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alkylboronic esters (50) 50
chemistry, organic (39) 39
chemistry, multidisciplinary (32) 32
catalysis (21) 21
alkylboronic acids (20) 20
cross-coupling reactions (19) 19
alkyl-halides (18) 18
aryl halides (16) 16
borylation (16) 16
halides (16) 16
palladium (16) 16
esters (15) 15
hydroboration (15) 15
room-temperature (15) 15
organoboron compounds (14) 14
coupling reactions (13) 13
secondary (12) 12
bromides (11) 11
boronic acids (10) 10
cross-coupling (10) 10
reagents (10) 10
alkoxy diboron reagents (9) 9
asymmetric-synthesis (9) 9
catalyzed borylation (9) 9
derivatives (9) 9
activation (8) 8
alkenes (8) 8
arylboronic acids (8) 8
c-h bonds (8) 8
grignard-reagents (8) 8
index medicus (8) 8
article (7) 7
substitution (7) 7
aryl (6) 6
bonding (6) 6
catalysts (6) 6
organic chemistry (6) 6
organic-synthesis (6) 6
arylation (5) 5
boron (5) 5
communication (5) 5
cross-coupling reaction (5) 5
electrophiles (5) 5
functionalization (5) 5
molecular structure (5) 5
alcohols (4) 4
alkylation (4) 4
alkylboronic acids/esters (4) 4
c-h borylation (4) 4
carbon-hydrogen bonds (4) 4
carbonyl-compounds (4) 4
chemical properties (4) 4
chemistry, inorganic & nuclear (4) 4
chemistry, physical (4) 4
complexes (4) 4
construction (4) 4
copper-catalyzed borylation (4) 4
cross‐coupling (4) 4
diastereoselective synthesis (4) 4
kreuzkupplung (4) 4
ligand (4) 4
ligands (4) 4
methylation (4) 4
nickel (4) 4
oxidation (4) 4
secondary alcohols (4) 4
suzuki coupling (4) 4
alpha,beta-unsaturated carbonyl-compounds (3) 3
alpha-amino-acids (3) 3
amides (3) 3
analysis (3) 3
boronic acid (3) 3
boronic esters (3) 3
chemical bonds (3) 3
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chemical sciences (3) 3
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ester (3) 3
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organoboranes (3) 3
palladium catalysts (3) 3
photoredox catalysis (3) 3
reactivity (3) 3
regiospecific functionalization (3) 3
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Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2770 - 2773
The conventional methods for preparing alkyl boronates often necessitate anhydrous and demanding reaction conditions. Herein, a new, operationally simple... 
CATALYZED DECARBONYLATIVE BORYLATION | METAL-FREE BORYLATION | MERGING PHOTOREDOX | CROSS-COUPLING REACTION | ARYL HALIDES | CHEMISTRY, ORGANIC | ALPHA-AMINO-ACIDS | QUATERNARY CARBONS | REDOX-ACTIVE ESTERS | ALKYLBORONIC ESTERS | CARBOXYLIC-ACIDS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 05/2019, Volume 60, Issue 18, pp. 1302 - 1305
Utilizing Lewis base/photoredox dual catalysis, carbon radicals generated from either alkylboronic acids or esters were coupled with Baylis–Hillman derivatives... 
Visible light photocatalysis | Baylis–Hillman derivatives | Lewis base activation | Alkylboronic acids and esters | ACTIVATION | VISIBLE-LIGHT PHOTOCATALYSIS | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, ORGANIC | ADDUCTS | PHOTOREDOX CATALYSIS | ALKENES | BASE CATALYSIS | CHEMISTRY | GENERATION | RADICALS | Baylis-Hillman derivatives | Esters | Catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2016, Volume 22, Issue 44, pp. 15654 - 15658
The oxidative copper‐catalyzed cross‐coupling of functionalized alkyl boronic esters with primary amides is reported. Through the identification of appropriate... 
cross-coupling | copper | amides | alkyl boronic esters | NacNac ligand | CUPRIC ACETATE | O-METHYLATION | ELECTROPHILIC AMINATION | DIORGANOZINC REAGENTS | ALKYLBORONIC ESTERS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | CROSS-COUPLING REACTIONS | AMINES | N-CYCLOPROPYLATION | Copper | Amides | Esters | Ligands | Cross coupling | Coupling | nacnac | amide
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2014, Volume 50, Issue 31, pp. 4053 - 4055
The synthesis of primary and secondary pinacol boronic esters via lithiation-borylation of carbamates and benzoates with pinacolborane is described. This new... 
SECONDARY ALCOHOLS | COUPLING REACTIONS | ALLYLATION | GENERATION | CATALYZED BORYLATION | ASYMMETRIC HYDROBORATION | ELECTROPHILIC SUBSTITUTION | ALKYLBORONIC ESTERS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | Esters | Benzoates | Synthesis | Methodology | Conversion | Alcohols
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 04/2017, Volume 15, Issue 16, pp. 3418 - 3422
A transition-metal-free lithiation-borylation method has been developed to access a variety of 1,1-diboronate esters with a fully substituted benzylic center... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 16, pp. 3418 - 3422
A transition-metal-free lithiation-borylation method has been developed to access a variety of 1,1-diboronate esters with a fully substituted benzylic center... 
TERTIARY BORONIC ESTERS | SECONDARY ALCOHOLS | BORYLATION METHODOLOGY | ASYMMETRIC-SYNTHESIS | GEM-DIBORYLALKANES | DIASTEREOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | STABILIZED CARBANIONS | ALLYLIC SUBSTITUTION | ALKYLBORONIC ESTERS | STEREOCONTROLLED SYNTHESIS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2004, Volume 69, Issue 10, pp. 3554 - 3557
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2016, Volume 138, Issue 19, pp. 6139 - 6142
The use of low-cost manganese­(II) bromide (MnBr2) and tetramethyl­ethylene­diamine (TMEDA) catalyzes the cross coupling of (bis)­pinacolato­diboron with a... 
HALIDES | PALLADIUM | SUBSTITUTION | REAGENTS | CROSS-COUPLING REACTION | SECONDARY | ALKYLBORONIC ESTERS | ELECTROPHILES | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | ARYL CHLORIDES | Chemical properties | Catalysis | Chemical compounds | Analysis
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 12/2016, Volume 55, Issue 51, pp. 15920 - 15924
Short and highly stereoselective total syntheses of the sesquilignan natural product tatanan A and its C3 epimer are described. An assembly-line synthesis... 
ASYMMETRIC-SYNTHESIS | NATURAL-PRODUCTS | TRISUBSTITUTED ALKENES | lithiation-borylation | BORONIC ESTERS | tatanan A | ORGANOBORONIC ESTERS | alkynylation | ALKYLBORONIC ESTERS | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | CARBOALUMINATION | REAGENT-CONTROLLED HOMOLOGATION | total synthesis | Matteson homologation | GRIGNARD-REAGENTS
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2018, Volume 8, Issue 10, pp. 9537 - 9542
A simple method for the conversion of carboxylic acids to boronic esters via redox-active esters (RAEs) is reported using copper catalysis. The scope of this... 
copper catalysis | practical protocol | redox-active esters | kinetic studies | decarboxylative borylation | PHOTOREDOX | CHEMISTRY, PHYSICAL | ALKYLBORONIC ESTERS | ALKYL-HALIDES | BORONIC ACIDS | ALKENYL | BOND | CYCLIZATION | Letter
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 30, pp. 10581 - 10584
Journal Article
Nature Communications, ISSN 2041-1723, 12/2017, Volume 8, Issue 1, pp. 345 - 7
Organoboron compounds play an irreplaceable role in synthetic chemistry and the related transformations based on the unique reactivity of C-B bond are... 
CARBON BOND FORMATION | HYDROBORATION | ASYMMETRIC-SYNTHESIS | MULTIDISCIPLINARY SCIENCES | CONSTRUCTION | ENANTIOSELECTIVE DIBORATION | BORONIC ESTERS | REMOTE | ALKYLBORONIC ESTERS | BORYLATION | ALKYL-HALIDES | Organic chemistry | Boron | Transformation | Alkenes | Regioselectivity | Nickel | Transformations | Catalysis | Chemical synthesis | Organoboron compounds | Aliphatic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2018, Volume 140, Issue 20, pp. 6221 - 6225
A method for transition metal-free 1,2-carboboration of unactivated alkenes with bis­(catecholato)­diboron as the boron source in combination with alkyl... 
ALPHA-FLUOROALKYLATION | RADICAL CYCLIZATIONS | POLAR CROSSOVER REACTIONS | ENANTIOSELECTIVE ARYLBORATION | CARBONYL-COMPOUNDS | CATALYZED BORYLATION | ANTI-CARBOBORATION | ALKYLBORONIC ESTERS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC PINACOL ESTERS | ALKYL-HALIDES | Communication
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 90, pp. 12189 - 12192
Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are... 
OXIDATION | FUNCTIONALIZATION | REAGENTS | ALKYLATION | COMPLEXES | ESTERS | ALPHA-OXOCARBOXYLIC ACIDS | ALKYLBORONIC ACIDS | DECARBOXYLATIVE ORTHO-ACYLATION | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2018, Volume 57, Issue 51, pp. 16832 - 16836
Journal Article
Nature Communications, ISSN 2041-1723, 04/2016, Volume 7, Issue 1, p. 11129
New carbon-carbon bond formation reactions expand our horizon of retrosynthetic analysis for the synthesis of complex organic molecules. Although many methods... 
ORGANIC-SYNTHESIS | ALKENES | CROSS-COUPLING REACTIONS | NOBEL LECTURE | MULTIDISCIPLINARY SCIENCES | ARYL HALIDES | INTERNAL OLEFINS | HYDROAMINATION | ALKYLBORONIC ESTERS | GRIGNARD-REAGENTS | ALKYL-HALIDES
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2013, Volume 78, Issue 9, pp. 4615 - 4619
Copper-catalyzed borylation of a variety of organic halides with bis(pinacolato)diboron allows the preparation of diverse potassium organotrifluoroborates. The... 
HALIDES | PALLADIUM | BORATION | COUPLING REACTIONS | ACIDS | CHEMISTRY, ORGANIC | CATALYZED BORYLATION | ALKYLBORONIC ESTERS | TERTIARY
Journal Article
Nature Chemistry, ISSN 1755-4330, 09/2017, Volume 9, Issue 9, pp. 896 - 902
Journal Article