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Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 15, pp. 4328 - 4332
A cobalt‐catalyzed Z‐selective hydrosilylation of alkynes has been developed relying on catalysts generated from bench‐stable Co(OAc)2 and pyridine‐2,6‐diimine... 
hydrosilylation | cobalt | homogeneous catalysis | vinylsilanes | alkynes | HYDROBORATION | HYDROGENATION | MECHANISM | ISOMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | REGIO | TRANS ADDITION | HYDROSILATION | STEREOSELECTIVE HYDROSILYLATION | ALKENE HYDROSILYLATION | RUTHENIUM COMPLEX | Pyridine | Catalysis | Cobalt | Isomerization | Pyridines | Transformation | Catalysts | Phenols | Hydrosilylation | Alkynes
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2017, Volume 7, Issue 2, pp. 1227 - 1243
This review covers the advance in the development of Fe, Co, and Ni catalysts for the alkene hydrosilylation reaction, as well as the related dehydrogenative... 
Hydrosilylation | Iron | Nickel | Alkene | Cobalt | Dehydrogenative silylation | nickel | ORGANIC-SYNTHESIS | NICKEL-COMPLEXES | SILICON HYDRIDES | CHEMISTRY, PHYSICAL | cobalt | IRON CATALYSTS | HIGHLY EFFICIENT | dehydrogenative silylation | CROSS-COUPLING REACTIONS | alkene | hydrosilylation | iron | COBALT CATALYST | TERTIARY SILANES | ELECTRONIC-STRUCTURE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 15, pp. 4661 - 4664
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 28, pp. 9439 - 9442
A cobalt-catalyzed highly Markovnikov-type and enantioselective hydrosilylation of alkenes is developed for the efficient synthesis of valuable chiral... 
ASYMMETRIC HYDROSILYLATION | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | SILICON BOND FORMATION | LIGANDS | SILANES | INTRAMOLECULAR HYDROSILATION | COMPLEXES | OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | MARKOVNIKOV HYDROSILYLATION | Metal catalysts | Olefins | Asymmetric induction (Stereochemistry) | Research | Chemical properties | Cobalt | Silane
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 09/2018, Volume 13, Issue 17, pp. 2307 - 2315
Over the past few decades, manganese‐catalyzed hydrosilylation of C=O or C=C/C≡C unsaturated bonds have undergone enormous developments. In this focus review,... 
hydrosilylation | alkenes | carbonyl bonds | manganese | alkynes | KETONE HYDROSILYLATION | WELL-DEFINED MANGANESE | 1,3-DICARBONYL COMPOUNDS | CARBONYL-COMPOUNDS | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | HETEROCYCLIC CARBENE COMPLEXES | MN-III CATALYST | PINCER COMPLEXES | STEREOSELECTIVE HYDROSILYLATION | ALKENE HYDROSILYLATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2016, Volume 6, Issue 1, pp. 290 - 300
The demand for economical and environmentally benign catalysts for important chemical transformations has recently initiated great efforts on nonprecious... 
selectivity | hydrosilylation | alkyne | cobalt | alkene | ASYMMETRIC HYDROSILYLATION | NICKEL-COMPLEXES | SILICON HYDRIDES | CHEMISTRY, PHYSICAL | N-HETEROCYCLIC CARBENES | IRON CATALYSTS | REGIOSELECTIVE HYDROSILYLATION | ELECTRONIC-STRUCTURES | HOMOGENEOUS CATALYSIS | BOND ACTIVATION | METAL-COMPLEXES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2014, Volume 356, Issue 2‐3, pp. 584 - 590
The chemo‐, regio‐, and stereoselective iron‐catalysed hydrosilylation of alkenes and alkynes with excellent functional group tolerance is reported (34... 
hydrosilylation | catalysis | iron | olefins | synthetic methods | Hydrosilylation | Iron | Synthetic methods | Catalysis | Olefins | HALIDES | OXIDATION | ORGANIC-SYNTHESIS | HYDROBORATION | HYDROGENATION | COMPLEXES | CHEMISTRY, ORGANIC | DEACTIVATION PATHWAYS | CARBON BOND | REDUCTION | SILAFUNCTIONAL COMPOUNDS | CHEMISTRY, APPLIED | Chemotherapy | Chemical tests and reagents | Silane | Cancer | Silanes | Alkenes | Catalysts | Tolerances | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 36, pp. 10835 - 10838
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 87, pp. 12322 - 12325
Hydrofunctionalizations of unsaturated hydrocarbons are key strategies for the synthesis of functionalized building blocks. Here, we report highly versatile... 
Z-SELECTIVE HYDROSILYLATION | ANTI-MARKOVNIKOV HYDROSILYLATION | TERMINAL ALKYNES | (Z)-SELECTIVE HYDROSILYLATION | INTERNAL ALKYNES | STEREOSELECTIVE HYDROSILYLATION | REGIOSELECTIVE HYDROSILYLATION | INTERMOLECULAR HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENE HYDROSILYLATION | RUTHENIUM COMPLEX
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2013, Volume 135, Issue 51, pp. 19154 - 19166
A series of new pincer iron complexes with electron-donating phosphinite-iminopyridine (PNN) ligands has been prepared and characterized. These iron compounds... 
ASYMMETRIC HYDROSILYLATION | KETONES | SILICON BOND | HYDROGENATION | HYDROSILANE REDUCTION | PINCER COMPLEXES | EFFICIENT HYDROSILYLATION | CARBONYL-COMPOUNDS | METAL | SELECTIVE HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | Phosphorus compounds | Iron | Chemical properties | Research | Olefins
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 52, pp. 16621 - 16625
Although there has been significant progress in the development of transition‐metal‐catalyzed hydrosilylations of alkenes over the past several decades,... 
hydrosilylation | alkenes | photocatalysis | hydrogen atom transfer | polarity reversal | ALKYLATION | HYDRIDES | IRON | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | BONDS | RADICAL-CHAIN HYDROSILYLATION | POLARITY-REVERSAL CATALYSIS | Hydrogen | Olefins | Catalysis | Alkenes | Metals | Polarity | Activation | Hydrosilylation | Acetic acid | Hydrogen ion concentration | Electrons
Journal Article
Chemical Communications, ISSN 1359-7345, 2015, Volume 51, Issue 24, pp. 5073 - 5076
A series of iron complexes of chiral iminopyridine-oxazoline (IPO) ligands have been synthesized. The most sterically hindered iron catalyst exhibits excellent... 
ENANTIOSELECTIVE HYDROSILYLATION | CHIRAL LIGANDS | HYDROGENATION | REDUCTION | COMPLEXES | CARBONYL-COMPOUNDS | ARYL | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | POLYMETHYLHYDROSILOXANE | ALKENE HYDROBORATION | Synthesis | Ketones | Asymmetry | Aromatic compounds | Ligands | Hydrosilylation | Iron | Coordination compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 2, pp. 615 - 618
A highly regio‐ and enantioselective cobalt‐catalyzed sequential hydrosilylation/hydrogenation of alkynes was developed to afford chiral silanes. This one‐pot... 
hydrosilylation | silanes | cobalt | hydrogenation | alkynes | HYDROBORATION | MECHANISM | COMPLEXES | HETEROAROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | 1,1-DISUBSTITUTED ALKENES | LIGANDS | OLEFINS | TRANS ADDITION | EFFICIENT | ASYMMETRIC ALKENE HYDROGENATION | Hydrogenation | Silanes | Hydrogen storage | Hydrosilylation | Enantiomers | Cobalt | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 36, pp. 10839 - 10843
A pyridinebis(oxazoline) cobalt complex is a very efficient precatalyst for the hydrosilylation of terminal alkynes with Ph2SiH2, providing α‐vinylsilanes with... 
hydrosilylation | cobalt | hydroboration | vinylsilanes | alkynes | MECHANISM | SILICON | C(SP)-H BORYLATION | TERMINAL ALKYNES | IRON CATALYSTS | COPPER(I)-CATALYZED REACTION | CHEMISTRY, MULTIDISCIPLINARY | METHYL-GROUP | RUTHENIUM COMPLEXES | STEREOSELECTIVE HYDROSILYLATION | ALKENE HYDROSILYLATION | Cobalt | Pyridine | Pyridines | Hydroboration | Catalysts | Regioselectivity | Hydrosilylation | Selectivity | Cobalt compounds | Alkynes
Journal Article