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alkylarenes (61) 61
oxidation (28) 28
chemistry, organic (22) 22
chemistry, multidisciplinary (16) 16
chemistry, physical (16) 16
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catalysis (13) 13
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alkylarene (5) 5
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1,4-addition reactions (2) 2
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Chemistry – A European Journal, ISSN 0947-6539, 07/2015, Volume 21, Issue 31, pp. 10932 - 10932
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 2015
Journal Article
Organic Letters, ISSN 1523-7060, 01/2019, Volume 21, Issue 1, pp. 65 - 69
A copper-catalyzed route to alpha-substituted, primary benzylamines by C-H functionalization of alkylarenes is described. The method directly affords the amine... 
AMINES | BONDS | ALKYLARENES | ARYLATION | SECONDARY | AMIDATION | CHEMISTRY, ORGANIC | C-H AMINATION | ALKYL-HALIDES
Journal Article
Chemical Science, ISSN 2041-6520, 2019, Volume 10, Issue 4, pp. 1207 - 1211
A Cu-catalyzed strategy has been developed that harnesses a radical relay mechanism to intercept a distal C-centered radical for C-C bond formation. This... 
FUNCTIONALIZATION | OXIDATION | C(SP)-H BONDS | AMINATION | AMINES | ALKYLATION | OXYGENATION | ARYLATION | ALKYLARENES | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS
Journal Article
by Wang, HQ and Wang, Z and Huang, HC and Tan, JJ and Xu, K
ORGANIC LETTERS, ISSN 1523-7060, 11/2016, Volume 18, Issue 21, pp. 5680 - 5683
An efficient and practical (hetero)benzylic sp(3) C-H oxidation method has been developed. Notably, this user-friendly protocol employs inexpensive potassium... 
BENZYLIC OXIDATION | SECONDARY ALCOHOLS | HIGHLY EFFICIENT OXIDATION | CATALYZED OXIDATION | AMINES | ALKYLARENES | CHEMISTRY, ORGANIC | C-H OXIDATION | COPPER | MANGANESE COMPLEX | TERT-BUTYL HYDROPEROXIDE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2019, Volume 141, Issue 5, pp. 1887 - 1892
An enantioselective copper-catalyzed arylation of tertiary carbon-centered radicals, leading to quaternary all-carbon stereocenters, has been developed herein.... 
ARYL BROMIDES | FUNCTIONALIZATION | ALKENES | ASYMMETRIC-SYNTHESIS | COUPLING REACTION | ALKYLARENES | INTERMOLECULAR TRIFLUOROMETHYLARYLATION | AZACALIXAROMATICS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ALKYL-HALIDES
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2018, Volume 140, Issue 39, pp. 12415 - 12423
A method to directly arylate toluene derivatives with aryl bromides to generate diarylmethanes, which are important building blocks in drug discovery, is... 
C(SP)-H BONDS | CROSS-COUPLING REACTIONS | STEREOSPECIFIC FORMATION | ACTIVATION | ALKYLARENES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZED DIARYLMETHANES | ARYLBORONIC ACIDS | ARYL CHLORIDES
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2017, Volume 56, Issue 21, pp. 13329 - 13336
To develop coordination polymers (CPs) as catalysts to selectively catalyze the reaction of C-H bond activation of arylalkanes to their homologous ketones,... 
NODES | METAL-ORGANIC FRAMEWORKS | ROBUST | CONVERSION | AMIDE | ALKYLARENES | SITES | AEROBIC OXIDATION | SEPARATION | MOFS | CHEMISTRY, INORGANIC & NUCLEAR | Ketones | Analysis | Chemical bonds | Chemical reactions | Chemical properties | Research | Polymers
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2015, Volume 56, Issue 49, pp. 6843 - 6845
The reaction of diverse alkylarenes with tribromoisocyanuric acid (0.34 mol equiv) in reflux EtOAc in the absence of any catalysts or light irradiation... 
Alkylarenes | Benzylic bromination | Radical reaction | Tribromoisocyanuric acid | ALKENES | KETONES | CHEMISTRY | CHEMISTRY, ORGANIC | HALOGENATION | ALKYLBENZENES | EFFICIENT | SOLVENT
Journal Article
Organic Letters, ISSN 1523-7060, 12/2017, Volume 19, Issue 23, pp. 6352 - 6355
Higher pi-extended naphthalene, contained in methylnaphthalenes, which could capture alkyl radicals via SOMO-LUMO interactions, enabled the development of... 
FUNCTIONALIZATION | FISCHER CARBENE COMPLEXES | GOLD | ACTIVATION | DIELS-ALDER REACTIONS | ALKYLARENES | ARYLATION | CHEMISTRY, ORGANIC | OLEFINS | PHYTOALEXIN | C-H BONDS
Journal Article
by Ang, WJ and Lam, Y
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 2015, Volume 13, Issue 4, pp. 1048 - 1052
A copper-catalyzed method for the oxidation of allylic and benzylic sp(3) C-H by aqueous tert-butyl hydroperoxide (T-Hydro) in water using a recyclable... 
MICELLAR SYSTEMS | NANOPARTICLES | ORGANIC-REACTIONS | ALKYLARENES | CHEMISTRY | CHEMISTRY, ORGANIC | DINUCLEAR COPPER CENTER | GENERATION | CATALYST | TERT-BUTYL HYDROPEROXIDE | EFFICIENT
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 2018, Volume 140, Issue 43, pp. 14059 - 14063
A method for direct cross coupling between unactivated C(sp(3))-H bonds and chloroformates has been accomplished via nickel and photoredox catalysis. A diverse... 
FUNCTIONALIZATION | ELECTRON-TRANSFER | REAGENTS | NICKEL | HYDROCARBONS | ARYLATION | ALKYLARENES | H BONDS | ARYL | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2018, Volume 74, Issue 36, pp. 4746 - 4753
A one-pot procedure for the synthesis of 5-benzoyl-8 -phthalazino[1,2- ]quinazolin-8-ones is achieved by an iodine-catalyzed reaction of 2-aminobenzohydrazides... 
Benzylic oxidation | Phthalazinoquinazoline | Hydroamination | Iodine-catalyzed | SELECTIVE OXIDATION | ALKYLARENES | CHEMISTRY, ORGANIC | CANCER | ANTITUMOR AGENTS | RING | AEROBIC OXIDATION | IONIC LIQUIDS | EFFICIENT | CYCLIZATION | MOLECULAR-OXYGEN | Oxidation-reduction reaction
Journal Article
Organic Letters, ISSN 1523-7060, 10/2010, Volume 12, Issue 19, pp. 4388 - 4391
Aryltrimethylammonium triflates and tetrafluoroborates were found to be highly reactive electrophiles in the Pd-catalyzed cross coupling with aryl Grignard... 
ACTIVATION | ONE-STEP TRANSFORMATIONS | TERT-BUTYL SULFONES | ALKYLARENES | NICKEL-INDUCED CONVERSION | CHEMISTRY, ORGANIC | OLEFINS | CARBON-CARBON BONDS | SUBSTITUTED UNSYMMETRICAL BIARYLS | CLEAVAGE | SALTS | Temperature | Molecular Structure | Catalysis | Quaternary Ammonium Compounds - chemistry | Palladium - chemistry | Mesylates - chemical synthesis
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 04/2007, Volume 349, Issue 6, pp. 861 - 864
A small amount of iron(III) chloride (2 mol %) catalyzes benzylic oxidations with tert‐butyl hydroperoxide (TBHP) as oxidant in pyridine. The corresponding... 
oxidation | catalysis | CH activation | iron | ferric chloride | carbonyl compounds | Ferric chloride | Carbonyl compounds | Iron | Oxidation | C-H activation | Catalysis | SELECTIVE OXIDATION | OXIDE | ALKYLARENES | COMPLEXES | CHEMISTRY, ORGANIC | SATURATED-HYDROCARBONS | FUNCTIONALIZATION | TBHP | HYDROGEN-PEROXIDE | GIF CHEMISTRY | BUTYLHYDROPEROXIDE | CHEMISTRY, APPLIED
Journal Article
Journal of Molecular Catalysis. A, Chemical, ISSN 1381-1169, 12/2014, Volume 395, pp. 494 - 499
Cobalt(II) phthalocyanine covalently immobilized on cellulose as a heterogeneous catalyst was synthesized and characterized. The catalyst showed good catalytic... 
Heterogeneous catalysis | Alkylarenes | Cobalt(II) phthalocyanine | Cellulose | Aerobic oxidation | ETHYLENEDIAMINE-FUNCTIONALIZED CELLULOSE | CHEMISTRY, PHYSICAL | POT 3-COMPONENT SYNTHESIS | SULFURIC-ACID | H2O2 OXIDATION | SECONDARY ALCOHOLS | NANOPARTICLES | KETONES | BENZALDEHYDE | IRON TETRASULFOPHTHALOCYANINE | Phthalocyanins | Chemical properties
Journal Article
by Tian, XZ and Ren, FP and Zhao, B and Ren, YL and Zhao, S and Wang, JJ
CATALYSIS COMMUNICATIONS, ISSN 1566-7367, 03/2018, Volume 106, pp. 44 - 49
HNO3 was demonstrated to be an effective catalyst for aerobic oxidation of benzylic se C-H bonds under additive-free conditions. A series of isochromans,... 
CARBON | Carbon-hydrogen bonds | Aerobic oxidation | ALKYLARENES | CHEMISTRY, PHYSICAL | N-HYDROXYPHTHALIMIDE | FERRIC NITRATE | Nitric acid | FUNCTIONALIZATION | ETHERS | ALCOHOL | Catalysis | NITROGEN-DIOXIDE
Journal Article
Catalysis Communications, ISSN 1566-7367, 07/2007, Volume 8, Issue 7, pp. 1112 - 1116
Alkyl and aryl sulfides are oxidized to the corresponding sulfoxides or sulfones in excellent yields with aqueous hydrogen peroxide in the presence of silica... 
Sulfide | Sulfoxide | Oxidation | Hydrogen peroxide | Sulfone | Silica sulfuric acid | silica sulfuric acid | ASYMMETRIC-SYNTHESIS | hydrogen peroxide | ALKYLARENES | oxidation | CHEMISTRY, PHYSICAL | CATALYST | GREEN | sulfoxide | ALCOHOLS | MILD | POTASSIUM-PERMANGANATE | SOLVENT-FREE | HYDROGEN-PEROXIDE | sulfide | sulfone | WATER
Journal Article
Scientific Reports, ISSN 2045-2322, 06/2015, Volume 5, Issue 1, p. 10360
A general strategy involving a novel and highly efficient aerobic benzylic oxidation promoted by cheap, reusable activated carbon in water is developed.... 
KETONES | SECONDARY BENZYLIC ALCOHOLS | DEHYDROGENATION | MULTIDISCIPLINARY SCIENCES | ALKYLARENES | COMPLEXES | EFFICIENT | DERIVATIVES | CATALYSTS | Activated carbon | Oxidation | Benign
Journal Article
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