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Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 37, pp. 11947 - 11951
Metal‐catalyzed intramolecular C−H amination of alkyl azides constitutes an appealing approach to alicyclic amines; challenges remain in broadening substrate... 
porphyrinoids | iron | C−H amination | homogeneous catalysis | alkyl azides | C-H amination | COMPLEX | HYDROCARBONS | H BOND AMINATION | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | AZIDATION | AMINES | ARYL AZIDES | Heterocyclic compounds | Catalysis | Porphyrins | Amines | Regioselectivity | Hydrogen bonds | Amination | Natural products | Iron | Tropane | Substrates | Nicotine
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2013, Volume 52, Issue 31, pp. 8031 - 8036
New horizons in the utility of azides: The rhodium‐catalyzed intermolecular direct CH amination of arenes with alkyl azides provides a convenient route to... 
alkyl nitrenoids | CH amination | azides | rhodium catalysis | aniline derivatives | C-H amination | Utilities | Ketones | Rhodium | Aniline | Aromatic compounds | Catalysis | Benzamide | Functional groups
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 04/2015, Volume 2015, Issue 12, pp. 2706 - 2717
A mild and convenient method for the synthesis of amides has been explored by using secondary alcohols, Cu(ClO4)2·6H2O as a catalyst, and trimethylsilyl azide... 
Azides | Amides | Chemo­selectivity | Synthetic methods | Copper | Alcohols | Chemoselectivity | CLICK CHEMISTRY | DIRECT CONVERSION | CHEMISTRY, ORGANIC | BOND FORMATION | ORGANIC AZIDES | OXIDATIVE TRANSFORMATION | AZIDATION | COUPLING REACTIONS | PRIMARY AMINES | C-H | ALKYL AZIDES | Chemotherapy | Chemical tests and reagents | Quinone | Cancer
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 08/2006, Volume 71, Issue 17, pp. 6697 - 6700
A practical, rapid, and efficient microwave (MW) promoted synthesis of various azides, thiocyanates, and sulfones is described in an aqueous medium. This... 
HALIDES | CATALYSIS | AMINES | CHEMISTRY | CHEMISTRY, ORGANIC | N-HETEROCYCLIZATION | EFFICIENT | BROMIDES | SOLVENT | ALKYL AZIDES | WATER | Thermal properties | Nucleophilic reactions | Chemical properties | Phase transformations (Statistical physics) | Analysis | Sulfones
Journal Article
by Shin, K and Baek, Y and Chang, S
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 07/2013, Volume 52, Issue 31, pp. 8031 - 8036
  New horizons in the utility of azides: The rhodium-catalyzed intermolecular direct CH amination of arenes with alkyl azides provides a convenient route to... 
VICARIOUS NUCLEOPHILIC-SUBSTITUTION | IMIDO COMPLEXES | ROOM-TEMPERATURE | INTRAMOLECULAR SCHMIDT REACTIONS | METAL-FREE CONDITIONS | H BOND AMINATION | azides | ORGANIC AZIDES | CHEMISTRY, MULTIDISCIPLINARY | rhodium catalysis | alkyl nitrenoids | CH amination | STAUDINGER LIGATION | SECONDARY-AMINES | NITRENE COMPLEXES | aniline derivatives
Journal Article
by Zhu, J and Li, R and Su, Y and Gu, PM
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 05/2019, Volume 84, Issue 9, pp. 5813 - 5820
Rh-catalyzed intramolecular condensation of the benzyl azides with alpha-aryldiazoesters was explored. The reaction proceeded through the nucleophilic attack... 
CHEMISTRY, ORGANIC | GENERATION | ACIDS | DERIVATIVES | CYCLIZATION | ALKYL AZIDES
Journal Article
Chemical Science, ISSN 2041-6520, 2019, Volume 10, Issue 11, pp. 3202 - 3207
The catalytic enantioselective intramolecular C(sp(3))-H amination of aliphatic azides represents an efficient method for constructing chiral saturated cyclic... 
PHOSPHORYL AZIDES | FUNCTIONALIZATION | NITRENE TRANSFER | PYRROLIDINE | BOND AMINATION | AZIRIDINATION | COMPLEXES | ARYL AZIDES | C(SP)-H | CHEMISTRY, MULTIDISCIPLINARY | ALKYL AZIDES
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 62, pp. 8798 - 8801
Visible light sensitization of benzoyl azides was examined in reaction with N-phenylmethacrylamides to afford biologically important oxindoles and... 
CATALYSIS | PHENYL AZIDE | PHOTOREDOX | NITROGEN-SOURCE | C-H AMIDATION | PHOTOCHEMISTRY | ACYL AZIDES | PHOTOLYSIS | CHEMISTRY, MULTIDISCIPLINARY | ALKYL AZIDES | SINGLET
Journal Article
Organic Letters, ISSN 1523-7060, 03/2018, Volume 20, Issue 6, pp. 1643 - 1646
Cyclic ketones tethered with a vinyl azide group undergo a Schmidt-hydrolysis sequence to give secondary lactams bearing a ketone side chain. Secondary lactams... 
CYCLOADDITION | 2H-AZIRINES | AMIDE SYNTHESIS | CHEMISTRY, ORGANIC | CYCLIZATION | ACCESS | ALKYL AZIDES | TRIFLUOROMETHYLATION
Journal Article
Organometallics, ISSN 0276-7333, 09/2017, Volume 36, Issue 18, pp. 3471 - 3476
A ruthenium bisammine complex was formed in the reaction of ruthenium 1,4-dibenzyltetraazadiene complex with primary amines at room temperature, which was a... 
IMIDO COMPLEXES | CYCLOADDITION | DEMANDING CYCLOPENTADIENYL LIGANDS | ZIRCONIUM | AMINES | CRYSTAL-STRUCTURE | BENZYL AZIDES | CHEMISTRY, ORGANIC | HALF-SANDWICH COMPLEXES | N-UNSUBSTITUTED IMINES | ALKYL AZIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic Letters, ISSN 1523-7060, 01/2011, Volume 13, Issue 1, pp. 114 - 117
Tetrasubstituted 1,4-dien-3-ones undergo Nazarov cyclization at low temperature, followed by reaction with organic azides via an apparent [3 + 3]-cycloaddition... 
CHEMISTRY, ORGANIC | REARRANGEMENTS | ALKYL AZIDES
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 37, pp. 6902 - 6907
A conversion of o-phenylenediamines into benzotriazoles was achieved at room temperature using tert-butyl nitrite. The optimized conditions are also well... 
BORONIC ACIDS | ORGANIC-SYNTHESIS | SULFONYL AZIDES | ONE-POT SYNTHESIS | TRIFLUOROMETHANESULFONYL AZIDE | CHEMISTRY, ORGANIC | BOND FORMATION | ARYL-N-NITROSAMINES | ACYL AZIDES | EFFICIENT | ALKYL AZIDES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 6, pp. 1104 - 1110
The dual behaviour of acyl azides in transition‐metal‐catalyzed direct C−H amidation is investigated. Variously substituted acyl azides reacted smoothly with... 
C−H functionalization | amidation reaction | acyl azide | 7-azaindole | selective activation | C-H AMIDATION | ARENES | CHEMISTRY, ORGANIC | C-H functionalization | ORGANIC AZIDES | PALLADIUM-CATALYZED AMINATION | DIRECTING GROUPS | FUNCTIONALIZATION | COUPLING REACTIONS | BOND ACTIVATION | CHEMISTRY, APPLIED | ACCESS | ALKYL AZIDES | Nitrogen | Controllability | Derivatives
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 12/2014, Volume 2014, Issue 34, pp. 7577 - 7581
A synthetic strategy towards highly substituted α‐silyl homoallylic amines was discovered. The key event is the unique synthesis of N‐unsubstituted... 
Azides | Silicon | Synthetic methods | Ruthenium | Amines | ROUTE | ENANTIOSELECTIVE SYNTHESIS | ONE-POT | STRATEGY | CHEMISTRY, ORGANIC | ALDEHYDES | HOMOPROPARGYLIC AMINES | LITHIATION | UTILITY | ALKYL AZIDES
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2006, Volume 35, Issue 2, pp. 146 - 156
The azide group has a diverse and extensive role in organic chemistry, reflected in the power of azide anion as a strong nucleophile, the role of organic... 
HYDROXY AZIDES | KETONES | ETHERS | INTRAMOLECULAR SCHMIDT REACTION | CARBOCATIONS | ALIPHATIC AZIDES | LACTAMS | ASYMMETRIC TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | ALKYL AZIDES | ALKALOIDS | Alcohols - chemistry | Alkenes - chemistry | Cyclization | Stereoisomerism | Ketones - chemistry | Molecular Structure | Azides - chemical synthesis | Azides - chemistry | Electrons
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 11/2015, Volume 2015, Issue 31, pp. 6917 - 6923
Reactions of functionalized [CN, CO2Et, C(O)NHR, C(S)NR1R2] derivatives of thiomalonic acid and 2‐arylthioacetamides with sulfonyl azides were shown to give... 
Azides | Synthetic methods | Thioamides | Sulfonamides | ALKYL | CHEMISTRY, ORGANIC | REARRANGEMENTS | ACCESS | Nitriles | Pyridine | Nitrogen
Journal Article