X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
alpha-arylation (883) 883
chemistry, organic (779) 779
chemistry, multidisciplinary (471) 471
catalysis (371) 371
palladium (357) 357
ketones (238) 238
index medicus (218) 218
derivatives (178) 178
arylation (174) 174
aryl halides (168) 168
molecular structure (151) 151
catalyzed alpha-arylation (146) 146
cross-coupling reactions (138) 138
ligands (135) 135
chemical properties (117) 117
palladium - chemistry (110) 110
cyclization (109) 109
stereoisomerism (107) 107
esters (104) 104
coupling reactions (103) 103
synthesis (101) 101
alkylation (100) 100
chemistry (97) 97
carbonyl-compounds (96) 96
enantioselective alpha-arylation (92) 92
asymmetric-synthesis (91) 91
one-pot synthesis (90) 90
aldehydes (87) 87
complexes (85) 85
oxindoles (85) 85
halides (84) 84
activation (83) 83
direct alpha-arylation (83) 83
enantioselective synthesis (82) 82
bromides (81) 81
aromatic compounds (80) 80
arylboronic acids (79) 79
chemistry, inorganic & nuclear (78) 78
copper (78) 78
aryl chlorides (76) 76
catalysts (76) 76
functionalization (76) 76
amides (73) 73
analysis (72) 72
cross-coupling (71) 71
organic chemistry (70) 70
bond formation (67) 67
c-h activation (66) 66
efficient (66) 66
chemistry, applied (65) 65
research (65) 65
organic-synthesis (64) 64
intramolecular alpha-arylation (62) 62
room-temperature (62) 62
c-h bonds (61) 61
c-h functionalization (61) 61
homogeneous catalysis (61) 61
efficient synthesis (60) 60
aryl bromides (59) 59
reductive elimination (58) 58
ligand (56) 56
nitriles (56) 56
heterocycles (55) 55
oxidation (55) 55
chlorides (54) 54
construction (54) 54
α-arylation (53) 53
asymmetric catalysis (52) 52
palladium catalysts (52) 52
amines (50) 50
article (50) 50
amination (48) 48
chemical synthesis (48) 48
chemistry, physical (48) 48
diaryliodonium salts (48) 48
reagents (48) 48
alkaloids (47) 47
chemical sciences (46) 46
indoles - chemistry (46) 46
nickel (46) 46
synthetic methods (46) 46
arylierung (45) 45
indoles (45) 45
oxidative addition (45) 45
ketones - chemistry (44) 44
stereoselective-synthesis (44) 44
heck reaction (43) 43
alkynes (42) 42
indoles - chemical synthesis (40) 40
inhibitors (39) 39
suzuki-miyaura (38) 38
aryl (37) 37
c-n (37) 37
palladium catalysis (37) 37
iodides (36) 36
n-heterocyclic carbenes (36) 36
reactivity (36) 36
arenes (35) 35
carboxylic-acids (35) 35
olefins (35) 35
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 07/2009, Volume 131, Issue 26, pp. 9168 - 9168
Catalytic asymmetric 1,4-additions of 3-substituted oxindoles to beta-aryl, beta-heteroaryl, and beta-alkenyl nitroalkenes are described. A new homodinuclear... 
REARRANGEMENT | ENANTIOSELECTIVE SYNTHESIS | ALPHA-ARYLATION | ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
SCIENCE, ISSN 0036-8075, 06/2016, Volume 352, Issue 6291, pp. 1304 - 1308
The use of sp(3) C-H bonds-which are ubiquitous in organic molecules-as latent nucleophile equivalents for transition metal-catalyzed cross-coupling reactions... 
OXIDATION | ALPHA-ARYLATION | AMINES | ACIDS | STRATEGY | MULTIDISCIPLINARY SCIENCES | ARYL HALIDES | C(SP)-H ARYLATION | PHOTOREDOX CATALYSIS
Journal Article
Chemical Science, ISSN 2041-6520, 2019, Volume 10, Issue 12, pp. 3586 - 3591
The first organocatalysed, metal-free cross-nucleophile coupling of indoles with -branched aldehydes forming acyclic stereoselective quaternary carbon centres... 
ALPHA-ARYLATION | AMINES | CHEMISTRY, MULTIDISCIPLINARY | ALKYLATION
Journal Article
by Fu, GC
ACCOUNTS OF CHEMICAL RESEARCH, ISSN 0001-4842, 11/2008, Volume 41, Issue 11, pp. 1555 - 1564
Metal-catalyzed coupling reactions of aryl electrophiles with organometallics and with olefins serve as unusually effective tools for forming new carbon-carbon... 
HALIDES | CROSS-COUPLINGS | MILD CONDITIONS | ALPHA-ARYLATION | CHLOROARENES | SCOPE | CHLORIDES | HECK REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | GENERAL-METHOD
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 11/2008, Volume 41, Issue 11, pp. 1523 - 1533
N-Heterocyclic carbenes (NHCs), especially monodentate ones, have become the ligand of choice for many transition-metal-catalyzed transformations. They... 
ELECTRONIC-PROPERTIES | ROOM-TEMPERATURE | TRANSITION-METAL-COMPLEXES | RUCL CP-ASTERISK | SECONDARY ALKYL BROMIDES | ALPHA-ARYLATION | HOMOGENEOUS CATALYSIS | ETA-C5ME5 MOIETY | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA | NEGISHI REACTIONS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2015, Volume 137, Issue 4, pp. 1416 - 1419
Arylation using diaryliodonium salts generates one equivalent of an iodoarene as a side-product, a significant waste of atom economy. Here, we show that... 
METAL-FREE SYNTHESIS | IODONIUM SALTS | PHENYLATION | PHOTOREDOX | PALLADIUM-CATALYZED ARYLATION | SELECTIVE ARYLATION | CARBAZOLES | ENANTIOSELECTIVE ALPHA-ARYLATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | OXYARYLATION | Copper compounds | Nitrogen compounds | Chemical properties | Indole
Journal Article
Organic Letters, ISSN 1523-7060, 11/2015, Volume 17, Issue 21, pp. 5384 - 5387
An efficient and general method for the synthesis of difluoroalkylated phenanthridine derivatives through palladium-catalyzed reaction of difluoroalkyl... 
ALKENES | DIFLUOROMETHYLATION | ARYL BORONIC ACIDS | PHOSPHONATES | HETEROCYCLES | ALPHA-ARYLATION | FLUOROALKYLATION | CHEMISTRY, ORGANIC | RADICAL TRIFLUOROMETHYLATION | ALPHA,ALPHA-DIFLUOROKETONES | INHIBITORS
Journal Article
Organic Letters, ISSN 1523-7060, 09/2012, Volume 14, Issue 17, pp. 4525 - 4527
Copper(I)-catalyzed dearomative arylation and vinylation of 2-substituted tryptophols were realized with a subsequent cyclization reaction. The cascade... 
(-)-PHYSOVENINE | ALKYLATION | CONSTRUCTION | INDOLINES | CHEMISTRY, ORGANIC | DIARYLIODONIUM SALTS | ALLYLIC DEAROMATIZATION | ENANTIOSELECTIVE ALPHA-ARYLATION | DERIVATIVES | PYRROLOINDOLINES | INDOLES
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 12/2015, Volume 17, Issue 24, pp. 6074 - 6077
Novel and general copper-catalyzed cyclopropanol ring opening cross-coupling reactions with difluoroalkyl bromides, perfluoroalkyl iodides, monofluoroalkyl... 
ETHYL BROMODIFLUOROACETATE | MEDIATED DIFLUOROMETHYLATION | ARYL BORONIC ACIDS | ALPHA-ARYLATION | SECONDARY | CHEMISTRY, ORGANIC | GENERAL-APPROACH | SILYL ETHERS | BROMIDES | ALKYL-HALIDES | TRIFLUOROMETHYLATION
Journal Article
Nature Communications, ISSN 2041-1723, 04/2015, Volume 6, Issue 1, p. 7011
Cascade reactions initiated by radical addition to alkynes are synthetically very attractive because they enable access to highly complex molecular skeletons... 
ALKENES | KETONES | SULFONYL KETIMINES | AMINATION | ASYMMETRIC-SYNTHESIS | ALPHA-ARYLATION | CATALYTIC HYDROAMINATION | MULTIDISCIPLINARY SCIENCES | ARYL HALIDES | BONDS | TERMINAL ALKYNES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 36, pp. 11562 - 11565
A mild Ni-catalyzed reductive arylation of tertiary alkyl halides with aryl bromides has been developed that delivers products bearing all-carbon quaternary... 
CONCISE TOTAL-SYNTHESIS | ALPHA-ARYLATION | KETONE FORMATION | ALLYLATION | UNACTIVATED PRIMARY | SECONDARY | ORGANIC HALIDES | CARBOXYLATION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | TOSYLATES | Arylation | Usage | Chemical properties | Metal catalysts | Halides | Isomerization
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 05/2016, Volume 81, Issue 9, pp. 3654 - 3664
An efficient and general method for C(sp(2))-H difluoroalkylation of aldehyde derived hydrazones via a Cu-II/B(2)pin(2)-catalyzed reaction between... 
PHARMACEUTICALS | ALPHA-ARYLATION | ALKYLATION | PROGRESS | CHEMISTRY, ORGANIC | FLUORINE | C-H DIFLUOROALKYLATION | ALPHA,ALPHA-DIFLUOROKETONES | RADICAL-ADDITION | BROMIDES | TRIFLUOROMETHYLATION
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 11/2013, Volume 135, Issue 46, pp. 17602 - 17609
The Tsuji-Trost allylic substitution reaction provides a useful and efficient approach to construct C-C bonds between sp(3)-hybridized carbons. The widely... 
AMINATION | LIGANDS | DIPHENYLPHOSPHINO | ALPHA-ARYLATION | ALKYLATION | REGIO | EQUILIBRIUM ACIDITIES | METAL | REGIOSELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | CARBON ACIDS
Journal Article
Organometallics, ISSN 0276-7333, 10/2015, Volume 34, Issue 23, pp. 5497 - 5508
A brief account of the major developments of palladium-catalyzed cross-coupling during the last two decades is highlighted chronologically, with an emphasis on... 
AIR-STABLE CATALYSTS | ROOM-TEMPERATURE | HIGHLY-ACTIVE CATALYST | ALPHA-ARYLATION | C-N | HETEROCYCLIC CARBENE COMPLEXES | CHEMISTRY, ORGANIC | DEACTIVATED ARYL CHLORIDES | SUZUKI-MIYAURA | LARGE-SCALE APPLICATIONS | GENERAL-METHOD | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
by Basle, O and Li, CJ
ORGANIC LETTERS, ISSN 1523-7060, 09/2008, Volume 10, Issue 17, pp. 3661 - 3663
An efficient method was developed for arylation of sp(3) C-H bonds using copper bromide as catalyst in absence of directing group with arylboronic acids. The... 
HALIDES | ACTIVATION | COMPLEX | TETRAHYDROISOQUINOLINES | ALPHA-ARYLATION | NITROGEN ATOM | CHEMISTRY, ORGANIC | ADJACENT | ALKYNYLATION | DERIVATIVES
Journal Article
Synlett, ISSN 0936-5214, 10/2014, Volume 25, Issue 16, pp. 2377 - 2378
Using 1,4-naphthoquinone (1) as arylation reagent, Jorgensen and co-workers realized the highly enantioselective alpha-arylation of aldehydes 2, affording... 
spotlight | OXINDOLES | CHEMISTRY, ORGANIC | ALPHA-ARYLATION
Journal Article
Chemical Society reviews, ISSN 0306-0012, 02/2010, Volume 39, Issue 2, pp. 694 - 711
The strong electron-donation and the steric bulk of trialkylphosphines renders them as very useful ligands for palladium-catalyzed cross coupling reactions.... 
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2010, Volume 39, Issue 2, pp. 694 - 711
The strong electron-donation and the steric bulk of trialkylphosphines renders them as very useful ligands for palladium-catalyzed cross coupling reactions.... 
ELECTRON-RICH PHOSPHINES | ROOM-TEMPERATURE | ALPHA-ARYLATION | C-O BOND | RESONANCE ENERGY-TRANSFER | HOMOGENEOUS CATALYSIS | DEACTIVATED ARYL CHLORIDES | OXIDATIVE ADDITION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2008, Volume 47, Issue 17, pp. 3096 - 3099
Copper makes the difference: Important challenges have been overcome in copper‐catalyzed Ullmann reactions since its renaissance in the early 2000s.... 
enantioselectivity | copper | homogeneous catalysis | cross‐coupling | arylation | Arylation | Cross-coupling | Enantioselectivity | Copper | Homogeneous catalysis | ALPHA-ARYLATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | ETHER FORMATION | IODIDES | MILD CONDITIONS | LIGANDS | ARYL HALIDES | cross-coupling | NITROGEN | BENZIMIDAZOLES
Journal Article
No results were found for your search.

Cannot display more than 1000 results, please narrow the terms of your search.