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alkene isomerization-hydroboration (30) 30
chemistry, multidisciplinary (26) 26
hydroboration (22) 22
alkenes (19) 19
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iron (15) 15
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pinacolborane (9) 9
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selective hydroboration (6) 6
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functionalization (5) 5
markovnikov-selective hydroboration (5) 5
organic-synthesis (5) 5
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eisen (4) 4
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1,3,2-benzodioxaborole (2) 2
1,3-dienes (2) 2
activation (2) 2
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Organic Letters, ISSN 1523-7060, 06/2015, Volume 17, Issue 11, pp. 2716 - 2719
Generated in situ from air-stable cobalt precursors or readily synthesized using NaHBEt3, (PPh3)(3)CoH(N-2) was found to be an effective catalyst for the... 
TERTIARY BORONIC ESTERS | MOLECULAR-STRUCTURE | CHEMISTRY, ORGANIC | REGIO | ARYL ALKENES | PINACOLBORANE | C-H BORYLATION | ASYMMETRIC HYDROBORATION | HYDRIDODINITROGENTRIS(TRIPHENYLPHOSPHINE)COBALT(I) | TERMINAL SELECTIVITY | NITROGEN COMPLEXES
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 10/2019, Volume 9, Issue 10, pp. 9034 - 9044
The remote, diastereoselective hydroboration of 2- and 3-substituted indenes with a 2,2':6',2"-terpyridine cobalt alkyl precatalyst is described that maintains... 
chain walking | ALPHA-OLEFINS | HYDROFUNCTIONALIZATION | HYDROGENATION | hydroboration | diasteroselective | COMPLEXES | indanes | SECONDARY | CHEMISTRY, PHYSICAL | ASYMMETRIC HYDROBORATION | CROSS-COUPLING REACTIONS | MINIMALLY FUNCTIONALIZED ALKENES | MARKOVNIKOV-SELECTIVE HYDROBORATION | BOND | cobalt catalysis
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 34, pp. 4726 - 4729
A bipyridiyl-oxazoline cobalt catalyst (BPOCoCl2)-B-tBu has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and... 
ALKENE ISOMERIZATION-HYDROBORATION | CHEMO | COMPLEXES | IRON | ALKYNES | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 39, pp. 13929 - 13935
A highly efficient strategy for remote reductive cross-electrophile coupling has been developed through the ligand-controlled nickel migration/arylation. This... 
ARYL BROMIDES | HALIDES | NUCLEOPHILES | CATALYSIS | ALKENE ISOMERIZATION-HYDROBORATION | SECONDARY ALKYL ELECTROPHILES | NICKEL | NEGISHI ARYLATIONS | CARBOXYLATION | H BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | Arylation | Ligands | Usage | Research | Electrophiles
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 04/2017, Volume 53, Issue 34, pp. 4726 - 4729
A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as... 
Selectivity | Hydroboration | Alkenes | Catalysts | Cobalt
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2015, Volume 137, Issue 50, pp. 15600 - 15603
The selective preparation of 1,1,1-tris­(boronates) from vinylarenes and bis­(pinacolato)­diboron is described. The reactions occur at ambient temperature with... 
ALKENE ISOMERIZATION-HYDROBORATION | ASYMMETRIC-SYNTHESIS | CONSTRUCTION | COMPLEXES | SP-CARBON | DIBORYLATION | REACTIVITY | DIBORATION | CHEMISTRY, MULTIDISCIPLINARY | H ACTIVATION | COBALT
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 06/2017, Volume 53, Issue 53, pp. 7333 - 7336
Addition of NaEt BH to ( DI)CoCl affords the corresponding monohydride, ( DI)CoH. X-ray diffraction and DFT calculations indicate that this compound possesses... 
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 08/2018, Volume 83, Issue 16, pp. 9442 - 9448
Highly effective hydroboration precatalyst is developed based on a cobalt­(II)-terpyridine coordination polymer (CP). The hydroboration of ketones, aldehydes,... 
CARBENE | ALKENE ISOMERIZATION-HYDROBORATION | REDUCTION | AMINES | ALKYLATION | CHEMISTRY, ORGANIC | TRANSFER HYDROGENATION | LIGAND | MAGNESIUM-CATALYZED HYDROBORATION | DISCOVERY | HYDRIDE
Journal Article
Organic Letters, ISSN 1523-7060, 03/2017, Volume 19, Issue 5, pp. 969 - 971
A highly Markovnikov-selective, iron-catalyzed hydroboration of styrenes is reported using available oxazolinylphenyl picolinamide as the ligand to afford the... 
REGIOSELECTIVE HYDROBORATION | ALKENE ISOMERIZATION-HYDROBORATION | COBALT CATALYSTS | 1,1-DISUBSTITUTED ALKENES | LIGANDS | VINYL ARENES | CHEMISTRY, ORGANIC | ARYL ALKENES | PINACOLBORANE | ASYMMETRIC HYDROGENATION | TRANSITION-METALS
Journal Article
Chemical Reviews, ISSN 0009-2665, 02/2019, Volume 119, Issue 4, pp. 2876 - 2953
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 46, pp. 14369 - 14372
Well‐defined manganese complexes based on inexpensive, readily available ligands, 2,2′:6′,2′′‐terpyridine and its derivatives have been prepared and employed... 
manganese catalysis | hydroboration | alkenes | carbonyl compounds | Markovnikov selectivity | COBALT CATALYSTS | HYDROSILYLATION | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL SELECTIVITY | CROSS-COUPLING REACTIONS | 1,1-DISUBSTITUTED ALKENES | ARYL ALKENES | ISOMERIZATION-HYDROBORATION | CARBON-DIOXIDE | GRIGNARD-REAGENTS | Ketones | Aldehydes | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2017, Volume 139, Issue 19, pp. 6526 - 6529
We report a cobalt-catalyzed asymmetric hydroboration/cyclization of 1,6-enynes with catalysts generated from Co­(acac)2 and chiral bisphosphine ligands and... 
BORYLATIVE CYCLIZATION | ALKENE ISOMERIZATION-HYDROBORATION | RHODIUM | HYDROGENATION | FORMAL SYNTHESIS | COMPLEXES | HYDROSILYLATION | TERMINAL ALKYNES | ENYNE CYCLOISOMERIZATION | REDUCTIVE CYCLIZATION | CHEMISTRY, MULTIDISCIPLINARY | Borane | Catalysts | Esters | Chemical properties | Ring formation (Chemistry) | Research | Asymmetric induction (Stereochemistry) | Cobalt
Journal Article
by Xi, Tuo and Lu, Zhan
ACS Catalysis, ISSN 2155-5435, 02/2017, Volume 7, Issue 2, pp. 1181 - 1185
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 02/2016, Volume 45, Issue 7, pp. 2823 - 2828
Development of CCC-NHC pincer Co complexes via transmetalation from Zr is reported. Formation of these air-stable Co(iii) complexes was achieved through use of... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 53, pp. 7333 - 7336
Addition of NaEt3BH to ((DI)-D-Ph2PPr)CoCl2 affords the corresponding monohydride, ((DI)-D-Ph2PPr)CoH. X-ray diffraction and DFT calculations indicate that... 
ALKENE ISOMERIZATION-HYDROBORATION | CROSS-COUPLING REACTIONS | 1,1-DISUBSTITUTED ALKENES | MAGNESIUM CATALYSIS | 1,3,2-BENZODIOXABOROLE | COMPLEXES | HYDROSILYLATION | ESTERS | PINACOLBORANE | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL SELECTIVITY | Hydroboration | Mathematical analysis | Nitriles | Hydrides | X ray diffraction | Cobalt | Radicals | Alkynes
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2018, Volume 57, Issue 23, pp. 14671 - 14685
This work reports the first successful isolation and full characterization of cobalt­(I) complexes of 5-aryl-2-iminopyrrolyl ligands. In one approach, when... 
COORDINATION CHEMISTRY | ALKENE ISOMERIZATION-HYDROBORATION | BIS(IMINOPYRROLYL) COMPLEXES | MOLECULAR CALCULATIONS | EFFECTIVE CORE POTENTIALS | DIIMINE | PINCER COMPLEXES | REACTIVITY | IRON | GAUSSIAN-BASIS SETS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic Letters, ISSN 1523-7060, 12/2018, Volume 20, Issue 24, pp. 7840 - 7845
An NHC-supported Co­(I) catalyst has been developed for selective Markovnikov hydroboration of vinylarenes under mild reaction conditions. The hydroboration... 
REGIOSELECTIVE HYDROBORATION | ALKENE ISOMERIZATION-HYDROBORATION | COBALT CATALYSTS | COUPLING REACTIONS | CHEMISTRY, ORGANIC | CATALYTIC ASYMMETRIC HYDROBORATION | H BONDS | ALKYLBORONIC ESTERS | B-H | BORYLATION | ALKYL-HALIDES
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 2018, Volume 42, Issue 20, pp. 16456 - 16459
A highly selective anti-Markovnikov hydroboration reaction of alkenes with bis(pinacolato)diboron catalyzed by 4-cyanopyridine has been described. This... 
CATALYZED HYDROBORATION | HALIDES | COBALT CATALYSTS | 1,1-DISUBSTITUTED ALKENES | CROSS-COUPLING REACTION | VINYL ARENES | PINACOLBORANE | ISOMERIZATION-HYDROBORATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION
Journal Article
by Wang, ZC and Shen, D and Gao, J and Jia, X and Xu, YJ and Shi, SL
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2019, Volume 55, Issue 60, pp. 8848 - 8851
An unprecedented base-catalysed reductive relay hydroboration of allylic alcohols is described. Commercially available (BuLi)-Bu-n was found to be a robust... 
ALKENE ISOMERIZATION-HYDROBORATION | COUPLING REACTIONS | ROBUSTNESS SCREEN | RAPID ASSESSMENT | SECONDARY | BORONIC ESTERS | METAL | ALKYNES | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE HYDROBORATION
Journal Article
by Zhang, YL and Xu, XF and Zhu, SL
NATURE COMMUNICATIONS, ISSN 2041-1723, 04/2019, Volume 10, Issue 1, pp. 1752 - 9
Direct (utilize easily available and abundant precursors) and selective (both chemo- and regio-) aliphatic C-H functionalization is an attractive mean with... 
FUNCTIONALIZATION | ELECTRON-TRANSFER | CROSS-COUPLINGS | CHAIN WALKING | MULTIDISCIPLINARY SCIENCES | HYDROSILYLATION | INTERNAL OLEFINS | BOND FORMATION | ISOMERIZATION-HYDROBORATION | REMOTE | HYDROARYLATION | Thiols | Amines | Alkenes | Regioselectivity | Amides | Aliphatic compounds | Alcohols | Regeneration | Organic chemistry | Reagents | Nickel | Chemical synthesis | Alkynes
Journal Article
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