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chemistry, organic (83) 83
alpha-diazo ketones (68) 68
chemistry, multidisciplinary (29) 29
catalysis (24) 24
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intermolecular 1,3-dipolar cycloaddition (11) 11
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chiral dirhodium carboxylates (10) 10
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carbonyl ylide formation (9) 9
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wolff rearrangement (9) 9
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esters (8) 8
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ylides (8) 8
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acyldiazomethanes (7) 7
alkyne insertion reactions (7) 7
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chemistry (7) 7
chemistry, inorganic & nuclear (7) 7
complexes (7) 7
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organic chemistry (7) 7
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alpha-diazo carbonyls (6) 6
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ethyl diazoacetate (6) 6
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zaragozic acids (6) 6
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alkynes - chemistry (5) 5
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amines (5) 5
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1,3-dipolar cycloaddition reactions (4) 4
alkaloids (4) 4
alkene dipolarophiles (4) 4
alpha-diazo compounds (4) 4
aspidosperma alkaloids (4) 4
azo compounds - chemistry (4) 4
beta-hydroxy esters (4) 4
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diazoacetophenone derivatives (4) 4
dipolar cycloaddition (4) 4
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Chemistry – A European Journal, ISSN 0947-6539, 08/2015, Volume 21, Issue 33, pp. 11671 - 11676
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 40, pp. 13974 - 13982
A detailed quantum mechanical study on the role of transition metal fragments towards the epoxidation reaction of metallabenzynes (1M, M = Fe, Ru, Os) to give... 
TRIPLET GROUND-STATE | AB-INITIO | BASIS-SETS | METALLABENZYNES | DENSITY-FUNCTIONAL THEORY | CARBENE COMPLEXES | ABSORPTION INTENSITY CALCULATIONS | ALPHA-DIAZO-KETONES | MOLECULAR-ORBITAL CALCULATIONS | INDEPENDENT CHEMICAL-SHIFTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2012, Volume 51, Issue 9, pp. 2093 - 2097
Pass the baton: A one‐pot relay catalysis for a carbonyl ylide formation/enantioselective reduction sequence using a dirhodium(II) tetracarboxylate and chiral... 
organocatalysis | ylides | asymmetric catalysis | reduction | rhodium | ACYLIMINIUM CYCLIZATION CASCADES | BOND-FORMING REACTIONS | INTERMOLECULAR 1,3-DIPOLAR CYCLOADDITION | TRANSFER HYDROGENATION | DIRHODIUM(II) CARBOXYLATES | ASYMMETRIC CYCLOADDITIONS | CHEMISTRY, MULTIDISCIPLINARY | CHIRAL PHOSPHORIC-ACIDS | ALPHA-DIAZO KETONES | LEWIS-ACIDS | C-H
Journal Article
Organic Letters, ISSN 1523-7060, 12/2015, Volume 17, Issue 23, pp. 5760 - 5763
A method for chemoselective carbonyl ylide formation utilizing the Rh­(II) catalyzed decomposition of electronically differentiated diazo malonates is... 
REARRANGEMENT | DIRHODIUM(II) | CYCLIZATION-CYCLOADDITION REACTION | ZARAGOZIC-ACID-C | 1,3-DIPOLAR | STRATEGY | CONSTRUCTION | CHEMISTRY, ORGANIC | ALPHA-DIAZO KETONES | RHODIUM CARBENOIDS | ALKALOIDS | Cyclization | Malonates - chemistry | Stereoisomerism | Esters | Alkynes - chemistry | Molecular Structure | Catalysis | Rhodium - chemistry
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2003, Volume 68, Issue 2, pp. 581 - 586
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2009, Volume 131, Issue 3, pp. 1101 - 1105
Conditions are described for the Rh-catalyzed formation of highly functionalized dihydro- and tetrahydrofuran products via three-component reactions of... 
MULTICOMPONENT REACTIONS | SPIRO-DIOXOLANES | 1,3-DIPOLAR CYCLOADDITION | AZOMETHINE YLIDES | DICARBOMETHOXYCARBENE | ALPHA-DIAZO KETONES | ALDEHYDES | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | DIAZOESTERS
Journal Article
Organic Letters, ISSN 1523-7060, 10/2007, Volume 9, Issue 21, pp. 4359 - 4362
We have found the first successful example of reverse-electron-demand dipole-LUMO/dipolarophile-HOMO controlled cycloaddition reactions between carbonyl... 
CONSTRUCTION | COMPLEXES | CYCLIZATION/CYCLOADDITION CASCADE | CHEMISTRY, ORGANIC | ALPHA-DIAZO KETONES | INTERMOLECULAR CYCLOADDITIONS | ENANTIOSELECTIVE 1,3-DIPOLAR CYCLOADDITION
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 08/2013, Volume 11, Issue 32, pp. 5374 - 5382
The first catalytic asymmetric carbonyl ylide cycloaddition with arylallenes is described. With dirhodium(II)... 
DIRHODIUM(II) COMPLEX | NATURAL-PRODUCT | ACID | RH(II) CATALYST | GENERAL ACCESS | CHEMISTRY, ORGANIC | INTERMOLECULAR 1,3-DIPOLAR CYCLOADDITION | ALPHA-DIAZO KETONES | DIPOLAROPHILES | ALLENES | CATALYTIC ASYMMETRIC-SYNTHESIS
Journal Article
CHIMIA International Journal for Chemistry, ISSN 0009-4293, 03/2009, Volume 63, Issue 3, pp. 162 - 167
Journal Article
TETRAHEDRON LETTERS, ISSN 0040-4039, 12/2010, Volume 51, Issue 50, pp. 6572 - 6575
A catalytic asymmetric synthesis of descurainin has been achieved by incorporating an enantioselective 1,3-dipolar cycloaddition, a stereoselective alkene... 
1,3-Dipolar cycloaddition | CARBENOIDS | DNA TOPOISOMERASE-II | ONE-POT | CHIRAL DIRHODIUM(II) CARBOXYLATES | Carbonyl ylide | Descurainin | CYCLIZATION/CYCLOADDITION CASCADE | CHEMISTRY, ORGANIC | POLYGALOLIDE-B | Chiral dirhodium(II) catalyst | ALPHA-DIAZO KETONES | LEWIS-ACIDS | EFFICIENT | CYCLIZATION
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 09/2010, Volume 75, Issue 17, pp. 6039 - 6042
The reaction of a six-membered cyclic formyl-carbonyl ylide derived from alpha-diazo-beta-ketoester with phenylacetylene derivatives under the catalysis of... 
PRACTICAL ROUTE | GENERAL ACCESS | CHIRAL DIRHODIUM(II) CARBOXYLATES | CYCLIZATION/CYCLOADDITION CASCADE | CHEMISTRY, ORGANIC | ABSOLUTE STEREOCHEMISTRY | ALPHA-DIAZO KETONES | OXYALLYL CATIONS | POLYGALOLIDE-B | LEWIS-ACIDS | DERIVATIVES
Journal Article
ACS Sustainable Chemistry & Engineering, ISSN 2168-0485, 01/2018, Volume 6, Issue 1, pp. 1327 - 1335
Journal Article
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