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Angewandte Chemie International Edition, ISSN 1433-7851, 10/2012, Volume 51, Issue 42, pp. 10633 - 10637
Highly reactive gold vinylidene species are used for intermolecular C(sp3)H insertions into unactivated alkanes (see scheme). In addition, they can be... 
dual activation | gold | CH activation | benzocyclobutenes | vinylidenes | C-H activation | CATALYZED SYNTHESIS | METHYLENECYCLOPROPANES | C?H activation | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | REARRANGEMENT | DUAL-ACTIVATION | CARBENES | CYCLOISOMERIZATION | 2+2 CYCLOADDITION | GENERATION | DIYNES | Vinylidene | Gold | Cascades | Alkylidene | Insertion | Alkanes | Derivatives | Carbenes
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 06/2015, Volume 54, Issue 12, pp. 5624 - 5633
Treatment of NiCl2(dme) and NiBr2(dme) (dme = dimethoxyethane) with 2 equiv of LiOR (OR = (OCBu2Ph)-Bu-t) forms the distorted trigonal planar complexes... 
CARBON-MONOXIDE CLEAVAGE | ALKYLIDENE COMPLEXES | COPPER(I) | BETA-SCISSION | MANGANESE(II) | RAY CRYSTAL-STRUCTURES | TERT-BUTYLMETHOXIDE LIGAND | COBALT(II) | STRUCTURAL-CHARACTERIZATION | INITIO QM/MM CALCULATIONS | CHEMISTRY, INORGANIC & NUCLEAR | Usage | Ligands | Voltammetry | Research | Chemical properties | Chemical synthesis | Copper
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 19, pp. 5506 - 5511
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 12, pp. 5122 - 5139
A series of P-NHC-type hybrid ligands containing both PR2 and N-heterocyclic carbene (NHC) donors on meta-bis-substituted phenylene backbones, L-Cy, L-tBu and... 
COORDINATION CHEMISTRY | N-HETEROCYCLIC CARBENE | COPPER(I) COMPLEXES | PALLADIUM COMPLEXES | MAGNETIC-RESONANCE | CATALYTIC TRANSFER HYDROGENATION | RUTHENIUM ALKYLIDENE COMPLEXES | STRUCTURAL-CHARACTERIZATION | NICKEL(II) COMPLEXES | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie, ISSN 0044-8249, 05/2018, Volume 130, Issue 19, pp. 5604 - 5609
Unprecedented silyl‐phosphino‐carbene complexes of uranium(IV) are presented, where before all covalent actinide–carbon double bonds were stabilised by... 
Alkylidene | Carbene | Uran | Metall-Ligand-Mehrfachbindungen | Phosphane | Cytokinins | Uranium
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2018, Volume 24, Issue 21, pp. 5637 - 5643
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 38, pp. 13108 - 13110
Using a geminal dianion as precursor, a nucleophilic scandium carbene complex (2) has been synthesized by salt metathesis on ScCl3(THF)3 in 52% isolated yield.... 
ALKYLIDENE | ABSTRACTION | REAGENTS | ACID | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | METATHESIS | METAL-CARBON BONDS | Ketones | Benzene | Scandium | Chemical properties | Structure | Carbenes | Electric properties | Chemical Sciences | Coordination chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2014, Volume 53, Issue 2, pp. 376 - 383
Transition‐metal carbene complexes have been known for about 50 years and widely applied as reagents and catalysts in organic transformations. In contrast, the... 
methylidene | rare‐earth metals | carbene | lanthanides | rare-earth metals | ACTIVATION | REACTIVITY | STRUCTURAL-CHARACTERIZATION | BASE INDUCED REDUCTIONS | HYDROAMINATION | CHEMISTRY, MULTIDISCIPLINARY | ORGANOLANTHANIDE CHEMISTRY | CATALYSTS | Earth | Rare earth metals | Organic chemistry | Catalysts | Metalorganic compounds | Alkylidene | Transformations | Catalysis | Carbenes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2017, Volume 139, Issue 49, pp. 17759 - 17762
The first phosphoniomethylidene complexes of scandium and lutetium, [LLn­(CHPPh3)­X] (L = [MeC­(NDIPP)­CHC­(NDIPP)­Me]−; Ln = Sc, X = Me, I, TfO; Ln = Lu, X =... 
ALKYLIDENE COMPLEXES | ACTIVATION | NOBEL LECTURE | TANTALUM | METATHESIS REACTIONS | REACTIVITY | CARBON MULTIPLE BOND | CRYSTAL | CARBENE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | METAL METHYLIDENE COMPLEXES | Chemical bonds | Density functionals | Hydrogen | Analysis | Scandium | Electric properties | Physics | Chemical Sciences
Journal Article
Dalton Transactions, ISSN 1477-9226, 2008, Issue 15, pp. 1957 - 1972
The stabilisation of the carbene centre in a complex can be achieved either by the metal moiety or the carbon substituents. The balance between these two... 
ALKYLIDENE COMPLEXES | ALKALI-METAL LI | CARBON-MONOXIDE | CRYSTAL-STRUCTURE | X-RAY-STRUCTURE | IMINOPHOSPHORANE COMPLEXES | HETEROCYCLIC CARBENES | GROUP-4 METAL | TRANSITION-METALS | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2018, Volume 24, Issue 52, pp. 13903 - 13917
Journal Article