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Synlett, ISSN 0936-5214, 07/2015, Volume 26, Issue 11, pp. 1596 - 1600
Abstract Versatile cobalt-catalyzed C–H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C–H/C–O functionalization... 
letter | cobalt | C-H activation | allylation | heteroarene | C-O cleavage
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 12/2018, Volume 57, Issue 52, pp. 17151 - 17155
Biaryl atropisomers are of great importance in natural products, pharmaceuticals, and asymmteric synthesis. The efficient synthesis of these chiral scaffolds... 
C−H allylation | ligands | palladium | atroposelectivity | biaryls | Asymmetric synthesis | Natural products | Chemical reactions | Carboxylic acids | Catalysis | Leucine | Aldehydes | Enantiomers | Allyl compounds | Chemical synthesis | Erosion
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2018, Volume 74, Issue 38, pp. 5032 - 5039
Formal syntheses of lasubine II and subcosine II have been completed by the synthesis of epi-lasubine II. The synthesis involves diastereoselective allylation... 
Alkaloid | Tandem | Indolizidine | Isoxazolidine | Allylation | Hydrogenation
Journal Article
Tetrahedron letters, ISSN 0040-4039, 01/2018, Volume 59, Issue 4, pp. 379 - 382
[Display omitted] •A new catalytic system for the C–H allylation of arenes is presented.•The reaction tolerates a wide number of arenes and allylic... 
Arenes | C–H activation | Palladium | S,O-ligand | Allylation | C–H activation, S,O-ligand, Palladium, Allylation, Arenes
Journal Article
Synthesis, ISSN 0039-7881, 04/2019, Volume 51, Issue 7, pp. 1655 - 1661
Abstract An iridium-catalyzed branch-selective ring-opening reaction of vinylcyclopropanes with indoles has been established, which afforded C3-allylindoles in... 
paper | vinylcyclopropane | indole | allylation | metal catalysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2017, Volume 56, Issue 23, pp. 6641 - 6645
A chiral PdII‐catalyzed cascade sp2 C−H functionalization/intramolecular asymmetric allylation reaction is reported. A new chiral sulfoxide–oxazoline (SOX)... 
chiral indoline | asymmetric allylation | C−H activation | sulfoxide–oxazoline | cascade reaction | Sulfur compounds | Palladium | Ligands | Construction | Sulfur
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 12/2014, Volume 53, Issue 50, pp. 13780 - 13784
A rhodium‐catalyzed chemo‐, regio‐, and enantioselective addition of 2‐pyridones to terminal allenes to give branched N‐allyl 2‐pyridones is reported.... 
reaction mechanisms | allenes | asymmetric allylation | 2‐pyridones | rhodium | Allenes | Asymmetric allylation | Rhodium | Reaction mechanisms | 2-pyridones | Catalysis | Pyridones - chemistry | Stereoisomerism | Alkadienes - chemistry | Rhodium - chemistry | Thermodynamics | Chemotherapy | Enantiomers | Analysis | Cancer | Index Medicus | Reaction kinetics | Branched | Terminals
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2016, Volume 55, Issue 27, pp. 7747 - 7750
The first manganese(I)‐catalyzed C−H allylations with ample scope were achieved by carboxylate assistance. The highly selective C−H/C−O functionalizations... 
reaction mechanisms | heteroarenes | C−H activation | manganese | electrophiles
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2016, Volume 55, Issue 20, pp. 6099 - 6102
Quaternary stereocenters are found in numerous bioactive molecules. The Tsuji–Trost reaction has proven to be a powerful C−C bond forming process, and, at... 
enol catalysis | atom economy | allylic alcohol | quaternary stereocenters | α-allylation | Asymmetry | Ketones | Carbon dioxide | Chemical reactions | Catalysis | Enantiomers | Allyl compounds | Molecular chains | Alcohols
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2017, Volume 56, Issue 38, pp. 11515 - 11519
An iridium‐catalyzed cyclocondensation of amino alcohols and aldehydes is reported. Intramolecular allylic substitution by an enamine intermediate and... 
iridium | piperidines | catalysis | allylation | stereoselective synthesis | Catalysis | Iridium | Piperidine | Aldehydes | Chemical synthesis | Alcohols
Journal Article
Synthesis, ISSN 0039-7881, 05/2018, Volume 50, Issue 9, pp. 1907 - 1913
Abstract A simple and efficient synthetic approach is reported for the synthesis of 5-trifluoromethyl-5-aryl-3-methylidenepyrrolidin-2-ones in moderate to... 
paper | acylhydrazines | tin | lactams | allylation | trifluoromethyl ketones
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 07/2014, Volume 53, Issue 27, pp. 7038 - 7042
The direct regioselective allylation of in situ generated aldehyde acyl anions has been achieved by synergistic NHC and Pd catalysis. It provides an efficient... 
aldehyde umpolung | C allylation | palladium | synergistic catalysis | N‐heterocyclic carbenes | C allylation | N-heterocyclic carbenes
Journal Article
Synlett, ISSN 0936-5214, 08/2012, Volume 23, Issue 15, pp. 2266 - 2268
Abstract Iminium ions generated from isoxazolidines and tetrahydro-1,2-oxazines undergo allylation under Sakurai conditions. Allylated isoxazolidines are... 
letter | stereoselectivity | heterocycles | allylation
Journal Article
Chemistry : a European journal, ISSN 1521-3765, 12/2018, Volume 25, Issue 3, pp. 724 - 727
Dehydrative allylation between widely available aldehydes and allylic alcohols to afford β,γ‐unsaturated ketones was enabled by a synergistic merger of a... 
dehydrative allylation | aldehyde | palladium | synergistic catalysis | carbene | Ketones | Catalysts | Chemical reactions | Alcohol | Palladium | Catalysis | Dehydration | Aldehydes | Allyl compounds | Alcohols
Journal Article
Synlett, ISSN 0936-5214, 08/2016, Volume 27, Issue 13, pp. 2019 - 2023
Abstract The Barbier-type allylation of isatin imines with allylic chlorides was achieved by using metallic barium as the promoter. Various α-allylated... 
letter | barium | imines | allylic chlorides | 3-amino-2-oxindoles | allylation
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 03/2015, Volume 357, Issue 5, pp. 961 - 966
A class of bipyridyl alcohol ligands has been developed. A catalyst synthesized using a chromium(II)‐ligand promotes the enantioselective Nozaki–Hiyama–Kishi... 
enantioselectivity | asymmetric catalysis | bipyridyl alcohol | chromium catalysis | Nozaki–Hiyama–Kishi allylation | Nozaki-Hiyama-Kishi allylation | Chromium | Catalysis | Ketones | Enantiomers | Aldehydes | Synthesis | Catalysts | Halides | Ligands | Aliphatic compounds | Alcohols
Journal Article