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1. Full Text Deoxygenative Deuteration of Carboxylic Acids with D2O
by Zhang, Muliang and Yuan, Xiang‐Ai and Zhu, Chengjian and Xie, Jin
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2019, Volume 58, Issue 1, pp. 312 - 316
We report a general, practical, and scalable means of preparing deuterated aldehydes from aromatic and aliphatic carboxylic acids with D2O as an inexpensive... 
deoxygenation | deuteration | aldehydes | synergistic catalysis | carboxylic acids | CATALYSIS | TRITIATION | ALKYNYLATION | CHEMISTRY, MULTIDISCIPLINARY | DEUTERIUM | FUNCTIONALIZATION | MILD | REDUCTION | AMINES | AMIDES | Deuterium | Acids | Natural products | Reagents | Deoxygenation | Carboxylic acids | Deuteration | Aldehydes | Aliphatic compounds
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2. Full Text Silver-Catalyzed Decarboxylative Chlorination of Aliphatic Carboxylic Acids
by Wang, Zhentao and Zhu, Lin and Yin, Feng and Su, Zhongquan and Li, Zhaodong and Li, Chaozhong
Journal of the American Chemical Society, ISSN 0002-7863, 03/2012, Volume 134, Issue 9, pp. 4258 - 4263
Decarboxylative halogenation of carboxylic acids, the Hunsdiecker reaction, is one of the fundamental functional group transformations in organic chemistry. As... 
OXIDATIVE DECARBOXYLATION | ALKYL HALIDES | HUNSDIECKER REACTION | AROMATIC-ACIDS | MOLECULAR-STRUCTURES | COMPLEXES | STRUCTURAL-CHARACTERIZATION | CRYSTAL-STRUCTURES | LEAD ACETATE | CHEMISTRY, MULTIDISCIPLINARY | EFFICIENT METHOD | Hydrocarbons, Chlorinated - chemistry | Stereoisomerism | Carboxylic Acids - chemistry | Decarboxylation | Halogenation | Hydrocarbons, Chlorinated - chemical synthesis | Silver - chemistry | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Silver | Usage | Chlorination | Analysis | Carboxylation | Chemical properties | Carboxylic acids | Aliphatic compounds | Index Medicus
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3. Transition-metal-free decarboxylative bromination of aromatic carboxylic acids
by Jacob M Quibell and Gregory J P Perry and Diego M Cannas and Igor Larrosa
Chemical Science, ISSN 2041-6520, 01/2018, Volume 9, Issue 15, pp. 3860 - 3865
Methods for the conversion of aliphatic acids to alkyl halides have progressed significantly over the past century, however, the analogous decarboxylative... 
Acids | Bromination | Halides | Aromatic compounds | Reagents | Bromides | Carboxylic acids | Chemical synthesis | Aliphatic compounds | Substrates
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4. Full Text Silver‐Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion
by Hu, Feng and Shao, Xinxin and Zhu, Dianhu and Lu, Long and Shen, Qilong
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 24, pp. 6105 - 6109
A silver‐catalyzed decarboxylative trifluoromethylthiolation of secondary and tertiary carboxylic acids under mild conditions tolerates a wide range of... 
silver | decarboxylation | radicals | trifluoromethylthiolation | fluorine | OXIDATIVE TRIFLUOROMETHYLTHIOLATION | ORGANIC-CHEMISTRY | ROOM-TEMPERATURE | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | NUCLEOPHILIC TRIFLUOROMETHYLTHIOLATION | ELEMENTAL SULFUR | ARYL BORONIC ACIDS | ALPHA-FLUORINATED ETHERS | FREE-RADICAL REACTIONS | ELECTROPHILIC TRIFLUOROMETHANESULFANYLATION | Silver | Hydrocarbons, Fluorinated - chemistry | Emulsions | Catalysis | Carboxylic Acids - chemistry | Decarboxylation | Fluorides | Surface active agents | Sulfates | Organic acids | Acids | Sodium dodecyl sulfate | Droplets | Derivatives | Carboxylic acids | Aliphatic compounds | Functional groups | Radicals
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5. Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation
by Le Vaillant, Franck and Wodrich, Matthew D and Waser, Jerome
Chemical Science, ISSN 2041-6520, 02/2017, Volume 8, Issue 3, pp. 1790 - 1800
The one-step conversion of aliphatic carboxylic acids to the corresponding nitriles has been accomplished via the merger of visible light mediated photoredox... 
Precursors | Reagents | Nitriles | Tolerances | Carboxylic acids | Conversion | Aliphatic compounds | Radicals
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6. Full Text Direct Ruthenium‐Catalyzed Hydrogenation of Carboxylic Acids to Alcohols
by Cui, Xinjiang and Li, Yuehui and Topf, Christoph and Junge, Kathrin and Beller, Matthias
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 36, pp. 10596 - 10599
The “green” reduction of carboxylic acids to alcohols is a challenging task in organic chemistry. Herein, we describe a general protocol for generation of... 
ruthenium | alcohols | homogeneous catalysis | hydrogenation | carboxylic acids | ASYMMETRIC TRANSFER HYDROGENATION | AQUEOUS-PHASE HYDROGENATION | IRON | CHEMISTRY, MULTIDISCIPLINARY | SELECTIVE HYDROGENATION | REDUCTION | EFFICIENT HYDROGENATION | BIOMASS | PINCER COMPLEXES | ESTERS | SUCCINIC ACID | Ruthenium | Catalysis | Hydrogenation | Organic acids | Alcohols | Acids | Atmospheric aerosols | Organic chemistry | Alcohol | Biomass | Carboxylic acids | Aliphatic compounds | Lewis acid | Tasks | Tolerances | Derivatives
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7. Full Text Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes
by Wu, Xinxin and Meng, Chunna and Yuan, Xiaoqian and Jia, Xiaotong and Qian, Xuhong and Ye, Jinxing
Chemical Communications, ISSN 1359-7345, 07/2015, Volume 51, Issue 59, pp. 11864 - 11867
We report herein an efficient, general and green method for decarboxylative fluorination of aliphatic carboxylic acids. By using a transition-metal-free,... 
MEDICINAL CHEMISTRY | 9-MESITYL-10-METHYLACRIDINIUM ION | BENZYLIC FLUORINATION | ACTIVATION | FLUORIDE-ION | F BOND | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | UNACTIVATED ALKENES | AQUEOUS-SOLUTION | TRIFLUOROMETHYLATION | Light irradiation | Dyes | Carboxylic acids | Fluorides | Catalysis | Fluorination | Aliphatic compounds
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8. Full Text Decarboxylative Cyanation of Aliphatic Carboxylic Acids via Visible-Light Flavin Photocatalysis
by Ramirez, NP and Konig, B and Gonzalez-Gomez, JC
ORGANIC LETTERS, ISSN 1523-7060, 03/2019, Volume 21, Issue 5, pp. 1368 - 1373
An operationally simple method is disclosed for the decarboxylative cyanation of aliphatic carboxylic acids at room temperature. Riboflavin tetraacetate, which... 
RIBOFLAVIN | OXIDATION | CATALYZED HYDROCYANATION | ACTIVATION | ELECTRON-TRANSFER | NITRILE | MECHANISM | CHEMISTRY, ORGANIC | OLEFINS | CARBON RADICALS | CYANIDE
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9. The chemistry of carboxylic acids and esters
by Patai, Saul
1969, Chemistry of functional groups, xiv, 1155 p. illus.
Esters | Carboxylic acids
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10. Full Text Photoinduced electron transfer-promoted decarboxylative radical reactions of aliphatic carboxylic acids by organic photoredox system
by Yoshimi, Yasuharu
Journal of Photochemistry & Photobiology, A: Chemistry, ISSN 1010-6030, 06/2017, Volume 342, pp. 116 - 130
This feature article covers our efforts to develop a new method for radical reactions of aliphatic carboxylic acids via a photoinduced electron... 
Aliphatic carboxylic acid | PET-promoted decarboxylation | Decarboxylative radical reaction | Photoinduced electron transfer | Organic photoredox system | RING EXPANSION | ALKYL RADICALS | ACRYLONITRILE | CONVERSION | CHEMISTRY, PHYSICAL | ALPHA-AMINO-ACIDS | REDUCTION | PHOTOCHEMICAL DECARBOXYLATION | ESTERS | CHEMISTRY | DERIVATIVES | Electron transport | Organic acids
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11. Full Text Metal-free amidation of carboxylic acids with tertiary amines
by Phakhodee, Wong and Wangngae, Sirilak and Pattarawarapan, Mookda
RSC Advances, ISSN 2046-2069, 2016, Volume 6, Issue 65, pp. 60287 - 60290
A direct amidation of carboxylic acids with tertiary amines could be carried out in the presence of the Ph3P-I-2 activator. With an appropriate reagent... 
ACYLOXYPHOSPHONIUM | MITSUNOBU REACTION | ORGANIC-SYNTHESIS | CATALYZED OXIDATIVE AMIDATION | ACTIVATIONS | ACYL IODIDES | ACETIC-ANHYDRIDE | C-N BOND | CLEAVAGE | AMINOLYSIS | CHEMISTRY, MULTIDISCIPLINARY | Amides | Amines | Carboxylic acids | Catalysis | Aliphatic compounds | Reagents
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12. Full Text From Alkanes to Carboxylic Acids: Terminal Oxygenation by a Fungal Peroxygenase
by Olmedo, Andrés and Aranda, Carmen and del Río, José C and Kiebist, Jan and Scheibner, Katrin and Martínez, Angel T and Gutiérrez, Ana
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 40, pp. 12248 - 12251
A new heme–thiolate peroxidase catalyzes the hydroxylation of n‐alkanes at the terminal position—a challenging reaction in organic chemistry—with H2O2 as the... 
oxidoreductases | alkanes | terminal hydroxylation | peroxygenase | carboxylic acids | CONVERSION | HYDROXYLATION | ALIPHATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | AROMATIC PEROXYGENASE | COPRINOPSIS-CINEREA | PEROXIDASE | OXYFUNCTIONALIZATION | Oxidases | Hydroxylation | Organic acids | Heme | Acids | Tetradecane | Hydrogen peroxide | Dodecane | Chemical reactions | Chains | Alkanes | Carboxylic acids | Conversion | Dodecanoic acid | Fungi | Organic chemistry | Chemistry | Dodecanol | Peroxidase | Oxidation | Cascade chemical reactions | N-Alkanes | Oxygenation
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13. Full Text A biocatalytic method for the chemoselective aerobic oxidation of aldehydes to carboxylic acids
by Knaus, T and Tseliou, V and Humphreys, L.D and Scrutton, N.S and Mutti, F.G
Green Chemistry, ISSN 1463-9262, 09/2018, Volume 20, Issue 17, pp. 3931 - 3943
Herein, we present a study on the oxidation of aldehydes to carboxylic acids using three recombinant aldehyde dehydrogenases (ALDHs). The ALDHs were used in... 
FORMIC-ACID | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | SELECTIVE OXIDATION | MILD CONDITIONS | MECHANISM | CATALYZED OXIDATION | AROMATIC-ALDEHYDES | UREA-HYDROGEN PEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | PRIMARY ALCOHOLS | DEHYDROGENASE | WATER | NADPH | Furfural | Oxidizing agents | Carboxylic acids | Aldehydes | Biocatalysts | Aliphatic compounds | Substrates | Alcohols | NAD | Furoic acid | Acids | Oxidants | Aromatic compounds | Halogenation | Oxidation | Nicotinamide | Catalysis | Sulfur | Recombinant
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14. Full Text Chiral Solvating Agents for Cyanohydrins and Carboxylic Acids
by Moon, Lomary S and Pal, Mohan and Kasetti, Yoganjaneyulu and Bharatam, Prasad V and Jolly, Ravinder S
The Journal of Organic Chemistry, ISSN 0022-3263, 08/2010, Volume 75, Issue 16, pp. 5487 - 5498
We have shown that a structure as simple as an ion pair of (R)- or (S)-mandelate and dimethylamminopyridinium ions possesses structural features that are... 
PERTURBATION-THEORY | STRUCTURALLY SIMPLE | ENANTIOMERIC EXCESS | ABSOLUTE-CONFIGURATION | ACTIVE ALIPHATIC CYANOHYDRINS | ENZYME-CATALYZED SYNTHESIS | NMR-SPECTROSCOPY | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE RECOGNITION | BINDING-PROPERTIES | SHIFT-REAGENT | Thermodynamics | Magnetic Resonance Spectroscopy | Models, Chemical | Solvents - chemistry | Stereoisomerism | Carboxylic Acids - chemistry | Computer Simulation | Molecular Conformation | Nitriles - chemistry | Models, Molecular | Usage | Solvation | Chirality | Analysis | Density functionals | Nitriles | Carboxylic acids | Chemical properties
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15. Full Text Preparative microdroplet synthesis of carboxylic acids from aerobic oxidation of aldehydes
by Yan, Xin and Lai, Yin-Hung and Zare, Richard N
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 23, pp. 5207 - 5211
Single liquid-phase and liquid-liquid phase reactions in microdroplets have shown much faster kinetics than that in the bulk phase. This work extends the scope... 
CHEMISTRY | PAPER SPRAY | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | WATER | Spray nozzles | Oxygen | Ethanol | Liquid phases | Carboxylic acids | Aldehydes | Mass transfer | Aliphatic compounds | Molecular chains | Acids | Reaction kinetics | Nozzles | Nickel | Oxidation | Catalysis | Chemical synthesis
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16. Full Text Silver-Catalyzed Radical Transformation of Aliphatic Carboxylic Acids to Oxime Ethers
by Zhu, Yuchao and Wen, Xiaojin and Song, Song and Jiao, Ning
ACS Catalysis, ISSN 2155-5435, 10/2016, Volume 6, Issue 10, pp. 6465 - 6472
Oximes and oxime ethers are privileged building blocks and can be conveniently converted to ketones, amines, hydroxylamines, and nitriles. We describe the... 
oxime ether | decarboxylation | radical | aliphatic carboxylic acids | late-stage functionalization | OXIDATIVE DECARBOXYLATION | CHEMISTRY, PHYSICAL | SANDMEYER TRIFLUOROMETHYLATION | HIGHLY EFFICIENT | PHOTOREDOX CATALYSIS | AQUEOUS-SOLUTION | MILD CONDITIONS | H-PHOSPHINE OXIDES | ARYL HALIDES | ALPHA-OXOCARBOXYLIC ACIDS | DECARBOXYLATIVE ORTHO-ACYLATION
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17. Full Text Rapid analysis of carboxylic acids and esters with a direct analysis in real time ion source
by Wang, Sheng‐Kang and Wei, Xian‐Yong and Li, Sheng and Liu, Fang‐Jing and Wang, Yu‐Gao and Li, Zhan‐Ku and Shi, Chong and Yang, Zheng and Zong, Zhi‐Min
Rapid Communications in Mass Spectrometry, ISSN 0951-4198, 09/2018, Volume 32, Issue 17, pp. 1521 - 1528
Rationale Coal oxidation produces carboxylic acids (CAs), including aliphatic acids, benzoic acids, and benzenepolycarboxylic acids, which are important fine... 
SEQUENTIAL OXIDATION | CHEMISTRY, ANALYTICAL | BENZENE POLYCARBOXYLIC ACIDS | SPECTROSCOPY | BIOCHEMICAL RESEARCH METHODS | ALKALI-OXYGEN OXIDATION | MASS-SPECTROMETRY | LIGNITE | SODIUM-HYPOCHLORITE | Esters | Analysis | Organic acids | Benzoic acid | Dimethyl | Fine chemicals | Carboxylic acids | Gas temperature | Real time | Aliphatic compounds | Organic chemistry | Acids | Coal | Oxidation | Mass spectrometry
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18. Full Text Zinc Oxide‐Catalyzed Dehydrogenation of Primary Alcohols into Carboxylic Acids
by Monda, Fabrizio and Madsen, Robert
Chemistry – A European Journal, ISSN 0947-6539, 12/2018, Volume 24, Issue 67, pp. 17832 - 17837
Zinc oxide has been developed as a catalyst for the dehydrogenation of primary alcohols into carboxylic acids and hydrogen gas. The reaction is performed in... 
alcohols | dehydrogenation | zinc | synthetic methods | carboxylic acids | OXIDATION | CONVERSION | COMPLEXES | SECONDARY | TRANSFER HYDROGENATION | TERMINAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | TISHCHENKO REACTION | CHEMOSELECTIVE REDUCTION | EFFICIENT | WATER | Hydrochloric acid | Hydroxides | Chemical tests and reagents | Dehydrogenation | Hydrogen | Zinc oxide | Aldehydes | Organic acids | Alcohols | Hydrogen storage | Salts | Transformation | Potassium hydroxide | Alcohol | Potassium hydroxides | Carboxylic acids | Zinc salts | Aliphatic compounds | Zinc | Zinc oxides | Mesitylene | Potassium | Hydrogen ion concentration
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