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Nature Communications, ISSN 2041-1723, 12/2017, Volume 8, Issue 1, pp. 2258 - 2258
Journal Article
Organic Letters, ISSN 1523-7060, 10/2017, Volume 19, Issue 20, pp. 5641 - 5644
Studies of the silyl-Heck reaction aimed at identifying active palladium complexes have revealed a new species that is formed in Situ. This complex has been... 
CHEMISTRY, ORGANIC | ETHERS | ALLYLSILANES | OXIDATIVE ADDITION | PRODUCT | COMPLEXES | Index Medicus
Journal Article
MENDELEEV COMMUNICATIONS, ISSN 0959-9436, 09/2018, Volume 28, Issue 5, pp. 546 - 547
Oxidations of {(1R,4R,5S)-2-[tert-butyl(dimethyl)silyloxy-methyl]-4-(trimethylsil)pcydopent-2-en-1-yl}methanol with m-chloroperoxybenzoic acid (mCPBA) and... 
ORGANIC-SYNTHESIS | SILICON | ALLYLSILANES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2019, Volume 9, Issue 2, pp. 1612 - 1618
The asymmetric 1,2-Markovnikov hydrosilylation of conjugated dienes with primary silanes catalyzed by a quinoline-oxazoline cobalt complex has been described.... 
conjugated dienes | hydrosilylation | cobalt | asymmetric catalysis | polyorganosiloxane | allylsilane | ALLYLIC SILANES | ASYMMETRIC HYDROSILYLATION | HYDROBORATION | CHEMISTRY, PHYSICAL | POLYMERIZATION | ALKENES | OPTICALLY-ACTIVE ALLYLSILANES | ALPHA,OMEGA-DIKETONES | 1,4-HYDROSILYLATION | COPOLYMERIZATION | POLY(SILYL ETHER)S
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 38, pp. 6371 - 6374
We report herein a single component Ir photoredox catalyst which is capable of catalyzing the hydrotrifluoromethylation of terminal alkenes and Michael... 
FUNCTIONALIZATION | (TRIFLUOROMETHYL)TRIMETHYLSILANE | ACIDS | OLEFINS | TRIFLUOROMETHYLATION REACTIONS | ARYL IODIDES | RADICALS | ALLYLSILANES | TRIFLUOROMETHANESULFINATE | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | Sodium | Ketones | Alkenes | Methyl alcohol | Reagents | Esters | Terminals | Ethers
Journal Article
Macromolecules, ISSN 0024-9297, 05/2012, Volume 45, Issue 10, pp. 4134 - 4141
The photoredox catalysis approach is used to initiate the free radical promoted cationic photopolymerization of N-vinylcarbazole (NVK) under very soft... 
CATALYSIS | POLYMER SCIENCE | SILYL RADICALS | ALKYLATION | PHOTOREDOX ORGANOCATALYSIS | PHOTOCATALYSIS | REACTIVITY | PROMOTED CATIONIC-POLYMERIZATION | DEVICES | ALDEHYDES | ALLYLSILANES | Material chemistry | Chemical Sciences
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 07/2013, Volume 78, Issue 14, pp. 7330 - 7336
Copper-mediated trifluoromethylation of allylic chlorides and trifluoroacetates was performed using a convenient Cu-CF3 reagent. The reaction is suitable for... 
HALIDES | SUBSTITUTION | (TRIFLUOROMETHYL)TRIMETHYLSILANE | ARENES | CATALYZED TRIFLUOROMETHYLATION | CHLORIDES | CHEMISTRY, ORGANIC | COPPER | ALLYLSILANES | ALKYNES | FLUORIDES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2017, Volume 2017, Issue 32, pp. 4651 - 4665
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 04/2019, Volume 55, Issue 27, pp. 3923 - 3926
A catalytic enantioselective Hosomi-Sakurai reaction of -ketoesters has been developed. A copper(ii) complex with a chiral bis(oxazoline) ligand bearing... 
MICHAEL | ALKYLATION | CHEMISTRY | ALPHA | ALDEHYDES | ALLYLSILANES | ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY | ORGANOSILICON COMPOUNDS | ASYMMETRIC ALLYLATION | MUKAIYAMA ALDOL
Journal Article
Organic Letters, ISSN 1523-7060, 12/2018, Volume 20, Issue 24, pp. 8061 - 8063
A silylation of vinyliodonium salts using zinc-based silicon reagents as nucleophiles is reported. This cross-coupling is catalyzed by copper, and vinylsilanes... 
HALIDES | REAGENTS | SILYLZINCATION | CHEMISTRY, ORGANIC | ARYL | ALLYLSILANES | ALKYNES | BOND | SILYLATION | VINYLSILANES
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 03/2019, Volume 84, Issue 6, pp. 3595 - 3611
A general method for generation of allyl carbenium ions from propargyl silanes via a 1,2-silyl shift by Bronsted acids is reported. Two possible reaction... 
ARYL BROMIDES | VINYL | ALLENYLSILANES | CYCLOADDITIONS | SILICON | COMPLEXES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | RING ANNULATION | ALLYLSILANES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2014, Volume 136, Issue 51, pp. 17706 - 17709
A regiodivergent silacarboxylation of allenes under a CO2 atmosphere with PhMe2Si-B(pin) as a silicon source in the presence of a copper catalyst at 70 degrees... 
ORGANIC-SYNTHESIS | SILYLCUPRATION | NICKEL | HYDROGEN-PEROXIDE | CARBOXYLATION | ALLYLSILANES | ALKYNES | SILYL-CUPRATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | VINYLSILANES | Carboxylation | Copper compounds | Chemical properties | Analysis
Journal Article
Organic Letters, ISSN 1523-7060, 12/2012, Volume 14, Issue 23, pp. 5880 - 5883
A simple copper-catalyzed enantioselective synthesis of axially chiral chloroallenes from the propargylic dichlorides is reported, employing a catalytic amount... 
SUBSTITUTION | ASYMMETRIC CONJUGATE ADDITION | ALLENYLSILANES | OPTICALLY-ACTIVE ALLENES | ALLYLIC ALKYLATION | CHLORIDES | CHEMISTRY, ORGANIC | PROPARGYLIC PHOSPHATES | ALLYLSILANES
Journal Article
Organic Letters, ISSN 1523-7060, 10/2017, Volume 19, Issue 20, pp. 5649 - 5652
Based upon a radical polar effect, an intermolecular azidoheteroarylation of simple alkenes via a metal-free radical multi component cascade process was... 
COPPER PHOTOREDOX CATALYST | SODIUM TRIFLUOROMETHANESULFINATE | C-H AZIDATION | BOND-FORMING REACTIONS | CHEMISTRY, ORGANIC | PYRIDINE N-OXIDES | CHIRAL ALLYLSILANES | BETA-KETO-ESTERS | LATE-STAGE FUNCTIONALIZATION | HETEROAROMATIC BASES | UNACTIVATED ALKENES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2018, Volume 59, Issue 29, pp. 2809 - 2812
A practical, operationally simple preparation of 2-(trimethylsilyl)methyl-2-propen-1-ol derivatives is described. The cobalt catalyzed coupling of a protected... 
Co catalyst | Trimethylenemethane precursors | Allylsilane | Sp2-sp3 coupling | IMINES | CHEMISTRY, ORGANIC | MEDIATED CYCLOADDITION APPROACH | TRIMETHYLENEMETHANE | CYCLOPENTANOIDS | ALLYLSILANES | CARBOCYCLES | BIOLOGICAL EVALUATION | STEREOSELECTIVE-SYNTHESIS | NEODYSIHERBAINE-A | ACCESS | Chemical tests and reagents | Cobalt | Silane
Journal Article
Synthesis, ISSN 0039-7881, 02/2016, Volume 48, Issue 4, pp. 520 - 534
Abstract In the presence of catalytic amounts of platinum(II) chloride and silver(I) hexafluoroantimonate, ( Z )-alkenylsilanes reacted with various carbon... 
paper | tandem reaction | allylsilanes | alkenylsilanes | platinum catalysis | allylation | acetals
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 04/2019, Volume 21, Issue 8, pp. 2493 - 2497
Successive nucleophilic and electrophilic allylation mediated by the bis-Boc-carbonate derived from 2-methylene-1,3-propane diol enables formation of... 
HETEROCYCLES | ASYMMETRIC 3+2 CYCLOADDITION | ALLYLBORATION | CONSTRUCTION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | TRIMETHYLENEMETHANE | ALDEHYDES | STEREOSELECTIVE-SYNTHESIS | ALLYLSILANES | CARBOAMINATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2017, Volume 58, Issue 33, pp. 3242 - 3245
The reaction of cyclopentenylsilane derivatives with -Bu NF in THF at rt was shown to proceed with the regio- and stereoselective formation of the... 
“Push-pull” mechanism | Cyclopropanation reaction | Allylsilanes | Carbocyclization | Fluoride anion | CHEMISTRY, ORGANIC | "Push-pull" mechanism | Cyclopropane compounds
Journal Article
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