ORGANIC | ARYL | ALDEHYDES | ISOCYANATES | DERIVATIVES | Amines - chemistry | Isoindoles - chemistry | Imines - chemistry | Isoindoles - chemical synthesis | Molecular Structure | Amines - chemical synthesis | Catalysis | Imines - chemical synthesis | Rhodium - chemistry | Benzamides - chemistry
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 25, pp. 4633 - 4640
By employing an easily available, exceptionally simple sulfur-olefin ligand, a highly enantioselective rhodium-catalyzed arylation of cyclic N-sulfonyl... 
DESIGN | ALDIMINES | STEREOCENTERS | CONSTRUCTION | EFFICIENT SYNTHESIS | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | KETOIMINES | OLEFIN LIGANDS | ARYLBORONIC ACIDS | ACCESS | Rhodium | Acids | Esters | Amino acids | Catalysis | Sulfur | Enantiomers | Chemical synthesis | Molecular chains
Journal Article
Organic Letters, ISSN 1523-7060, 06/2017, Volume 19, Issue 11, pp. 2841 - 2844
Amines such as 1,2,3,4-tetrahydroisoquinoline undergo redox-neutral annulations with 2-alkylquinoline-3-carbaldehydes as well as the corresponding 4-alkyl... 
AZAARENES NUCLEOPHILIC-ADDITION | AZOMETHINE YLIDE ROUTE | FACILE ACCESS | TRANSITION-METAL | CATALYST-FREE | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | ALPHA-AMINO-ACIDS | N-SULFONYL ALDIMINES | SECONDARY-AMINES | CYCLIC AMINES | Acetic Acid - chemistry | Molecular Structure | Amines | Catalysis | Oxidation-Reduction | Letter
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 11/2015, Volume 56, Issue 46, pp. 6468 - 6471
[Display omitted] Acylketene, generated from 2,2,6-trimethyl-4H-1,3-dioxin-4-one reacts with aryl aldimines derived from 4-methyl-2-aminopyridine to give a... 
Acylketene | Schiff base | Aldimines | 2,2,6-Trimethyl-4H-1,3-dioxin-4-one | 3,4-Dihydro-2H-pyrido[1,2-a]pyrimidin-2-one | CHEMISTRY, ORGANIC | DERIVATIVES | TRANSFORMATIONS
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 10/2017, Volume 90, Issue 10, pp. 1157 - 1163
A continuous flow synthesis of β-amino acid derivatives has been demonstrated using an asymmetric Mannich reaction. An enolate of tert-butyl acetate was... 
SULFINIMINES | ALDOL | THIOOXIME S-OXIDES | ALDIMINES | P-TOLUENESULFINAMIDE | FLASH CHEMISTRY | ENOLATE | BATCH | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 10/2011, Volume 13, Issue 20, pp. 5636 - 5639
A new strategy has been introduced to develop a catalytic asymmetric Pictet–Spengler-type reaction by replacing the aldehyde with an imine. A range of... 
ACYLIMINIUM CYCLIZATION CASCADES | ENANTIOSELECTIVE SYNTHESIS | PHOSPHORIC-ACID | IMINES | CONSTRUCTION | CHEMISTRY, ORGANIC | N-SULFONYL ALDIMINES | NONREARRANGED MONOTERPENOID UNIT | FRIEDEL-CRAFTS ALKYLATION | DERIVATIVES | SIMPLE INDOLE ALKALOIDS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 8, pp. 1918 - 1922
In recent years, H2 activation at non‐transition‐metal centers has met with increasing attention. Here, a system in which H2 is activated and transferred to... 
hydrides | catalytic hydrogenation | aldimines | ketimines | main group elements | Protons | Lithium | Activation | Imines | Lithium hydrides | Metals
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2018, Volume 74, Issue 25, pp. 3101 - 3106
A simple and convenient mechanochemical method for the condensation of aldehydes with tert-butanesulfinamide using catalytic amounts of iodine under metal- and... 
Sulfinamides | Sulfinylimines | Ball mill | Mechanochemistry | Iodine | ROUTE | ALDIMINES | ASYMMETRIC-SYNTHESIS | ENANTIOPURE SULFINIMINES | ACIDS | CHEMISTRY, ORGANIC | DIASTEREOSELECTIVE SYNTHESIS | AMINES | DERIVATIVES | Schiff bases
Journal Article
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