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alkylboranes (51) 51
chemistry, multidisciplinary (28) 28
chemistry, organic (20) 20
catalysis (15) 15
copper (15) 15
conjugate addition (14) 14
aryl (13) 13
alkylborane (11) 11
palladium (11) 11
reagents (11) 11
transmetalation (11) 11
esters (10) 10
halides (10) 10
allylic substitution (9) 9
complexes (9) 9
phosphates (9) 9
index medicus (8) 8
ligands (8) 8
alkenes (7) 7
alkylation (7) 7
asymmetric catalysis (7) 7
chemical properties (7) 7
chemistry (7) 7
acids (6) 6
boron (6) 6
chemical bonds (6) 6
chemistry, inorganic & nuclear (6) 6
kupfer (6) 6
ligated boranes (6) 6
stereochemistry (6) 6
substitution (6) 6
alkynes (5) 5
article (5) 5
carbon (5) 5
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chemistry, physical (5) 5
derivatives (5) 5
enantiomers (5) 5
grignard-reagents (5) 5
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olefins (5) 5
organic-synthesis (5) 5
research (5) 5
rhodium (5) 5
allylic phosphates (4) 4
analysis (4) 4
carbenes (4) 4
cross-coupling reactions (4) 4
cross-couplings (4) 4
electron-spin resonance (4) 4
enantioselective synthesis (4) 4
hydroboration (4) 4
hydrogen-atom abstraction (4) 4
ketones (4) 4
ligand (4) 4
organoboranes (4) 4
organoboron compounds (4) 4
polarity reversal catalysts (4) 4
synthesis (4) 4
triethylsilane (4) 4
1,4-addition (3) 3
allylic compounds (3) 3
allylsilanes (3) 3
arylboronic acids (3) 3
asymmetrische katalyse (3) 3
bearing tertiary (3) 3
carboxylation (3) 3
chemical reactions (3) 3
conductor like screening model (3) 3
copper catalysis (3) 3
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n-heterocyclic carbene (3) 3
propargylic phosphates (3) 3
regioselectivity (3) 3
retention (3) 3
semi-empirical calculations (3) 3
stereoselective-synthesis (3) 3
structure (3) 3
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trialkylboranes (3) 3
universities and colleges (3) 3
3+2 cycloaddition (2) 2
alcohols (2) 2
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alkyl-halides (2) 2
alkylborane addition (2) 2
alkylboron (2) 2
allenes (2) 2
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allylsilane (2) 2
alpha-benzylboronic esters (2) 2
amine-boranes (2) 2
amine-boryl radicals (2) 2
aromatic compounds (2) 2
arylation (2) 2
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Journal of the American Chemical Society, ISSN 0002-7863, 04/2012, Volume 134, Issue 13, pp. 5794 - 5797
The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as directing groups in Ni-catalyzed Suzuki reactions has been... 
ALKYLBORANES | CHEMISTRY, MULTIDISCIPLINARY | TRANSMETALATION | STEREOCHEMISTRY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 38, pp. 13191 - 13193
The first invertive B-alkyl Suzuki−Miyaura coupling has been achieved. The coupling of enantioenriched α-(acylamino)benzylboronic esters with aryl bromides and... 
HALIDES | PALLADIUM | ACID | C-N | RETENTION | TRANSMETALATION | STEREOCHEMISTRY | ALKYLBORANES | ARYL | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2013, Volume 135, Issue 9, pp. 3303 - 3306
Stereospecific coupling of benzylic carbamates and pivalates with aryl- and heteroarylboronic esters has been developed. The reaction proceeds with selective... 
PALLADIUM | CARBON | ACIDS | TRIARYLMETHANES | TRANSMETALATION | ARYLATION | BONDS | OXIDATIVE-ADDITION | ALKYLBORANES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 05/2019, Volume 58, Issue 9, pp. 5369 - 5374
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2011, Volume 133, Issue 51, pp. 20738 - 20741
The stereochemical course of the stereospecific Suzuki–Miyaura coupling of enantioenriched α-(acetylamino)benzylboronic esters with aryl bromides can be... 
HALIDES | PALLADIUM | CROSS-COUPLINGS | REAGENTS | TRANSITION-METAL-COMPLEXES | TRANSMETALATION | ALPHA-(ACYLAMINO)BENZYLBORONIC ESTERS | ALKYLBORANES | ARYL | CHEMISTRY, MULTIDISCIPLINARY | STEREOCONTROLLED SYNTHESIS
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 08/2011, Volume 44, Issue 8, pp. 603 - 613
Using two transition metals to simultaneously catalyze a reaction can offer distinct opportunities for reactivity and selectivity when compared to using... 
HALIDES | GOLD | MECHANISM | COMPLEXES | DIMERIZATION-CARBOSTANNYLATION | ALKYLBORANES | ARYL | ALKYNES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | STILLE REACTION | Chemical bonds | Gold | Research | Chemical properties | Structure | Metal catalysts | Cross coupling | Transition metals | Rhodium | Catalysts | Nickel | Catalysis | Compatibility
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 85, pp. 11686 - 11689
A copper(I)-catalysed asymmetric allylic reduction enables a regio- and stereoselective transfer of a hydride nucleophile in an S(N)2'-fashion onto allylic... 
FORMIC-ACID | ENANTIOSELECTIVE SYNTHESIS | ALKYLATION | ESTERS | PHOSPHATES | ALKYLBORANES | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | SILYLATION | CATALYZED SUBSTITUTION | CONJUGATE ADDITION
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2017, Volume 53, Issue 85, pp. 11686 - 11689
A copper(i)-catalysed asymmetric allylic reduction enables a regio- and stereoselective transfer of a hydride nucleophile in an S 2'-fashion onto allylic... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 30, pp. 10605 - 10608
We found that trialkylphosphine organocatalysts promoted unprecedented anti-carboboration of alkynoates with alkyl-, alkenyl-, or arylboranes to form β-boryl... 
TERTIARY BORONIC ESTERS | SECONDARY ALCOHOLS | LITHIATION-BORYLATION | ALLYLIC PHOSPHATES | ACTIVATION | ORGANOZIRCONIUM REAGENTS | ALPHA-(ACYLAMINO)BENZYLBORONIC ESTERS | ALKYLBORANES | STEREOSELECTIVE-SYNTHESIS | INTRAMOLECULAR CYANOBORATION | CHEMISTRY, MULTIDISCIPLINARY | Chemical properties | Stereochemistry | Carbon compounds | Analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2011, Volume 133, Issue 36, pp. 14293 - 14300
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 36, pp. 10816 - 10820
Copper‐catalyzed enantioselective allyl–allyl coupling between allylboronates and either Z‐acyclic or cyclic allylic phosphates using a new chiral... 
copper | asymmetric catalysis | boron | synthetic methods | allylic compounds | REAGENTS | MECHANISM | ALKYLATION | STEREOGENIC CARBON CENTERS | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLINGS | CONSTRUCTION | CHLORIDES | ALKYLBORANES | CONJUGATE ADDITION | Phosphates | Catalysis | Enantiomers | Copper | Heterocyclic compounds | Ligands | Phenols | Coupling | Phenolic compounds
Journal Article
Nature Communications, ISSN 2041-1723, 2014, Volume 5, Issue 1, p. 5474
Non-aromatic nitrogen- and oxygen-containing heterocycles such as piperidines and pyrans are prevalent components of natural products and pharmaceutical drugs.... 
ENANTIOSELECTIVE PREPARATION | PALLADIUM | RETENTION | TRANSMETALATION | MULTIDISCIPLINARY SCIENCES | ESTERS | ALKYLBORANES | CARBON-CARBON | ARYL | INVERSION | Anabasine - chemistry | Anabasine - chemical synthesis | Stereoisomerism | Ligands | Molecular Structure | Catalysis | Palladium - chemistry | Paroxetine - chemical synthesis | Paroxetine - chemistry
Journal Article
Synthesis, ISSN 0039-7881, 11/2017, Volume 49, Issue 21, pp. 4753 - 4758
Abstract A tandem hydrocupration/allylation of alkenyl boronates efficiently proceeds with NHC-copper catalysts using hydrosilane and allyl phosphate as... 
special topic | tandem reaction | copper | allylic substitution | hydrocupration | homoallylic boronates | N-heterocyclic carbenes | SITE | REAGENTS | CARBON | ALLYLIC SUBSTITUTION-REACTIONS | CHEMISTRY, ORGANIC | TERTIARY | PHOSPHATES | ALKYLBORANES | BEARING | ARYL
Journal Article
Organometallics, ISSN 0276-7333, 04/2011, Volume 30, Issue 7, pp. 1776 - 1779
A transmetalation reaction between rhodium(III) and sp2- and sp3-hybridized organogold(I) compounds proceeds rapidly at ambient temperature (15 min to 6 h).... 
PALLADIUM | SUBSTITUTION | CROSS-COUPLING REACTIONS | COMPLEXES | CHEMISTRY, ORGANIC | ALKYLBORANES | ELIMINATION | ARYL | LIGAND | STILLE REACTION | HYDROARYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 01/2014, Volume 43, Issue 3, pp. 1305 - 1312
A series of novel Cu(I) N,S-heterocyclic carbene (NSHC) complexes [Cu(μ-Br)(NSHC)]2, [Cu(μ-X)(NSHC)]4 (X = Br or I), [(NSHC)2Cu(μ-Br)2Cu(NSHC)], and... 
Journal Article
Chemistry Letters, ISSN 0366-7022, 5/2018, Volume 47, Issue 5, pp. 632 - 635
A reductive C–C-bond-forming cyclization of vinyl-terminated allyl chlorides via alkene hydroboration with 9-BBN-H followed by Cu-catalyzed asymmetric... 
Allylic alkylation | Alkylboranes | Copper catalysis | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | DESYMMETRIZATION | CROSS-COUPLING REACTIONS | LIGANDS | PHOSPHORAMIDITES | PHOSPHATES | RECENT PROGRESS | STEREOGENIC CENTERS | CONJUGATE ADDITION | Alkylboron | Hydroboration | Alkenes | Copper | Cyclic compounds | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2010, Volume 49, Issue 44, pp. 8145 - 8147
Asymmetric conjugate addition of arylboroxines to borylalkenes proceed in the presence of a chiral bisphosphine/rhodium complex as a catalyst to give chiral... 
alkylboranes | asymmetric catalysis | conjugate addition | borylalkenes | rhodium | Conjugate addition | Borylalkenes | Rhodium | Alkylboranes | Asymmetric catalysis | STRATEGY | CHEMISTRY, MULTIDISCIPLINARY | ORGANOBORONIC ACIDS | ENONES | CHEMISTRY | ARYL | ALKENYL | 1,4-ADDITION | ALPHA,BETA-UNSATURATED ESTERS | ALLYLIC SUBSTITUTION | GRIGNARD-REAGENTS
Journal Article
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