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by Yao, JN and Liang, X and Wei, K and Yang, YR
ORGANIC LETTERS, ISSN 1523-7060, 10/2019, Volume 21, Issue 20, pp. 8485 - 8487
A catalytic, enantioselective formal synthesis of monoterpene indole alkaloid (-)-alstoscholarine is described. The synthesis employs an Ir-amine dual... 
CHEMISTRY | CHEMISTRY, ORGANIC | ALPHA-ALLYLATION
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 08/2014, Volume 47, Issue 8, pp. 2558 - 2573
Conspectus Dearomatization reactions serve as powerful methods for the synthesis of highly functionalized, three-dimensional structures starting with simple... 
ALCOHOLS | HIGHLY ENANTIOSELECTIVE SYNTHESIS | N-ALLOC | IRIDIUM | PHOSPHINE-LIGANDS | RUTHENIUM(IV) COMPLEXES | NAPHTHOL DERIVATIVES | ALKYLATION REACTIONS | ALPHA-ALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | Transition metals | Chemical properties | Research | Stereochemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 43, pp. 14354 - 14361
A highly enantioselective allylic C–H alkylation reaction of allylarenes with pyrazol-5-ones has been established by the cooperative catalysis of a chiral... 
OXIDATION | ALCOHOLS | ACTIVATION | ASYMMETRIC CONJUGATE ADDITION | ATOM ECONOMY | LIGANDS | ALPHA-ALLYLATION | METAL CATALYSIS | QUATERNARY | CHEMISTRY, MULTIDISCIPLINARY | MICHAEL ADDITION
Journal Article
Organic Letters, ISSN 1523-7060, 2019, Volume 21, Issue 7, pp. 2449 - 2452
Aromatic enamide and enecarbamate as a novel type of nucleophile in the asymmetric allylation of branched, racemic allylic alcohols to give homoallylic ketones... 
NUCLEOPHILES | CHEMISTRY, ORGANIC | ALPHA-ALLYLATION | ACID | ALLYLIC SUBSTITUTION
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 17, pp. 3114 - 3120
A new, simple protocol for the synthesis of acetals under basic conditions from non-enolizable aldehydes and alcohols has been reported. Such reactivity is... 
ACETALIZATION | CHEMISTRY, ORGANIC | KETONES | CARBONYL-COMPOUNDS | ALPHA-ALLYLATION | KETALIZATION
Journal Article
Chemical Society reviews, ISSN 0306-0012, 03/2017, Volume 46, Issue 6, pp. 1675 - 1692
The development of switchable chemo-, regio-, or diastereodivergent reactions, in which two or more structurally and stereogenically different types of chiral... 
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 11/2015, Volume 44, Issue 22, pp. 7929 - 7967
The transition metal-catalyzed allylic substitution of unactivated allylic substrates (allylic alcohols, allylic ethers and allylic amines) is rapidly becoming... 
Carbon-carbon composites | Amines | Byproducts | Substitution reactions | Wastes | Ethers | Substrates | Alcohols
Journal Article
Organic Letters, ISSN 1523-7060, 05/2015, Volume 17, Issue 10, pp. 2458 - 2461
Enantioselective arylation of secondary beta-C(sp(3))-H bonds of 8-aminoquinoline amides was realized with a palladium catalyst. Chiral phosphoric amides and... 
BRONSTED ACID | FUNCTIONALIZATION | ACTIVATION | C-H ARYLATION | COUPLING REACTIONS | ALKYLATION | INDOLINES | CHEMISTRY, ORGANIC | ALPHA-ALLYLATION | CARBON-CARBON | METAL CATALYSIS
Journal Article
CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2012, Volume 41, Issue 12, pp. 4467 - 4483
Modern organic synthesis now requires efficient atom economical synthetic methods operating under greener pathways to achieve C-C and C-heteroatom bond... 
TANDEM ALLYLATION | PALLADIUM(II) COMPLEXES | C-N BONDS | COORDINATION PROPERTIES | ACTIVE METHYLENE-COMPOUNDS | RUTHENIUM(IV) COMPLEXES | REGIOSELECTIVE ALLYLATION | ALPHA-ALLYLATION | ALIPHATIC-ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | DEHYDRATIVE ALLYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2017, Volume 19, Issue 12, pp. 3235 - 3238
A method for the enantioselective synthesis of carbo- and heterocyclic ring systems enabled through the combination of Lewis acid activation and... 
ALCOHOLS | AMINATION | ACID | TETRAHYDROISOQUINOLINES | HETEROCYCLES | ALKYLATION | BIFUNCTIONAL CATALYST | CHEMISTRY, ORGANIC | ALPHA-ALLYLATION | REISSERT-TYPE REACTION | DEAROMATIZATION
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 08/2014, Volume 47, Issue 8, pp. 2365 - 2377
Conspectus Asymmetric catalysis has been considered to be the most intriguing means for building collections of functionalized optically active compounds. In... 
TANDEM CATALYSIS | RELAY CATALYSIS | COOPERATIVE CATALYSIS | ENANTIOSELECTIVE SYNTHESIS | ALLYLIC ALKYLATION | TRANSFER HYDROGENATION | ALPHA-ALLYLATION | CHIRAL PHOSPHORIC-ACID | 3-COMPONENT REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | SPENGLER CASCADE | Chemical properties | Research | Metal catalysts | Organic compounds
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 18, pp. 4662 - 4665
A C–C formation of an electron-rich N-heterocycle with fluorinated alcohol is developed. Through this radical-triggered cross-dehydrogenative coupling... 
ALKENES | ETHERS | CARBON | IRIDIUM | ALKYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | ALPHA-ALLYLATION | ETHERIFICATION | C-H FUNCTIONALIZATION | ALKENYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 05/2016, Volume 18, Issue 9, pp. 2220 - 2223
The stereoselective [3 + 2] cycloaddition between vinylcyclopropanes and α,β-unsaturated aldehydes promoted by combined palladium and organocatalysis is... 
CASCADE TRANSFORMATIONS | TRANSITION-METAL CATALYSIS | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | ALPHA-ALLYLATION | VINYL CYCLOPROPANES | DUAL CATALYSIS | COMBINATION | ENANTIOSELECTIVE CONSTRUCTION | ECONOMY | CYCLOPENTANES
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2014, Volume 136, Issue 48, pp. 16756 - 16759
The selective reverse prenylation of 3-substituted-1H-indoles at C3 is described. The iridium-catalyzed reaction proceeds with high branched to linear... 
ALCOHOLS | DIMETHYLALLYLTRYPTOPHAN SYNTHASE | AMAUROMINE | LIGANDS | CARBON QUATERNARY STEREOCENTERS | ALLYLIC DEAROMATIZATION REACTION | ALPHA-ALLYLATION | ASZONALENIN | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | ALKALOIDS
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 3/2017, Volume 46, Issue 6, pp. 1675 - 1692
The development of switchable chemo-, regio-, or diastereodivergent reactions, in which two or more structurally and stereogenically different types of chiral... 
ANNULATIONS | CYCLIC ENONES | CARBONATES | ALLENOATES | REACTIVITY | ALPHA-ALLYLATION | 4+2 CYCLOADDITIONS | DUAL CATALYSIS | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ENALS | Activation | Synthesis | Catalysis | Asymmetry | Catalysts | Lewis base
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2017, Volume 139, Issue 10, pp. 3603 - 3606
Experimental mechanistic studies of iridium-catalyzed, enantioselective allylic substitution enabled by (phosphoramidite,olefin) ligands are reported.... 
AMINATION | ASYMMETRIC-SYNTHESIS | LIGANDS | (PI-ALLYL)IR COMPLEXES | ALKYLATION | COMPLEXES-RESTING STATES | ALPHA-ALLYLATION | CATALYST | REGIOSELECTIVITY | IRIDIUM COMPLEX | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2017, Volume 139, Issue 16, pp. 5627 - 5639
This Perspective presents an overview of catalytic enantio­selective transformations that allow convenient access to all stereo­isomers of a given product with... 
ACYCLIC STEREOSELECTION | DIVERSITY-ORIENTED SYNTHESIS | COOPERATIVE CATALYSIS | NONADJACENT STEREOCENTERS | SMALL MOLECULES | SYNERGISTIC CATALYSIS | ALDOL REACTIONS | ALPHA-ALLYLATION | DUAL CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | ALLYLIC SUBSTITUTIONS | Usage | Chemical properties | Catalysis | Chemical synthesis | Isomerism
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 11/2015, Volume 44, Issue 22, pp. 7929 - 7967
Journal Article
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