X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
alkynylsilanes (103) 103
chemistry, organic (84) 84
alkynes (34) 34
chemistry, multidisciplinary (32) 32
alkynylsilane (26) 26
chemistry, inorganic & nuclear (24) 24
stereoselective synthesis (23) 23
acetylenes (19) 19
hydroboration (18) 18
vinylsilanes (18) 18
derivatives (17) 17
palladium (17) 17
reductive alkylation (17) 17
terminal alkynes (17) 17
organic-synthesis (16) 16
halides (15) 15
cross-coupling reactions (13) 13
aryl iodides (12) 12
copper (12) 12
hydromagnesiation (12) 12
stereoselective-synthesis (12) 12
catalysis (11) 11
cross-coupling reaction (11) 11
organoboration (11) 11
convenient synthesis (10) 10
one-pot synthesis (10) 10
route (10) 10
silylation (10) 10
alcohols (9) 9
chemistry (9) 9
reagents (9) 9
1,1-organoboration (8) 8
grignard-reagents (8) 8
oxidation (8) 8
polarization transfer (8) 8
acetylene (7) 7
complexes (7) 7
coupling reactions (7) 7
letter (7) 7
reactivity (7) 7
aryl (6) 6
c-h activation (6) 6
chemistry, applied (6) 6
chlorides (6) 6
cobalt (6) 6
copper-free (6) 6
cross-coupling (6) 6
diynes (6) 6
enhancement (6) 6
nmr (6) 6
room-temperature (6) 6
salt (6) 6
silicon (6) 6
siloles (6) 6
sonogashira reaction (6) 6
synthesis (6) 6
alkenes (5) 5
alkylarylacetylene (5) 5
alkynylation (5) 5
aqueous ammonia (5) 5
aryl bromides (5) 5
carbonyl-compounds (5) 5
catalysts (5) 5
copper catalyst (5) 5
palladium catalyst (5) 5
silane (5) 5
silanes (5) 5
alkine (4) 4
amides (4) 4
asymmetric-synthesis (4) 4
carbon (4) 4
conversion (4) 4
efficient (4) 4
efficient synthesis (4) 4
functional groups (4) 4
heterogeneous catalysis (4) 4
hydrozirconation (4) 4
index medicus (4) 4
iodine (4) 4
ketones (4) 4
ligands (4) 4
molecular structure (4) 4
nmr spectroscopy (4) 4
organic compounds (4) 4
rearrangements (4) 4
reduction (4) 4
sonogashira (4) 4
sonogashira reactions (4) 4
stereospecific synthesis (4) 4
tetrabutylammonium fluoride (4) 4
trisubstituted olefins (4) 4
1,2-hydroboration (3) 3
1,3-diynes (3) 3
1-alkynes (3) 3
activation (3) 3
aldehydes (3) 3
alkenylation (3) 3
alkyne (3) 3
analysis (3) 3
aryl halides (3) 3
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Chemistry Letters, ISSN 0366-7022, 2/2017, Volume 46, Issue 2, pp. 218 - 220
A palladium-catalyzed decarbonylative alkynylation reaction of aromatic esters with terminal alkynes is reported. This reaction allows for halogen-free... 
AZOLES | ALKYNYLSILANES | Palladium | HAGIHARA COUPLING REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | Decarbonylative reaction | OLEFINATION | NICKEL | CHLORIDES | ARYL IODIDES | CHEMOSELECTIVITY | Alkyne | AMIDES
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2007, Volume 36, Issue 5, pp. 759 - 769
Silver acetylides are among the oldest organometallics known; however, their applications in organic chemistry remained scarce until very recently. Indeed,... 
ACETYLENES | ALDEHYDE | ONE-POT SYNTHESIS | ALKYNYLSILANES | TERMINAL ALKYNES | ARYL IODIDES | CLEAVAGE | CATALYZED COUPLING REACTIONS | ALKYNYLATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 14, pp. 6060 - 6070
The 1,1-carboboration of 1-Me3Si-1-alkynes is the dominant reaction observed using [PhBCl(2-DMAP)][AlCl4], 1, and PhBCl2 electrophiles, with highly substituted... 
PHENYLBORATION | ARENE BORYLATION | 1,1-CARBOBORATION | ACTIVATION | ALKYNYLSILANES | 1,1-ORGANOBORATION | SELECTIVE SYNTHESIS | INTERNAL ALKYNES | BORENIUM CATIONS | ALKYNYLBORANES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 01/2016, Volume 14, Issue 1, pp. 85 - 92
A simple and expedient method for the synthesis of 3-methylene-isoindolin-1-ones 4 under aqueous phase-transfer conditions has been developed. Starting from... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 01/2013, Volume 11, Issue 1, pp. 164 - 169
Journal Article
Synlett, ISSN 0936-5214, 12/2013, Volume 24, Issue 20, pp. 2715 - 2719
Abstract The coupling of a 1-chloroalkyne and a terminal alkyne to furnish a 1,3-butadiyne under experimental Sonogashira conditions is investigated. Through... 
letter | cross-coupling | catalysis | copper | palladium | alkynes | ACETYLENES | ALKYNYLSILANES | OLIGOSACCHARIDE ANALOGS | POLYSACCHARIDES | CHEMISTRY, ORGANIC | DIYNES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2015, Volume 54, Issue 19, pp. 5697 - 5701
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2018, Volume 24, Issue 59, pp. 15777 - 15780
Aerobic cross‐dehydrogenative coupling between terminal alkynes and hydrosilanes occurred in the presence of nanoporous gold catalyst under O2 atmosphere. A... 
gold | C−H activation | alkynylsilanes | chemoselective protection | cross-dehydrogenative coupling | ORGANIC-SYNTHESIS | LOW-TEMPERATURE | CO OXIDATION | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | ALCOHOLS | C-H activation | REDUCTION | ARYL IODIDES | METAL | NANOSTRUCTURED MATERIALS | Gold | Catalysts | Dehydrogenation | Catalysis | Coupling | Chemical synthesis | Hydroxyl groups | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2013, Volume 52, Issue 21, pp. 5627 - 5630
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2019, Volume 25, Issue 23, pp. 5870 - 5874
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2002, Volume 67, Issue 6, pp. 1969 - 1971
A novel pathway for the homocoupling reaction has been achieved using a similar protocol as the cross-coupling reaction. Ethyl bromoacetate is chosen to... 
CROSS-COUPLING REACTIONS | LIGANDS | ALKYNYLSILANES | ARYL HALIDES | CHEMISTRY, ORGANIC | BOND FORMATION | DIARYL ETHERS | HECK REACTION | Palladium catalysts | Chemical reactions | Usage | Synthesis | Analysis | Organic compounds
Journal Article
Arkivoc, ISSN 1551-7012, 2013, Volume 2013, Issue 2, pp. 316 - 362
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2011, Volume 17, Issue 43, pp. 12153 - 12162
Bis‐TMS protected C,C‐diacetylenic phosphaalkene (A2PA) 1 (Mes*PC(C≡CTMS)2; Mes*=2,4,6‐tBu3Ph) has been used as a building block for the construction of... 
oxidative acetylene coupling | phosphaalkenes | carbon‐rich compounds | conjugation | dendralenes | carbon-rich compounds | RADIALENES | ALKYNYLSILANES | MOLECULAR WIRES | MACROCYCLES | RODS | CHEMISTRY, MULTIDISCIPLINARY | TRANSITION | PI-CONJUGATED MATERIALS | BONDS | PPV | CHEMISTRY | Naturvetenskap | Kemi | Natural Sciences | Chemical Sciences
Journal Article
Synlett, ISSN 0936-5214, 03/2012, Volume 23, Issue 5, pp. 773 - 777
Abstract The palladium/copper cocatalyzed sila-Sonogashira reaction of (hetero)arylethynysilanes with (hetero)aryl bromides in toluene and water at 40 ˚C under... 
letter | copper | palladium | phase-transfer catalysis | Sonogashira reaction | alkynylsilanes | di-arylethynes | ROOM-TEMPERATURE | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | diarylethynes | AMBIENT CONDITIONS | ARYL IODIDES | COPPER-FREE | IONIC LIQUIDS | HECK REACTION | IN-SITU | WATER
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2018, Volume 360, Issue 18, pp. 3579 - 3584
A Co(III)‐catalyzed counter anion triggered desilylative direct ortho‐vinylation of secondary benzamides is reported. The reaction furnishes the alkenylated... 
alkenylation | alkynylsilane | amides | C−H activation | desilylation | Cobalt | CATALYSIS | O BOND | ANNULATION | ALKYNYL CARBOXYLIC-ACIDS | ARENES | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | ISOQUINOLONE SYNTHESIS | C-H activation | OLEFINATION | CHEMISTRY, APPLIED | HYDROARYLATION | Amides | Anions | Functional groups | Alkynes
Journal Article