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alpha-aminoalkyl radicals (60) 60
chemistry, organic (26) 26
chemistry, multidisciplinary (20) 20
amines (17) 17
catalysis (17) 17
chemistry, physical (13) 13
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α-aminoalkyl radical (4) 4
ab-initio (3) 3
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Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9016 - 9085
Research and industrial interest in radical C–H activation/radical cross-coupling chemistry has continuously grown over the past few decades. These reactions... 
METAL-FREE SYNTHESIS | C(SP)-H BOND FUNCTIONALIZATION | ACTIVATED ALKENES | FREE OXIDATIVE FUNCTIONALIZATION | CATALYZED ORTHO-ACYLATION | 1,3-DICARBONYL COMPOUNDS | ALPHA-AMINOALKYL RADICALS | EFFICIENT SYNTHESIS | ELECTRON-DEFICIENT ALKENES | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2017, Volume 139, Issue 35, pp. 12259 - 12266
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2018, Volume 8, Issue 10, pp. 9471 - 9476
A protocol for the photooxidative activation of α-silylamines and α-amino acids for desilylative and decarboxylative additions, allylations, and... 
α-aminoalkyl radical | continuous flow | heterogeneous photocatalyst | carbon nitride | visible-light photocatalysis | C-C-BOND | SELECTIVE OXIDATION | BENZENE | PHENOL | alpha-aminoalkyl radical | CHEMISTRY, PHYSICAL | CYCLIZATION REACTIONS | AMINE ALPHA,BETA-UNSATURATED KETONE | GENERATION | PHOTOCATALYSTS | PHOTOCYCLIZATION REACTIONS | WATER
Journal Article
Beilstein Journal of Organic Chemistry, ISSN 1860-5397, 10/2013, Volume 9, Issue 1, pp. 1977 - 2001
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 5, pp. 925 - 931
Substituted Hantzsch esters can act as radical reservoirs in photoredox reactions, steadily releasing a carbon radical and a hydrogen atom radical in the... 
Photoredox | Radical | Hantzsch ester | Alkylation | TRANSITION-METAL CATALYSIS | PHOTOCATALYTIC REDUCTION | COMPLEXES | ALPHA-AMINOALKYL RADICALS | CHEMISTRY, ORGANIC | C-C CLEAVAGE | VISIBLE-LIGHT | ALKYLATION REAGENTS | GENERATION | ELECTRON-DEFICIENT ALKENES | CHEMISTRY, APPLIED | DUAL CATALYSIS | Hydrogen | Reservoirs | Esters | Substitutes | Styrenes | Reagents
Journal Article
Organic Letters, ISSN 1523-7060, 12/2016, Volume 18, Issue 24, pp. 6304 - 6307
A general and efficient visible light photocatalytic α-amino carbon radical-based cascade reaction of aroylhydrazones has been described. This protocol... 
FUNCTIONALIZATION | VISIBLE-LIGHT | ORGANIC-SYNTHESIS | ELECTRON-TRANSFER | LIGHT PHOTOREDOX CATALYSIS | ALPHA-AMINOALKYL RADICALS | CHEMISTRY, ORGANIC | MICHAEL ACCEPTORS | C-H BONDS | CYCLIZATION | HETEROCYCLIC-COMPOUNDS
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 04/2013, Volume 3, Issue 4, pp. 935 - 937
Amine-derived radicals, formed through photocleavage of aromatic ketones containing amine moieties or by electron transfer between tertiary amines and the... 
OXIDATION | VISIBLE-LIGHT PHOTOCATALYSIS | QUANTUM YIELDS | ALKYL | ALPHA-AMINOALKYL RADICALS | BENZOPHENONE | CHEMISTRY, PHYSICAL | POTENTIALS | KETYL | CATIONS | Carbonyl compounds | Amines | Ketones | Catalysts | Aromatic compounds | Electron transfer | Catalysis | Radicals
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 4002 - 4006
The synthetic utility of tertiary amines to oxidatively generate α‐amino radicals is well established, however, primary amines remain challenging because of... 
amines | reaction mechanisms | radicals | photochemistry | synthetic methods | ACIDS | ALPHA-AMINOALKYL RADICALS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ATOM | FUNCTIONALIZATION | ABSTRACTION | ADDITION-REACTIONS | ARENECARBONITRILES | ALIPHATIC-AMINES | PHOTOCHEMICAL-REACTIONS | Side reactions | Divergence | Amines | Alkenes | Sulfonamides | Selectivity | Catalysis | Derivatives | Amino radical | Alkylation | Intermediates
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 04/2019, Volume 361, Issue 7, pp. 1549 - 1553
Journal Article
Chemical Reviews, ISSN 0009-2665, 09/2016, Volume 116, Issue 17, pp. 10075 - 10166
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic transformations with a range of applications. This overview is... 
ARYL DIAZONIUM SALTS | C-H ARYLATION | PHOTOINDUCED ELECTRON-TRANSFER | DIELS-ALDER REACTION | ANTI-MARKOVNIKOV ADDITION | ALPHA-AMINOALKYL RADICALS | AEROBIC OXIDATIVE CYCLIZATION | ALIPHATIC CARBOXYLIC-ACIDS | TRIPLET EXCITED-STATE | CHEMISTRY, MULTIDISCIPLINARY | VISIBLE-LIGHT IRRADIATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2001, Volume 123, Issue 40, pp. 9727 - 9737
The fluorescence and phosphorescence quenching of acetone by 13 aliphatic amines has been investigated. The bimolecular rate constants lie in the range of... 
ELECTRON-TRANSFER | IONIZATION-POTENTIALS | N,PI-ASTERISK-EXCITED AZOALKANES | QUANTUM YIELDS | HINDERED-AMINE | TERTIARY-AMINES | ALPHA-AMINOALKYL RADICALS | GAS-PHASE | ABSOLUTE RATE CONSTANTS | CHARGE-TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | Chemical properties | Acetone | Photochemistry
Journal Article