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Synlett, ISSN 0936-5214, 06/2016, Volume 27, Issue 9, pp. 1428 - 1432
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2015, Volume 71, Issue 37, pp. 6481 - 6487
Allylic substitution of chiral allylic picolinate (1 equiv) with the copper reagents derived from 2-lithio-1-alkylimidazoles (2 equiv), CuBr·Me2S (1 equiv) and MgBr2 (3 equiv... 
Picolinate ester | Copper | Allylic substitution | Imidazole | Chiral | N-HETEROCYCLIC CARBENE | CHEMISTRY, ORGANIC | SYNTHETIC APPROACH | CONVENIENT ROUTE | AMINO-ACID | FACILE SYNTHESIS | PROTECTING GROUP | ASYMMETRIC MICHAEL ADDITION | ARYL | IONIC LIQUIDS | GRIGNARD-REAGENTS
Journal Article
Synthesis, ISSN 0039-7881, 04/2015, Volume 47, Issue 7, pp. 924 - 933
Abstract The near-quantitative transformation of a racemic cyclic allylic phosphate to a highly enantiomerically enriched allylic silane by allylic substitution with a silicon nucleophile is reported... 
feature | enantioselectivity | copper | silicon | allylic substitution | N-heterocyclic carbenes | TRANSFORMATION | ACTIVATION | COMPLEX | CARBONATES | STEREOCHEMISTRY | CHEMISTRY, ORGANIC | ALLYLSILANES | SILANES | MECHANISTIC INSIGHT | NUCLEOPHILIC SILICON | DERIVATIVES
Journal Article
中国化学快报:英文版, ISSN 1001-8417, 2016, Volume 27, Issue 5, pp. 619 - 622
Journal Article
Synthesis, ISSN 0039-7881, 08/2013, Volume 45, Issue 15, pp. 2109 - 2114
Abstract An air-stable (π-allyl)iridium complex derived from dinaphthocyclooctatetraene and a phosphoramidite ligand has been synthesized and found to be highly efficient in iridium-catalyzed allylic substitution reactions... 
special topic | regioselectivity | enantio-selectivity | (π-allyl)iridium complex | allylic substitution | dinaphthocyclooctatetraene | enantioselectivity | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | IRIDIUM | ALLYLATION | CHEMISTRY, ORGANIC | ALKYLATIONS | ETHERIFICATION | RING-CLOSING-METATHESIS | 2+2+2+2 CYCLOADDITIONS | (pi-allyl)iridium complex | RESTING STATES | AMINATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2008, Volume 47, Issue 40, pp. 7652 - 7655
A final tweak: A new phosphoramidite iridium catalyst (see scheme) allows allylic substitutions to be run with a higher degree of regioselectivity than with other iridium catalysts and under aerobic conditions... 
iridium | allylic amines | allylic substitution | asymmetric catalysis | cyclization | Allylic amines | Iridium | Cyclization | Asymmetric catalysis | Allylic substitution | LIGANDS | COMPLEXES | ETHERIFICATION | AMINATIONS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Synlett, ISSN 0936-5214, 03/2016, Volume 27, Issue 4, pp. 611 - 615
Abstract The allylic substitution of γ,γ-disubstituted secondary allylic picolinates... 
letter | copper reagents | allylic substitution | aryl lithium | picolinate | quaternary carbon | anti S
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2006, Volume 348, Issue 14, pp. 1841 - 1845
Journal Article
ACS Catalysis, ISSN 2155-5435, 04/2018, Volume 8, Issue 4, pp. 3587 - 3601
A modular approach employing indene as common starting material, has enabled the straightforward preparation in three reaction steps of P-thioether ligands for the Pd-catalyzed asymmetric allylic substitution... 
CHIRAL LIGANDS | CYCLOALKENYL ESTERS | NMR study | MOLECULAR-ORBITAL METHODS | ALKYLATION | AB-INITIO | EFFICIENT SYNTHESIS | CHEMISTRY, PHYSICAL | ORGANIC CARBONATES | DFT study | ETHERIFICATION | P,S-ligands | FORCE-FIELD PARAMETERS | palladium | BASIS-SETS | allylic substitution
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2005, Volume 690, Issue 24, pp. 6001 - 6007
Journal Article
Heterocycles, ISSN 0385-5414, 2016, Volume 92, Issue 5, pp. 793 - 828
.... The synthetic transformations are classified as N-heterocyclic ring-substitution, ring-enlargement, and ring-contraction. 
STEVENS REARRANGEMENT | ROUTE | CHIRALITY TRANSFER | 1-METHYLIDES | AMINES | ALLYLIC AMMONIUM | CHEMISTRY, ORGANIC | TRANSITION-STATE | SOMMELET-HAUSER REARRANGEMENT | SIGMATROPIC REARRANGEMENT | YLIDES
Journal Article
Synlett, ISSN 0936-5214, 3/2006, Volume 2006, Issue 5, pp. 0697 - 0700
Abstract Enantioselective Ir-catalyzed allylic alkylations with nitroalkanes and ethyl nitroacetate as nucleophiles are reported. Up to 99% ee was achieved... 
letter | Catalysis | Iridium | Ring-closing metathesis | Allylic substitution | Nitroalkanes | ASYMMETRIC-SYNTHESIS | CARBONATES | COMPLEXES | CHEMISTRY, ORGANIC | catalysis | ETHERIFICATION | ALKYLATIONS | PHOSPHORAMIDITE LIGAND | ring-closing metathesis | iridium | AMINATION | ESTERS | allylic substitution | nitroalkanes
Journal Article
Organic Letters, ISSN 1523-7060, 02/2012, Volume 14, Issue 3, pp. 890 - 893
.... The boryl substitution proceeded with normal and secondary alkyl chlorides, bromides, and iodides, but alkyl sulfonates did not react... 
SINGLE ELECTRON-TRANSFER | ENANTIOSELECTIVE SYNTHESIS | ALLYLIC CARBONATES | EFFICIENT ROUTE | ESTERS | CHEMISTRY, ORGANIC | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | DIBORON REAGENTS | ORGANIC HALIDES | COPPER-CATALYZED BORYLATION | BETA-BORATION
Journal Article
ChemCatChem, ISSN 1867-3880, 03/2017, Volume 9, Issue 6, pp. 1032 - 1039
...‐diols and the direct nucleophilic substitution of allylic alcohols. In general, high yields and regioselectivities are obtained in both reactions using 20 wt... 
green chemistry | graphene | rearrangement | allylic compounds | carbocations | OXIDATION | ACID CATALYSTS | CARBON | ALKYLATION | CHEMISTRY, PHYSICAL | GRAPHITE OXIDE | MECHANISMS | CLEAVAGE | CARBOCATALYSIS | WATER | Green chemistry | Graphene | Green technology | Graphite
Journal Article
Chemical Society reviews, ISSN 0306-0012, 08/2017, Volume 46, Issue 16, pp. 4845 - 4854
Chiral ligands play a central role in enantioselective transition-metal catalysis. The success of achiral N-heterocyclic carbenes (NHCs) as stable... 
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 8/2017, Volume 46, Issue 16, pp. 4845 - 4854
Chiral ligands play a central role in enantioselective transition-metal catalysis. The success of achiral N-heterocyclic carbenes (NHCs) as stable... 
NHC COMPLEXES | HYDROGENATION | REAGENTS | CYCLOADDITIONS | ENANTIOSELECTIVE OLEFIN METATHESIS | ARYL | ALKYLATIONS | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | ALLYLIC SUBSTITUTIONS
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 05/2013, Volume 8, Issue 5, pp. 974 - 981
In this study, we investigate the effect of the electrophiles and the nucleophiles for eight catalysts in the catalytic SN1 type substitution of alcohols with different degree of activation by sulfur‐, carbon‐, oxygen‐, and nitrogen... 
atom economy | alcohols | homogeneous catalysis | nucleophilic substitution | ROUTE | BENZYLIC ALCOHOLS | ALKYLATION | COMPLEXES | HYDROXY GROUP | CHEMISTRY, MULTIDISCIPLINARY | CARBON BOND FORMATION | ETHERS | ALLYLIC ALCOHOLS | PROPARGYLIC ALCOHOLS | SECONDARY-AMINES | Alcohols - chemistry | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Metals - chemistry | Stereoisomerism
Journal Article
Pure and Applied Chemistry, ISSN 0033-4545, 01/2008, Volume 80, Issue 5, pp. 1025 - 1037
...1025 Pure Appl. Chem., Vol. 80, No. 5, pp. 1025–1037, 2008. doi:10.1351/pac200880051025 © 2008 IUPAC Copper-catalyzed asymmetric allylic substitution reactions... 
synthesis | catalysis | asymmetric | allylic | alkylations | Asymmetric | Alkylations | Synthesis | Catalysis | Allylic | CHIRAL LIGANDS | CARBONATES | ENANTIOSELECTIVE SYNTHESIS | PHOSPHORAMIDITE LIGANDS | COMPLEXES | REGIOSELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | KINETIC RESOLUTION | ESTERS | CONJUGATE ADDITION | Allylic compounds | Substitution reactions | Influence | Research | Chemical synthesis | Copper | Properties
Journal Article