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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 5, pp. 1872 - 1875
Journal Article
Organic Letters, ISSN 1523-7060, 06/2018, Volume 20, Issue 11, pp. 3385 - 3389
The generation and fate of 2I–VII,3I–VII,6II–VII-icosa-O-methyl-β-cyclomaltoheptaos-6I-O-yl radical under reductive conditions is described. Two radical... 
REARRANGEMENT | ALPHA-CYCLODEXTRIN | RING EXPANSION | CONSTRUCTION | CHEMISTRY, ORGANIC | SYSTEMS | FRAGMENTATION | CYCLIZATION | DELIVERY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 41, pp. 12619 - 12623
Journal Article
Free Radical Biology and Medicine, ISSN 0891-5849, 01/2019, Volume 130, pp. 568 - 575
Biomolecule (lipid and protein) oxidation products formed in plant cells exposed to photooxidative stress play a crucial role in the retrograde signaling and... 
Alkoxyl radical | Hydroperoxide | Reactive oxygen species | Photosystem | Alkyl radical | Peroxyl radical | OXIDATION | BIOCHEMISTRY & MOLECULAR BIOLOGY | CHLOROPLASTS | BIOCHEMISTRY | ENDOCRINOLOGY & METABOLISM | PHOTOSYSTEM-II | DYNAMICS | SINGLET OXYGEN | GENERATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2018, Volume 360, Issue 22, pp. 4341 - 4347
Journal Article
by Gu, YR and Duan, XH and Chen, L and Ma, ZY and Gao, P and Guo, LN
ORGANIC LETTERS, ISSN 1523-7060, 02/2019, Volume 21, Issue 4, pp. 917 - 920
An efficient iron-catalyzed intermolecular remote C(sp(3))-H heteroarylation of alkyl ketones has been developed via an iminyl radical-triggered... 
FUNCTIONALIZATION | ARYLATION | ACYL OXIMES | CHEMISTRY, ORGANIC | HYDROGEN-ATOM | ALKOXYL RADICALS | IRON | QUINOXALIN-2(1H)-ONES | RING-CLEAVAGE | C-H BONDS | CYCLIZATION
Journal Article
Tetrahedron, ISSN 0040-4020, 12/2016, Volume 72, Issue 48, pp. 7699 - 7714
4-Pentenoxyl radicals cyclize 2,3- -selectively, when substituted by an allylic hydroxy, acetyloxy, or benzoyloxy group. Additional substituents increase or... 
Reactive conformer | Polar effect | Tetrahydrofuran | Alkoxyl radical | Stereoselective synthesis | RING-CLOSURE REACTIONS | CHEMISTRY, ORGANIC | CENTERED RADICALS | CYCLIZATIONS | TETRAHYDROFURANS | SILYL ENOL ETHERS | CONSTRUCTION | STEREOSELECTIVE-SYNTHESIS | POLYHYDROXYLATED PYRROLIZIDINE ALKALOIDS | DERIVATIVES | SELECTIVITY | Bonds | Olefins | Chemical properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2017, Volume 139, Issue 33, pp. 11519 - 11526
Sulfur-based thiyl radicals are known to be involved in a wide range of chemical and biological processes, but they are often highly reactive, which makes them... 
OXIDATION | SULFUR K-EDGE | SUBSTITUENT | RESONANCE | BIOCHEMISTRY | ALKOXYL | SPECTRA | CHEMISTRY, MULTIDISCIPLINARY | GENERALIZED GRADIENT APPROXIMATION | ELECTRONIC-STRUCTURE | MOLECULES | INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 12, pp. 2989 - 2994
Journal Article
Synlett, ISSN 0936-5214, 08/2014, Volume 25, Issue 13, pp. 1803 - 1816
Abstract This account describes the results of our recent mechanistic studies on unimolecular C–C bond fragmentation (β-scission and O -neophyl rearrangement)... 
account | alkoxyl radicals | radical reactions | β-cleavage | O-neophyl rearrangement | solvent effects | hydrogen atom transfer | ELECTRON-SPIN-RESONANCE | LOG K-VALUES | CHEMISTRY, ORGANIC | TERT-BUTOXYL | ABSOLUTE RATE CONSTANTS | LASER FLASH-PHOTOLYSIS | ABSTRACTION REACTIONS | BETA-SCISSION REACTION | 1,1-DIARYLALKOXYL RADICALS | CUMYLOXYL RADICALS | beta-cleavage
Journal Article
Synlett, ISSN 0936-5214, 08/2019, Volume 30, Issue 13, pp. 1489 - 1495
Abstract Alkoxyl radicals are highly reactive species which rapidly react by hydrogen atom transfer (HAT) or β-fragmentation to afford a carbon-centered... 
synpacts | alkoxyl radicals | ether synthesis | ELECTRON-SPIN-RESONANCE | VISIBLE-LIGHT PHOTOCATALYSIS | anti-Markovnikov addition | CHEMISTRY, ORGANIC | alkenes | MARKOVNIKOV | FUNCTIONALIZATION | N-alkoxypyridinium | METHOXYLATION | PHOTOCHEMISTRY | photoredox catalysis | GENERATION | ARYL | METAL-FREE | Organic chemistry | Chemical Sciences
Journal Article
Journal Article
Organic Letters, ISSN 1523-7060, 12/2007, Volume 9, Issue 26, pp. 5569 - 5572
A DFT study of model cyclohexyloxy radicals (8a−c, 9) show that (a) the presence of an adjacent oxygen atom, and (b) α-substituents on the cyclohexyl ring,... 
THERMOLYSIS | ANOMERIC ALKOXYL RADICALS | QINGHAOSU | DRUGS | CHEMISTRY | CHEMISTRY, ORGANIC | ANTIMALARIAL PEROXIDES | FRAGMENTATION | ARTEMISININ | DERIVATIVES | DECOMPOSITION PRODUCTS | Models, Molecular | Thermodynamics | Cyclohexanes - chemistry | Cyclization | Free Radicals
Journal Article