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alkenes (404) 404
chemistry, organic (300) 300
chemistry, multidisciplinary (232) 232
olefins (226) 226
catalysis (207) 207
aziridination (196) 196
alkene aziridination (162) 162
amination (112) 112
complexes (111) 111
index medicus (96) 96
catalysts (83) 83
oxidation (77) 77
alkenes - chemistry (75) 75
chemistry, inorganic & nuclear (73) 73
chloramine-t (73) 73
epoxidation (72) 72
molecular structure (71) 71
ligands (70) 70
amidation (68) 68
chemistry (66) 66
enantioselective aziridination (64) 64
chemical properties (62) 62
derivatives (61) 61
chemistry, physical (60) 60
catalyzed aziridination (58) 58
c-h amination (57) 57
stereoisomerism (55) 55
cyclopropanation (54) 54
aziridines (53) 53
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analysis (51) 51
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asymmetric aziridination (50) 50
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bonds (34) 34
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organic-synthesis (33) 33
azides (32) 32
aziridines - chemical synthesis (32) 32
efficient aziridination (32) 32
nitrogen-atom-transfer (32) 32
mechanism (31) 31
nitrogen-source (31) 31
stereoselective-synthesis (31) 31
asymmetric-synthesis (30) 30
copper-complexes (30) 30
iron (30) 30
bromamine-t (29) 29
chiral aziridines (29) 29
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organic compounds (27) 27
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esters (22) 22
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copper - chemistry (19) 19
hypervalent iodine (19) 19
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epoxides (18) 18
manganese porphyrins (18) 18
rhodium-catalyzed aziridination (18) 18
transition metals (18) 18
intermolecular amination (17) 17
organometallic compounds - chemistry (17) 17
stereoselectivity (17) 17
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1. Full Text Visible-Light-Induced Intramolecular C(sp2)–H Amination and Aziridination of Azidoformates via a Triplet Nitrene Pathway
by Zhang, Yipin and Dong, Xunqing and Wu, Yanan and Li, Guigen and Lu, Hongjian
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 16, pp. 4838 - 4842
Catalytic intramolecular C–H amination and aziridination reactions of o-allylphenyl azidoformates have been achieved under visible-light irradiation, providing... 
OXIDATION | FUNCTIONALIZATION | ARENES | AMIDATION | CHEMISTRY, ORGANIC | ALKENE AZIRIDINATION | SULFONAMIDES | CATALYST | ORGANIC AZIDES | C-H AMINATION | HIGHLY EFFICIENT
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2. Full Text Iron‐Catalyzed Aziridination Reactions
by Nakanishi, Masafumi and Salit, Anne‐Frederique and Bolm, Carsten
Advanced Synthesis & Catalysis, ISSN 1615-4150, 08/2008, Volume 350, Issue 11‐12, pp. 1835 - 1840
A small quantity of iron(II) triflate (2.5 to 5 mol%) catalyzes the aziridination reactions of enol silyl ethers with tosylimino(iodo)benzene (PhINTs) in... 
iron | sulfonamides | asymmetric catalysis | nitrogen transfer | aziridination | Iron | Aziridination | Sulfonamides | Asymmetric catalysis | Nitrogen transfer | ENANTIOSELECTIVE AZIRIDINATION | COPPER-COMPLEXES | P-TOLUENESULPHONAMIDE | EFFICIENT AZIRIDINATION | CHEMISTRY, ORGANIC | OLEFIN AZIRIDINATION | ASYMMETRIC ALKENE AZIRIDINATION | POTENT CATALYSTS | ALPHA-AMINO KETONES | CHEMISTRY, APPLIED | CHIRAL AZIRIDINES | C-H
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3. Full Text Styrene Aziridination by Iron(IV) Nitrides
by Muñoz, Salvador B and Lee, Wei‐Tsung and Dickie, Diane A and Scepaniak, Jeremiah J and Subedi, Deepak and Pink, Maren and Johnson, Michael D and Smith, Jeremy M
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 36, pp. 10600 - 10603
Thermolysis of the iron(IV) nitride complex [PhB(tBuIm)3FeN] with styrene leads to formation of the high‐spin iron(II) aziridino complex... 
alkenes | iron | nitrides | CATALYZED AZIRIDINATION | NITRENE TRANSFER-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | NITROGEN ATOM-TRANSFER | METAL NITRIDE | OLEFINS | ARYL AZIDES | SPIN-CROSSOVER COMPLEXES | STEREOSELECTIVE-SYNTHESIS | C-H | Styrene - chemistry | Aziridines - chemistry | Iron Compounds - chemistry | Nitrogen Compounds - chemistry | Nitrides | Styrene | Styrenes | Temperature effects | Metathesis | Iron | Electron spin | Formations
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4. Full Text Hypoiodite‐Mediated Metal‐Free Catalytic Aziridination of Alkenes
by Yoshimura, Akira and Middleton, Kyle R and Zhu, Chenjie and Nemykin, Victor N and Zhdankin, Viktor V
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2012, Volume 51, Issue 32, pp. 8059 - 8062
Look, no metal: A metal‐free catalytic procedure for aziridination of alkenes using tetrabutylammonium iodide as the catalyst, m‐chloroperoxybenzoic acid... 
organocatalysis | oxidation | iodine | aziridination | hypoiodous acid | ORGANIC-SYNTHESIS | ENANTIOSELECTIVE AZIRIDINATION | COPPER-COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | AMINATION | ASYMMETRIC AZIRIDINATION | CHEMISTRY | OLEFINS | AMMONIUM (HYPO)IODITE CATALYSIS | HYPERVALENT IODINE REAGENTS | Alkenes - chemistry | Iodine Compounds - chemistry | Models, Molecular | Crystallography, X-Ray | Molecular Structure | Catalysis | Aziridines - chemistry | Aziridines - chemical synthesis | Olefins | Universities and colleges | Iodides | Alkenes | Catalysts | Oxidants | Precursors | X-rays | Oxidizing agents | Terminals
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5. Full Text Spin‐Selective Generation of Triplet Nitrenes: Olefin Aziridination through Visible‐Light Photosensitization of Azidoformates
by Scholz, Spencer O and Farney, Elliot P and Kim, Sangyun and Bates, Desiree M and Yoon, Tehshik P
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 6, pp. 2239 - 2242
Azidoformates are interesting potential nitrene precursors, but their direct photochemical activation can result in competitive formation of aziridination and... 
chemoselectivity | aziridination | azides | photocatalysis | nitrenes | AZIDE COMPOUNDS | ENANTIOSELECTIVE AZIRIDINATION | ASYMMETRIC AZIRIDINATION | COMPLEXES | DECOMPOSITION | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | Olefins | Chemical bonds | Alkenes | Metals | Activation | Light effects | Flow | Amination | Photosensitization | Ethers | Coordination compounds | Metal complexes | Continuity (mathematics) | Organic compounds
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6. Full Text Chiral Cu(salen)-Based Metal–Organic Framework for Heterogeneously Catalyzed Aziridination and Amination of Olefins
by Liu, Yan and Li, Zijian and Yuan, Guozan and Xia, Qingchun and Yuan, Chen and Cui, Yong
Inorganic Chemistry, ISSN 0020-1669, 12/2016, Volume 55, Issue 24, pp. 12500 - 12503
A homochiral 3D porous metal–organic framework was assembled from a chiral dicarboxylic acid-functionalized Cu­(salen)-based catalyst and could serve as an... 
ASYMMETRIC CATALYSIS | POSTSYNTHETIC MODIFICATION | SALEN | SORPTION | ALKENE AZIRIDINATION | LIGAND | TRANSFORMATIONS | EPOXIDATION | CHEMISTRY, INORGANIC & NUCLEAR | Copper compounds | Chemical reactions | Usage | Chemical properties | Olefins | Metal ions
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7. Full Text Effective Synthesis of Chiral N‐Fluoroaryl Aziridines through Enantioselective Aziridination of Alkenes with Fluoroaryl Azides
by Jin, Li‐Mei and Xu, Xue and Lu, Hongjian and Cui, Xin and Wojtas, Lukasz and Zhang, X. Peter
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2013, Volume 52, Issue 20, pp. 5309 - 5313
The CoII complex of a D2‐symmetric chiral porphyrin ([Co(D2‐Por*)], see scheme) is a highly effective catalyst for the enantioselective aziridination of... 
aziridines | cobalt | asymmetric catalysis | porphyrins | aryl azides | NITROGEN-SOURCES | CATALYTIC CYCLOPROPANATION | ASYMMETRIC OLEFIN AZIRIDINATION | DEPROTECTION | ORGANIC AZIDES | CHEMISTRY, MULTIDISCIPLINARY | PORPHYRIN COMPLEXES | BONDS | FLUORINE | C-H AMINATION | Synthesis | Alkenes | Catalysts | Olefins | Constraining | Porphyrins
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8. Full Text Organocatalytic Asymmetric Epoxidation and Aziridination of Olefins and Their Synthetic Applications
by Zhu, Yingguang and Wang, Qian and Cornwall, Richard G and Shi, Yian
Chemical Reviews, ISSN 0009-2665, 08/2014, Volume 114, Issue 16, pp. 8199 - 8256
CINNAMIC ACID-DERIVATIVES | GENERATED IN-SITU | POLY-L-LEUCINE | HIGHLY ENANTIOSELECTIVE EPOXIDATION | JULIA-COLONNA EPOXIDATION | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | ARABINOSE-DERIVED KETONES | PHASE-TRANSFER CATALYSTS | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-DEFICIENT OLEFINS | TRANSFER MEDIATED EPOXIDATION | Amines - chemistry | Alkenes - chemistry | Peptides - chemistry | Molecular Structure | Aspartic Acid - chemistry | Catalysis | Thiourea - chemistry | Aziridines - chemistry | Pyrrolidines - chemistry | Aziridines - chemical synthesis | Thermal properties | Olefins | Chirality | Analysis | Amino acids | Oxidation-reduction reaction | Chemical properties | Structure
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9. Full Text Site-Selective, Catalyst-Controlled Alkene Aziridination
by Mat Lani, Amirah S and Schomaker, Jennifer M
Synthesis, ISSN 0039-7881, 11/2018, Volume 50, Issue 22, pp. 4462 - 4470
Abstract Transition-metal-catalyzed nitrene transfer is a convenient method to introduce nitrogen into simple substrates through either alkene aziridination or... 
paper | aziridine | silver | site-selective | alkene | nitrene transfer | OXIDATION | MECHANISM | EFFICIENT AZIRIDINATION | COMPLEXES | UNIQUE | CHEMISTRY, ORGANIC | OLEFIN AZIRIDINATION | COPPER | HIGHLY EFFICIENT | AMINATION | NITRENE-TRANSFER
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10. Full Text o‐Alkoxyphenyliminoiodanes: Highly Efficient Reagents for the Catalytic Aziridination of Alkenes and the Metal‐Free Amination of Organic Substrates
by Yoshimura, Akira and Nemykin, Victor N and Zhdankin, Viktor V
Chemistry – A European Journal, ISSN 0947-6539, 09/2011, Volume 17, Issue 38, pp. 10538 - 10541
Efficient nitrene precursors: Highly reactive iminoiodane‐based nitrene precursors were prepared from ortho‐alkoxyiodobenzenes. Owing to the presence of the... 
oxidation | amination | iodine | aziridination | hypervalent compounds | ENANTIOSELECTIVE AZIRIDINATION | COPPER-COMPLEXES | HYDROGEN-ATOM TRANSFER | CORROLE | AMIDATION | OXIDIZING REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | HYPERVALENT IODINE | ASYMMETRIC AZIRIDINATION | NITRENE SOURCES | C-H GROUPS | Alkenes | Catalysts | Precursors | Reagents | Solubility | Catalysis | Substrates | Organic compounds
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11. Full Text Recent Advances in the Stereoselective Synthesis of Aziridines
by Degennaro, Leonardo and Trinchera, Piera and Luisi, Renzo
Chemical Reviews, ISSN 0009-2665, 08/2014, Volume 114, Issue 16, pp. 7881 - 7929
ENANTIOSELECTIVE AZIRIDINATION | N-BOC-IMINES | DIASTEREOSELECTIVE SYNTHESIS | MEDIATED AZIRIDINATION | ALKENE AZIRIDINATION | OLEFIN AZIRIDINATION | CHIRAL AZIRIDINES | CHEMISTRY, MULTIDISCIPLINARY | CATALYTIC ASYMMETRIC AZIRIDINATION | TERMINAL AZIRIDINES | HETEROGENEOUS AZIRIDINATION | Molecular Structure | Aziridines - chemistry | Stereoisomerism | Aziridines - chemical synthesis | Thermal properties | Aziridines | Analysis | Chemical properties | Catalysis | Ring formation (Chemistry) | Nitrogen
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12. Full Text Copper‐Catalyzed Aziridination with Redox‐Active Ligands: Molecular Spin Catalysis
by Ren, Yufeng and Cheaib, Khaled and Jacquet, Jérémy and Vezin, Hervé and Fensterbank, Louis and Orio, Maylis and Blanchard, Sébastien and Desage‐El Murr, Marine
Chemistry – A European Journal, ISSN 0947-6539, 04/2018, Volume 24, Issue 20, pp. 5086 - 5090
Small‐molecule catalysts as mimics of biological systems illustrate the chemists’ attempts at emulating the tantalizing abilities displayed by nature's... 
redox-active ligands | copper catalysis | aziridination | multistate reactivity | spin catalysis | CYTOCHROME-P450 | COMPLEX | NON-INNOCENT LIGANDS | HYDROXYLATION | ALKENE AZIRIDINATION | NITRENE TRANSFER-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION | METAL REACTIVITY | RADICAL LIGANDS | AEROBIC OXIDATION | Thermodynamics | Catalysis | Biomimetics | Metalloenzymes | Copper | Reactivity | Catalysts | Chemists | Ligands | Chemical reactions | Chemical Sciences
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13. Full Text Highly Efficient Alkene Epoxidation and Aziridination Catalyzed by Iron(II) Salt + 4,4′,4′′-Trichloro-2,2′:6′,2′′-terpyridine/4,4′′-Dichloro-4′-O-PEG-OCH3-2,2′:6′,2′′-terpyridine
by Liu, Peng and Wong, Ella Lai-Ming and Yuen, Angella Wing-Hoi and Che, Chi-Ming
Organic Letters, ISSN 1523-7060, 08/2008, Volume 10, Issue 15, pp. 3275 - 3278
“Iron(II) salt + 4,4′,4′′-trichloro-2,2′:6′,2′′-terpyridine” is an effective catalyst for epoxidation and aziridination of alkenes and intramolecular amidation... 
SATURATED-HYDROCARBONS | COMPLEX | NONHEME | RIESKE DIOXYGENASES | DIASTEREOSELECTIVE EPOXIDATION | AQUEOUS HYDROGEN-PEROXIDE | AMIDATION | CHEMISTRY, ORGANIC | GIF CHEMISTRY | H2O2 | OLEFIN CIS-DIHYDROXYLATION | Alkenes - chemistry | Cyclization | Epoxy Compounds - chemical synthesis | Pyridines - chemistry | Allyl Compounds - chemistry | Polyethylene Glycols - chemistry | Ferrous Compounds - chemistry | Catalysis | Aziridines - chemical synthesis
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14. Full Text An Amine‐Promoted Aziridination of Chalcones
by Shen, Yu‐Mei and Zhao, Mei‐Xin and Xu, Jiaxi and Shi, Yian
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2006, Volume 45, Issue 47, pp. 8005 - 8008
Without protection: α‐Keto aziridines have been formed in a novel amine‐promoted direct aziridination of chalcones using an aminimide generated in situ from a... 
chalcones | aziridines | asymmetric catalysis | small ring systems | nitrogen heterocycles | Chalcones | Small ring systems | Aziridines | Nitrogen heterocycles | Asymmetric catalysis | ENANTIOSELECTIVE AZIRIDINATION | ONE-STEP SYNTHESIS | EFFICIENT AZIRIDINATION | ALKENE AZIRIDINATION | OLEFIN AZIRIDINATION | CHEMISTRY, MULTIDISCIPLINARY | ABSOLUTE-CONFIGURATION | DIASTEREOSELECTIVE AZIRIDINATION | NITROGEN TRANSFER | CATALYTIC ASYMMETRIC AZIRIDINATION | SELECTIVE AZIRIDINATION | Amines - chemistry | Chalcones - chemistry | Heterocyclic Compounds - chemistry | Models, Chemical | Nitrogen - chemistry | Catalysis | Aziridines - chemistry
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15. Full Text Unprecedented Trinuclear AgI Complex with 2,4,6‐Tris(2‐pyrimidyl)‐1,3,5‐triazine as an Efficient Catalyst for the Aziridination of Olefins
by Safin, Damir A and Pialat, Amélie and Korobkov, Ilia and Murugesu, Muralee
Chemistry – A European Journal, ISSN 0947-6539, 04/2015, Volume 21, Issue 16, pp. 6144 - 6149
An unprecedented trinuclear heteroleptic AgI complex was isolated using a stable multidentate 2,4,6‐tris(2‐pyrimidyl)‐1,3,5‐triazine (TPymT) ligand. The... 
crystal structure | silver cluster | catalysis | aziridination | olefins | Silver cluster | Catalysis | Aziridination | Olefins | Crystal structure
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16. Full Text Chemoselective Allene Aziridination via Ag(I) Catalysis
by Rigoli, Jared W and Weatherly, Cale D and Vo, Brian T and Neale, Samuel and Meis, Alan R and Schomaker, Jennifer M
Organic Letters, ISSN 1523-7060, 01/2013, Volume 15, Issue 2, pp. 290 - 293
Allene aziridination generates useful bicyclic methylene aziridine scaffolds that can be flexibly transformed into a range of stereochemically complex and... 
FUNCTIONALIZATION | INTERMOLECULAR AMINATION | EFFICIENT AZIRIDINATION | DISCRETE | CYCLOPROPANATION | CHEMISTRY, ORGANIC | ALKENE AZIRIDINATION | SILVER(I) | COORDINATION | C-H AMINATION | MOLECULES
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17. Full Text Mechanistic study of styrene aziridination by iron(iv) nitrides
by Crandell, Douglas W and Muñoz, 3rd, Salvador B and Smith, Jeremy M and Baik, Mu-Hyun
Chemical science, ISSN 2041-6520, 12/2018, Volume 9, Issue 45, pp. 8542 - 8552
A combined experimental and computational investigation was undertaken to investigate the mechanism of aziridination of styrene by the tris(carbene)borate... 
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