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Journal of the American Chemical Society, ISSN 0002-7863, 03/2010, Volume 132, Issue 8, pp. 2775 - 2783
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 1, pp. 76 - 79
A highly selective NHC-catalyzed synthesis of γ-butyro­lactones from the fusion of enals and α-keto­phosphonates has been developed. Computational modeling of... 
INTERMOLECULAR STETTER REACTIONS | COOPERATIVE CATALYSIS | ENANTIOSELECTIVE SYNTHESIS | ENOL ETHERS | ALPHA,BETA-UNSATURATED ALDEHYDES | CONJUGATE UMPOLUNG | ALPHA-HYDROXY PHOSPHONATES | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | GAMMA-BUTYROLACTONES | DIRECT ANNULATIONS
Journal Article
Tetrahedron, ISSN 0040-4020, 05/2017, Volume 73, Issue 20, pp. 2923 - 2930
A highly enantioselective 1, 3-dipolar cycloaddition of nitrone with α, β-unsaturated acyl phosphonate was developed for the first time by using a chiral... 
α, β-unsaturated acyl phosphonate | Nitrone | Dipolar cycloaddition | Isoxazolidine | 3-ALKENOYL-2-OXAZOLIDINONES | CATALYSIS | LEWIS-ACID | CHEMISTRY, ORGANIC | ALDEHYDES | alpha, beta-unsaturated acyl phosphonate | BIS(OXAZOLINE) COPPER(II) COMPLEXES | TRIFLATE COMPLEXES | MICHAEL ADDITION | DERIVATIVES | CONJUGATE ADDITION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2003, Volume 44, Issue 14, pp. 2803 - 2805
Treatment of acyl phosphonates with allylindium reagents in the presence of acetic acid afforded the corresponding α-hydroxy alkylphosphonates in good yields... 
FARNESYL-PROTEIN TRANSFERASE | OXIDATION | BETA-KETO PHOSPHONATES | ALPHA,BETA-UNSATURATED KETONES | ANALOGS | PYROPHOSPHATE | AQUEOUS-MEDIA | CHEMISTRY, ORGANIC | INHIBITORS | DERIVATIVES | INDIUM
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2011, Volume 76, Issue 10, pp. 4119 - 4124
By employing a cinchonine-based thiourea as catalyst, highly enantioselective Michael addition reactions of 2-hydroxy-1,4-naphthoquinone to β,γ-unsaturated... 
CATALYSIS | ASYMMETRIC CONJUGATE ADDITION | NITROALKANES | CHALCONES | CHEMISTRY, ORGANIC | HETERO-DIELS-ALDER | ALPHA,BETA-UNSATURATED IMIDES | ACYL PHOSPHONATES
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/1996, Volume 61, Issue 21, pp. 7455 - 7462
The unique electronic and structural nature of the α-acylphosphonate functional group affords both dimeric and chelated complexes of diethyl crotonyl... 
SOLID-PHASE REACTION | ACYCLIC STEREOSELECTION | TITANIUM TETRACHLORIDE | VINYL KETONE | ALPHA,BETA-UNSATURATED KETONES | MULTIPLE-QUANTUM NMR | EFFECTIVE CATALYSTS | SILYL ENOL ETHERS | COMPLEXES | CHEMISTRY, ORGANIC | CONJUGATE ADDITION | Phosphonates | Research
Journal Article
Organic Letters, ISSN 1523-7060, 09/2009, Volume 11, Issue 17, pp. 3870 - 3873
Lanthanum tricyanide efficiently catalyzes a benzoin-type coupling between acyl silanes and ketones. Yields range from moderate to excellent over a broad... 
TRIAZOLIUM SALTS | PHOSPHONATES | ACYLATION | DONOR | CHEMISTRY, ORGANIC | CONDENSATION | ALPHA,BETA-UNSATURATED AMIDES | ALDEHYDES | CYCLIZATION | CYANIDE | Silanes - chemistry | Combinatorial Chemistry Techniques | Cyanides - chemistry | Ketones - chemical synthesis | Ketones - chemistry | Benzoin - chemistry | Molecular Structure | Catalysis | Lanthanum - chemistry
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2010, Volume 75, Issue 10, pp. 3317 - 3325
We report the full account of our efforts on the lanthanum tricyanide-catalyzed acyl silane−ketone benzoin reaction. The reaction exhibits a wide scope in both... 
TRIAZOLIUM SALTS | PHOSPHONATES | NUCLEOPHILIC ACYLATION | SUBSTRATE | CHEMISTRY, ORGANIC | CONDENSATION | ALPHA,BETA-UNSATURATED AMIDES | ALDEHYDES | EFFICIENT | CYCLIZATION | CYANIDE
Journal Article
Chemical Science, ISSN 2041-6520, 10/2011, Volume 2, Issue 10, pp. 1918 - 1921
N-acyl pyrrole phosphonates were identified as a class of highly reactive HWE reagents. The asymmetric addition of the present HWE reagents to N-carbamoyl... 
ALPHA-AMIDO SULFONES | CINCHONA ALKALOIDS | ACID-DERIVATIVES | ALPHA,BETA-UNSATURATED N-ACYLPYRROLES | ACYL IMINES | BAYLIS-HILLMAN REACTION | BETA-KETO-ESTERS | CONJUGATE ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY | DIALKYL PHOSPHINE OXIDES | IN-SITU
Journal Article
SYNLETT, ISSN 0936-5214, 06/2013, Volume 24, Issue 10, pp. 1243 - 1249
NHC-mediated enantioselective formal [4+2] cycloadditions of alkylarylketenes with gamma-substituted-beta,gamma-unsaturated alpha-ketophosphonates is... 
N-HETEROCYCLIC CARBENE | ALPHA,BETA-UNSATURATED ALDEHYDES | CHEMISTRY, ORGANIC | asymmetric catalysis | DISUBSTITUTED KETENES | ACYL | MICHAEL ADDITION | NUCLEOPHILIC CARBENES | lactones | cycloaddition | asymmetric synthesis | ESTERS | CHIRAL ALCOHOLS | ASYMMETRIC ORGANOCATALYSIS | C-CARBOXYL TRANSFER | N-heterocyclic carbenes
Journal Article
Bioorganic & Medicinal Chemistry, ISSN 0968-0896, 09/2019, Volume 27, Issue 17, pp. 3929 - 3937
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 02/2018, Volume 59, Issue 7, pp. 568 - 582
Journal Article