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allylsilane (159) 159
allylsilanes (125) 125
chemistry (42) 42
science & technology (41) 41
physical sciences (38) 38
allylation (25) 25
cyclization (17) 17
catalysis (16) 16
organic chemistry (16) 16
chemistry, multidisciplinary (15) 15
asymmetric synthesis (13) 13
chemical sciences (12) 12
letter (12) 12
lewis acid (12) 12
stereoselectivity (12) 12
synthesis (12) 12
aldehydes (11) 11
ketones (11) 11
palladium (11) 11
vinylsilanes (11) 11
annulation (10) 10
chemistry, organic (10) 10
pyrrolidine (9) 9
silicon (9) 9
stereoisomerism (9) 9
tetrahedrons (9) 9
alcohols (8) 8
alkenes (8) 8
allenes (8) 8
allylstannane (8) 8
asymmetric catalysis (8) 8
catalysts (8) 8
chemistry, physical (8) 8
cycloaddition (8) 8
diastereoselectivity (8) 8
olefins (8) 8
tetrahydrofuran (8) 8
homoallylic alcohols (7) 7
kemi (7) 7
regioselectivity (7) 7
silane (7) 7
vinylsilane (7) 7
aldehyde (6) 6
aldol reaction (6) 6
allylstannanes (6) 6
cross-coupling (6) 6
domino reactions (6) 6
molecular structure (6) 6
natural products (6) 6
natural sciences (6) 6
naturvetenskap (6) 6
ruthenium (6) 6
silanes - chemistry (6) 6
silylcupration (6) 6
chiral allylsilane (5) 5
cross-metathesis (5) 5
derivatives (5) 5
enantioselectivity (5) 5
ene reaction (5) 5
hosomi-sakurai reaction (5) 5
hydrosilylation (5) 5
intramolecular cyclization (5) 5
metathesis (5) 5
polymer science (5) 5
stereochemistry (5) 5
stereoselective (5) 5
total synthesis (5) 5
α-methylene-γ-lactone (5) 5
acetal (4) 4
allene (4) 4
allylgermane (4) 4
allyltin (4) 4
asymmetrische katalyse (4) 4
chiral allylsilanes (4) 4
cobalt (4) 4
conjugate addition (4) 4
construction (4) 4
copper (4) 4
cyclizations (4) 4
cyclobutane (4) 4
dehydrogenative silylation (4) 4
diastereoselective synthesis (4) 4
esters (4) 4
fluorine (4) 4
heck reaction (4) 4
heterocycles (4) 4
michael addition (4) 4
organisk kemi (4) 4
organocatalysis (4) 4
radicals (4) 4
selectivity (4) 4
sigmatropic rearrangement (4) 4
silver (4) 4
反応 (4) 4
1,4-asymmetric induction (3) 3
[chim]chemical sciences (3) 3
accessibility (3) 3
alkaloid (3) 3
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Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2012, Volume 51, Issue 19, pp. 4577 - 4580
CF3 on C sp 3: Trifluoromethylation of allylsilane derivatives was accomplished through the use of CuI and Togni's reagent (1) under mild conditions. The... 
copper | allylsilanes | trifluoromethylation | homogeneous catalysis | fluorine | Silanes - chemistry | Copper - chemistry | Catalysis | Methylation | Palladium - chemistry | Fluorine - chemistry | Index Medicus
Journal Article
Synthesis, ISSN 0039-7881, 02/2016, Volume 48, Issue 4, pp. 520 - 534
Abstract In the presence of catalytic amounts of platinum(II) chloride and silver(I) hexafluoroantimonate, ( Z )-alkenylsilanes reacted with various carbon... 
paper | tandem reaction | allylsilanes | alkenylsilanes | platinum catalysis | allylation | acetals
Journal Article
Synlett, ISSN 0936-5214, 12/2010, Volume 2010, Issue 19, pp. 2879 - 2882
Abstract The cationic gold(I)-catalyzed reaction of 1-alkynyl-2-allylsilylbenzenes with water results in intramolecular allylation of the alkynes via 7-EXO-dig... 
letter | gold | catalysis | allylsilanes | 1,4-dienes | allylation
Journal Article
Tetrahedron, ISSN 0040-4020, 10/2020, Volume 76, Issue 40, p. 131493
The palladium-catalyzed reaction of γ-silylated allyl acetates with water in the presence of CsF induces a previously unprecedented 1,2-shift of a substituent... 
Homoallylic alcohols | Palladium | π-Allylpalladium | Migration | Allylsilanes
Journal Article
Synlett, ISSN 1437-2096, 01/2007, Volume 2007, Issue 1, pp. 0075 - 0078
Abstract Synthesis of Z-allylsilanes in high or good yields and with good stereoselectivity is achieved from O-acetylated 1-silyl-3-chloro alcohols promoted by... 
letter | Samarium | Eliminations | Diastereoselectivity | Allylsilanes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2014, Volume 53, Issue 40, pp. 10759 - 10762
An enantioselective allyl–allylsilane cross‐coupling involving racemic branched allylic alcohols and allylsilanes is reported. An iridium‐(P,olefin)... 
enantioselectivity | iridium | 1,5‐diene | allylic substitution | allylsilane | 1 5-diene | Enantiomers | Insecticides | Analysis | Utilities | Synthesis | Asymmetry | Catalysts | Branched | Joining | Transformations | Alcohols
Journal Article
Synlett, ISSN 0936-5214, 12/2007, Volume 2007, Issue 19, pp. 3022 - 3026
Abstract The electrophilic fluorination of silylated N,O-heterocycles, prepared from a nitroso-Diels-Alder reaction of silylated dienes, afforded fluorinated... 
letter | Oxazines | Silicon | Fluorine | Diastereoselectivity | Allylsilanes
Journal Article
Tetrahedron letters, ISSN 0040-4039, 01/2020, Volume 61, Issue 2, p. 151384
[Display omitted] The halogenation of various α-ester allylsilanes with halo-succinimides (NXS, X = Cl, Br, and I) has been investigated. It has been shown... 
Diastereoselective synthesis | Allylsilane | Olefination | Halogenation
Journal Article
European journal of organic chemistry, ISSN 1434-193X, 2009, Issue 30, pp. 5132 - 5134
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 07/2013, Volume 19, Issue 28, pp. 9167 - 9185
Detailed kinetic and computational investigation of the enantio‐ and diastereoselective allylation of aldehydes 1 with allyltrichlorosilanes 5, employing the... 
organocatalysis | allylsilanes | calculations | allylation | pyridine N‐oxides | pyridine N-oxides | Alkaloids | Oxides | Pyridine | Aldehydes | Pyridines | Asymmetry | Computation | Cationic | Chemical reactions | Allyl compounds | Dichotomies | Kemi | Chemical Sciences
Journal Article
Synlett, ISSN 0936-5214, 10/2006, Volume 2006, Issue 16, pp. 2589 - 2592
Abstract Acetals react with allyltrimethylsilane in the presence of a catalytic amount of sulfonic acids to give the corresponding homoallylic ethers in high... 
letter | Hosomi-Sakurai reaction | Acetals | Brønsted acid catalysis | Organocatalysis | Allylsilanes
Journal Article
Journal of molecular modeling, ISSN 0948-5023, 12/2016, Volume 23, Issue 1, pp. 1 - 11
Journal Article
Synthesis, ISSN 0039-7881, 04/2012, Volume 44, Issue 8, pp. 1199 - 1207
Abstract The embodiment of lactam rings within a wealth of physiologically active natural products and pharmaceutical agents ensures that the development of... 
special topic | hypervalent iodine | aziridinium | nitrenium ion | allylsilane | O- alkyl hydroxamate
Journal Article
Synlett, ISSN 0936-5214, 4/2007, Volume 2007, Issue 7, pp. 1166 - 1168
Abstract A synthesis of enantioenriched fluorinated carbocycles has been developed combining a sequential enantioselective silyl­allylboration-ring-closing... 
cluster | Stereoselectivity | Silicon | Allylsilane | Fluorine
Journal Article
Tetrahedron letters, ISSN 0040-4039, 06/2004, Volume 45, Issue 24, pp. 4677 - 4679
The reaction of trimethylsilylmethylmagnesium chloride (TMSCH MgCl) with 1,2-dihalogenoethylene in the presence of 1mol% of Co(II) or Co(III) acetylacetonate... 
Allylsilane | Co-catalyst | Cross-coupling
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 08/2014, Volume 356, Issue 11‐12, pp. 2661 - 2670
We report the first successful allylation of aromatic esters by allyltrimethylsilane. The reaction is mediated by 0.3–1.0 equiv. of titanium tetrachloride... 
Lewis acids | allylsilanes | esters | triallylmethanes | allylation | Synthesis | Tetrachlorides | Accessibility | Titanium | Esters | Models | Derivatives | Catalysis
Journal Article
Tetrahedron letters, ISSN 0040-4039, 04/2020, Volume 61, Issue 18, p. 151777
[Display omitted] •Collection of novel 2-arylpiperidines prepared.•Synthesis features condensation of aryl aldehyde with amino allylsilane and tandem... 
Allylsilane | Iminium ion | Cyclization | Multicomponent assembly process
Journal Article
Synlett, ISSN 0936-5214, 03/2011, Volume 2011, Issue 5, pp. 679 - 683
Abstract Motivated by our preliminary results on Cp 2 TiF 2 -catalysed 1,4-hydrosilylation of monosubstituted dienes, we assessed the performance of several... 
letter | hydrosilylation | homo-geneous catalysis | diene | titanium | allylsilane
Journal Article
Synthesis, ISSN 0039-7881, 05/2012, Volume 44, Issue 10, pp. 1535 - 1541
Abstract A copper-catalyzed γ-selective allyl–alkyl coupling between γ-silylated allylic phosphates and alkylboron compounds (alkyl-9-BBN, prepared by... 
special topic
Journal Article
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