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Nature Chemistry, ISSN 1755-4330, 02/2016, Volume 8, Issue 3, pp. 209 - 219
Exploiting the reactivity of one functional group within a molecule to generate a reaction at a different position is an ongoing challenge in organic... 
CATALYZED HYDROBORATION | CHAIN-WALKING | ALLYLIC ALCOHOLS | INTERNAL ALKENES | HECK ARYLATIONS | UNSATURATED ALCOHOLS | BIFUNCTIONAL CATALYST | C-H ACTIVATION | NONCONJUGATED DIENES | CHEMISTRY, MULTIDISCIPLINARY | TRANSMETALATION REACTIONS | Organic chemistry | Inorganic chemistry | Chemical Sciences
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 35, pp. 11254 - 11257
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 04/2019, Volume 141, Issue 15, pp. 6152 - 6156
Visible light-mediated photocatalytic organic transformation has drawn significant attention as an alternative process for replacing thermal reactions.... 
RESVERATROL | PHOTOISOMERIZATION | CONSTRUCTION | CARBON NITRIDE | MECHANISMS | PHOTOCHEMICAL-REACTIONS | CATALYTIC Z | CRYSTALLINE | CHEMISTRY, MULTIDISCIPLINARY | Z-ALKENES | METATHESIS
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2018, Volume 2018, Issue 25, pp. 3317 - 3325
Novel chiral gold(III) complexes, based on bisoxazoline (BOX) and 2‐pyridyl‐(–)menthol ligands, were prepared and characterised (X‐ray), and their catalytic... 
Cycloaddition | Isomerization | Homogeneous catalysis | Diastereoselectivity | GOLD(I)-CATALYZED RING EXPANSION | COMPLEXES | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | REARRANGEMENT | KETONES | ALKENES | INTERMOLECULAR REACTIONS | GOLD-CATALYZED CYCLOISOMERIZATION | PROPARGYLIC CARBOXYLATES | ENYNES | Cyclopropane compounds
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2014, Volume 20, Issue 43, pp. 13918 - 13922
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2017, Volume 82, Issue 19, pp. 9955 - 9977
Iteratively executed with exquisite spatial and temporal control, the selective isomerization of polarized alkenes underpins a plethora of complex biological... 
PUSH-PULL ALKENES | VISIBLE-LIGHT | CIS-TRANS ISOMERIZATION | COUPLED ELECTRON-TRANSFER | LIGHT PHOTOREDOX CATALYSIS | CHEMISTRY, ORGANIC | LEWIS-ACID CATALYSIS | ASYMMETRIC HYDROGENATION | PHOTOCHEMICAL-REACTIONS | HULA-TWIST | ALPHA,BETA-UNSATURATED NITRILES | Usage | Chemical properties | Olefins | Isomerization | Photocatalysis | Ultraviolet radiation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2018, Volume 57, Issue 12, pp. 3168 - 3172
Journal Article
Organic Letters, ISSN 1523-7060, 06/2015, Volume 17, Issue 11, pp. 2716 - 2719
Generated in situ from air-stable cobalt precursors or readily synthesized using NaHBEt3, (PPh3)(3)CoH(N-2) was found to be an effective catalyst for the... 
TERTIARY BORONIC ESTERS | MOLECULAR-STRUCTURE | CHEMISTRY, ORGANIC | REGIO | ARYL ALKENES | PINACOLBORANE | C-H BORYLATION | ASYMMETRIC HYDROBORATION | HYDRIDODINITROGENTRIS(TRIPHENYLPHOSPHINE)COBALT(I) | TERMINAL SELECTIVITY | NITROGEN COMPLEXES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 17, pp. 5723 - 5728
We report herein that thermodynamic and kinetic isomerization of alkenes can be accomplished by the combination of visible light with Co catalysis. Utilizing... 
alkene isomerization | cobalt | visible light catalysis | photosynthesis | DEBROMINATION | MONOISOMERIZATION | MECHANISM | COMPLEXES | THERMAL-DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | 1-ALKENES | HYDROGEN | BITE ANGLE | EFFICIENT | TERMINAL ALKENES | Thermodynamics | Phytochemistry | Olefins | Isomerization | Catalysis | Photosynthesis | Cobalt | Transformation | Stability | Alkenes | Ligands | Isomers | Communications | Communication
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2013, Volume 135, Issue 46, pp. 17393 - 17400
A one-pot three-step reaction, isomerization/hydroformylation/hydrogenation of internal alkenes to n-alcohols, was accomplished by employing a Rh/Ru... 
DEHYDROGENATION | HYDROGENATION | RHODIUM CATALYSTS | LIGANDS | CARBON-MONOXIDE | LINEAR ALDEHYDES | COMPLEXES | OLEFINS | REGIOSELECTIVE ISOMERIZATION-HYDROFORMYLATION | BITE ANGLE | CHEMISTRY, MULTIDISCIPLINARY | Measurement | Olefins | Analysis | Chemical properties | Catalysis | Structure | Hydrogenation | Surface energy
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 06/2018, Volume 2018, Issue 22, pp. 2584 - 2588
N‐heterocyclic carbenes (NHCs) are a highly important class of ligands in transition metal‐mediated catalysis. Recently, a modification of the NHCs has... 
Abnormal carbenes | Palladium | N‐Heterocyclic olefins | Structure elucidation | Isomerization | N-Heterocyclic olefins | Transition metal compounds | DVD | Alkenes | Ligands | Catalysis | Coordination compounds | Carbenes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2014, Volume 136, Issue 17, pp. 6215 - 6218
In the asymmetric hydrovinylation (HV) of an E/Z-mixture of a prototypical 1,3-diene with (S,S)-(DIOP)­CoCl2 or (S,S)-(BDPP)­CoCl2 catalyst in the presence of... 
DIENYLATION | ALKENE ISOMERIZATION | HYDROGENATION | ORGANOTITANIUM | METAL-CATALYSTS | 1,3-DIENES | COMPLEXES | BOND | CHEMISTRY, MULTIDISCIPLINARY | STEREOSELECTIVE SYNTHESIS | ASYMMETRIC HYDROVINYLATION | Polyenes - chemistry | Catalysis | Ethylenes - chemistry | Isomerism | Cobalt - chemistry | Research | Isomerization | Analysis | Nuclides | Ethylene | Ligands | Hydrides | Asymmetry | Catalysts | Communication
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 11/2016, Volume 2016, Issue 32, pp. 5415 - 5422
Stereoselective allyl isomerization and regiospecific allyl arylation reactions of allylarenes with a catalytic system comprising nickel(II) with an aryl... 
C‐H activation | Nickel | Allylic compounds | Cross‐coupling | Isomerization | C-H activation | Cross-coupling | ARYL GRIGNARD-REAGENTS | ALKENE ISOMERIZATION | REGIOSELECTIVE HECK ARYLATION | CHEMISTRY, ORGANIC | OXIDATIVE ARYLATION | IONIC LIQUID | IRON | ALKYL-HALIDES | BOND ACTIVATION | OLEFIN ISOMERIZATIONS | Chemical tests and reagents | Olefins
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 72, pp. 10010 - 10013
We report a method for palladium-catalysed chain-running isomerization of terminal and internal alkenes. Using an air-stable... 
TRANS-2-ALKENES | MONOISOMERIZATION | COMPLEXES | BIFUNCTIONAL CATALYST | CYCLOISOMERIZATION | OLEFIN ISOMERIZATION | SILYL ETHERS | OLIGOMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | 1-ALKENES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 3, pp. 801 - 804
The cobalt‐catalyzed selective isomerization of terminal alkenes to the thermodynamically less‐stable (Z)‐2‐alkenes at ambient temperatures takes place by a... 
cobalt | stereoselectivity | alkenes | isomerization | double‐bond migration | Stereoselectivity | Alkenes | Cobalt | Isomerization | Double-bond migration | COMPLEXES | OLEFINS | double-bond migration | CHEMISTRY, MULTIDISCIPLINARY | 1-ALKENES | Thermodynamics | Hydrogen | Olefins | Ambient temperature | Ligands | Formations | Materials selection | Hydrogen atoms | Terminals
Journal Article