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alpha-diazocarbonyl compounds (375) 375
chemistry, organic (225) 225
chemistry, multidisciplinary (151) 151
diazo-compounds (151) 151
organic-synthesis (127) 127
catalysis (95) 95
diazo compounds (86) 86
carbenes (56) 56
insertion (51) 51
derivatives (49) 49
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n-tosylhydrazones (48) 48
carbene insertion (41) 41
rhodium (41) 41
ethyl diazoacetate (37) 37
c-h insertion (36) 36
stereoselective-synthesis (36) 36
cyclopropanation (35) 35
esters (34) 34
carben (32) 32
synthesis (32) 32
carbonyl-compounds (31) 31
cross-coupling reactions (31) 31
c-h activation (29) 29
diazoverbindung (28) 28
efficient synthesis (28) 28
migratory insertion (28) 28
asymmetric-synthesis (27) 27
complexes (27) 27
palladium (27) 27
c-h functionalization (26) 26
chemical properties (26) 26
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metal carbene (26) 26
copper (25) 25
molecular structure (25) 25
activation (24) 24
catalysts (22) 22
h insertion reactions (22) 22
carbenoids (21) 21
enantioselective synthesis (21) 21
bond formation (20) 20
cycloaddition (20) 20
diazoesters (20) 20
rhodium carbenoids (20) 20
terminal alkynes (20) 20
transformations (20) 20
functionalization (19) 19
alkynes (18) 18
heterocycles (18) 18
indoles (18) 18
bonds (17) 17
carbene (17) 17
carbene migratory insertion (17) 17
chemical synthesis (17) 17
cyclization (17) 17
cycloaddition reactions (17) 17
insertion reactions (17) 17
olefins (17) 17
research (17) 17
alkenes (16) 16
chemical reactions (16) 16
ligands (16) 16
palladium - chemistry (16) 16
stereoisomerism (16) 16
aldehydes (15) 15
amino-acids (15) 15
azo compounds - chemistry (15) 15
chemistry, applied (15) 15
metal carbene transformations (15) 15
reagents (15) 15
rearrangement (15) 15
arylation (14) 14
arylboronic acids (14) 14
chemistry, inorganic & nuclear (14) 14
gold (14) 14
h bond functionalization (14) 14
ketones (14) 14
vinyl halides (14) 14
wolff rearrangement (14) 14
acid (13) 13
alkylation (13) 13
aryl halides (13) 13
asymmetric cyclopropanation (13) 13
benzyl bromides (13) 13
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aromatic compounds (12) 12
beta-keto-esters (12) 12
c-h bonds (12) 12
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gold catalysis (12) 12
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rhodium - chemistry (12) 12
usage (12) 12
acids (11) 11
aryl (11) 11
bond functionalization (11) 11
chemical bonds (11) 11
cyclopropane compounds (11) 11
decomposition (11) 11
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1. Full Text Cycloaddition reactions of enoldiazo compounds
by Cheng, Qing-Qing and Deng, Yongming and Lankelma, Marianne and Doyle, Michael P
Chemical Society Reviews, ISSN 0306-0012, 2017, Volume 46, Issue 17, pp. 5425 - 5443
Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition reactions that allow highly efficient construction of various carbocycles... 
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2. Full Text Cycloaddition reactions of enoldiazo compounds
by Cheng, Qing-Qing and Deng, Yongming and Lankelma, Marianne and Doyle, Michael P
Chemical Society Reviews, ISSN 0306-0012, 8/2017, Volume 46, Issue 17, pp. 5425 - 5443
Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition reactions that allow highly efficient construction of various carbocycles... 
METAL CARBENE TRANSFORMATIONS | ALPHA-DIAZOCARBONYL COMPOUNDS | ASYMMETRIC-SYNTHESIS | CATALYZED 4+3 CYCLOADDITION | AROMATIC AZOMETHINE IMINES | DONOR-ACCEPTOR CYCLOPROPENES | RHODIUM-STABILIZED VINYLCARBENOIDS | DIAZO-COMPOUNDS | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | PROTECTED ENOL DIAZOACETATES
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3. Full Text Cobalt(III)‐Catalyzed Alkylation of Primary C(sp3)–H Bonds with Diazo Compounds
by Yan, Sheng‐Yi and Ling, Peng‐Xiang and Shi, Bing‐Feng
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2017, Volume 359, Issue 17, pp. 2912 - 2917
Chelation‐assisted C(sp2)–H metalation/carbenoid insertion has been well investigated. However, the analogous carbene functionalization of C(sp3)–H bonds... 
carbenoid insertion | alkylation | cobalt | diazo compounds | C(sp3)–H activation | H activation | C(sp | ALPHA-DIAZOCARBONYL COMPOUNDS | CHEMISTRY, ORGANIC | CARBENE MIGRATORY INSERTION | N-OXIDES | C-H ACTIVATION | FACILE SYNTHESIS | MILD CONDITIONS | UNPROTECTED INDOLES | METAL CARBENE | C(sp)-H activation | COBALT CATALYSIS | RH(III)-CATALYZED SYNTHESIS | CHEMISTRY, APPLIED | Antibiotics | Chemical bonds | Chelation | Insertion | Cobalt compounds | Functional groups | Alkylation
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4. Full Text Reaction of Diazo Compounds with Organoboron Compounds
by Li, Huan and Zhang, Yan and Wang, Jianbo
Synthesis, ISSN 0039-7881, 11/2013, Volume 45, Issue 22, pp. 3090 - 3098
Abstract The transition-metal-free reactions of diazo compounds with organoboron compounds are reviewed. This type of reaction provides an alternative approach... 
short review | hydrazine | transition-metal-free reactions | diazo compounds | boron | 1,2-migration | ALPHA-DIAZOCARBONYL COMPOUNDS | ASYMMETRIC ALLYLBORATION | REGIOSPECIFIC SYNTHESIS | TOSYLHYDRAZONES | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ETHYL DIAZOACETATE | KETONES | METAL-CATALYZED REACTIONS | ESTERS | REACTIONS INVOLVING BORON | 2-migration
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5. Full Text Diazo Compounds and N‑Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions
by Xiao, Qing and Zhang, Yan and Wang, Jianbo
Accounts of Chemical Research, ISSN 0001-4842, 02/2013, Volume 46, Issue 2, pp. 236 - 247
Transition-metal-catalyzed carbene transformations and cross-couplings represent two major reaction types in organometallic chemistry and organic synthesis.... 
ALPHA-DIAZOCARBONYL COMPOUNDS | ROUTE | REAGENTS | BENZYL BROMIDES | MIGRATORY INSERTION | CARBENE INSERTION | TERMINAL ALKYNES | VINYL HALIDES | ARYL HALIDES SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | DIAZOESTERS | Palladium catalysts | Diazo compounds | Spin coupling | Palladium | Research | Chemical properties | Carbon-carbon composites | Synthesis (chemistry) | Cross coupling | Metalorganic compounds | Evolution | Transformations | Carbenes | Bonding
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6. Full Text Diastereoselective Three-Component Synthesis of β‑Amino Carbonyl Compounds Using Diazo Compounds, Boranes, and Acyl Imines under Catalyst-Free Conditions
by Luan, Yi and Yu, Jie and Zhang, Xiaowei and Schaus, Scott E and Wang, Ge
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2014, Volume 79, Issue 10, pp. 4694 - 4698
Diazo compounds, boranes, and acyl imines undergo a three-component Mannich condensation reaction under catalyst-free conditions to give the anti β-amino... 
BORONIC ACIDS | ALPHA-DIAZOCARBONYL COMPOUNDS | ASYMMETRIC ALLYLBORATION | REGIOSPECIFIC SYNTHESIS | CF3-SUBSTITUTED BORANES | CHIRAL BIPHENOLS | ESTERS | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE ADDITION | ETHYL DIAZOACETATE | MULTICOMPONENT REACTION | Azo Compounds - chemistry | Stereoisomerism | Boranes - chemistry | Imines - chemistry | Amino Acids - chemistry | Molecular Structure | Amino Acids - chemical synthesis | Catalysis | Diazo compounds | Borane | Chemical properties | Research | Note
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7. Full Text Homologation Reaction of Ketones with Diazo Compounds
by Candeias, Nuno R and Paterna, Roberta and Gois, Pedro M. P
Chemical Reviews, ISSN 0009-2665, 03/2016, Volume 116, Issue 5, pp. 2937 - 2981
This review covers the addition of diazo compounds to ketones to afford homologated ketones, either in the presence or in the absence of promoters or... 
ALPHA-DIAZOCARBONYL COMPOUNDS | HIGHLY ENANTIOSELECTIVE SYNTHESIS | CARBENE-TRANSFER REACTIONS | RING-EXPANSION REACTION | STEREOCONTROLLED TOTAL-SYNTHESIS | ASYMMETRIC ROSKAMP REACTION | IRON-CATALYZED CYCLOPROPANATION | ACENAPHTHENCHINON MIT DIAZOALKANEN | IN-SITU GENERATION | CHEMISTRY, MULTIDISCIPLINARY | H INSERTION REACTIONS | Heterocyclic Compounds - chemical synthesis | Chemistry Techniques, Synthetic | Hydrocarbons, Alicyclic - chemical synthesis | Diazonium Compounds - chemistry | Ketones - chemistry
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8. Full Text New Syntheses of Diazo Compounds
by Maas, Gerhard
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2009, Volume 48, Issue 44, pp. 8186 - 8195
Diazo compounds (R1R2CN2) are known as versatile and useful substrates for an array of chemical transformations and, therefore, diazo chemistry is still far... 
azides | diazo compounds | nitrogen groups | group transfer | synthetic methods | Azides | Diazo compounds | Synthetic methods | Nitrogen groups | Group transfer | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | FORMATION-INTRAMOLECULAR CYCLOADDITION | CHEMISTRY, MULTIDISCIPLINARY | ALDOL-TYPE REACTION | ETHYL DIAZOACETATE | DIASTEREOSELECTIVE SYNTHESIS | ASYMMETRIC CYCLOPROPANATION | SPIROCYCLIC AMMONIUM YLIDE | HETEROCYCLIC-COMPOUNDS
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9. Full Text When diazo compounds meet with organoboron compounds
by Wang, Jianbo
Pure and Applied Chemistry, ISSN 0033-4545, 03/2018, Volume 90, Issue 4, pp. 617 - 623
Transition-metal free reactions of diazo compounds with organoboron compounds provide some unique approaches for the formation of C–C, C–B and C–Si bonds. With... 
IMEBORON-16 | diazo compounds | organoboron compounds | C–B bond formation | transition-metal-free reaction | C-B bond formation | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | CF3-SUBSTITUTED BORANES | CARBENE MIGRATORY INSERTION | H BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | ETHYL DIAZOACETATE | N-TOSYLHYDRAZONES | CROSS-COUPLING REACTIONS | METAL CARBENE | Diazo compounds | Chemical reactions | Chemical properties | Observations | Carbon-carbon composites | Chemical bonds | Chemical synthesis | Organoboron compounds
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10. Full Text Fluorinated diazoalkanes – a versatile class of reagents for the synthesis of fluorinated compounds
by Mertens, Lucas and Koenigs, Rene M
Organic & Biomolecular Chemistry, ISSN 1477-0520, 2016, Volume 14, Issue 45, pp. 10547 - 10556
Although diazoalkanes find regular application in organic synthesis, the synthesis and application of their fluorinated homologues was long neglected. First... 
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11. Full Text Recent developments in copper-catalyzed reactions of diazo compounds
by Zhao, Xia and Zhang, Yan and Wang, Jianbo
Chemical Communications, ISSN 1359-7345, 9/2012, Volume 48, Issue 82, pp. 1162 - 1173
Copper-catalyzed reaction of diazo compounds generates copper carbene intermediates that undergo diverse transformations. In recent years, the selectivity and... 
ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | SULFUR YLIDES | HIGHLY ENANTIOSELECTIVE INSERTION | 3-COMPONENT REACTION | MEDIATED DIRECT ARYLATION | TERMINAL ALKYNES | CYCLOPROPANATION REACTIONS | CARBENOID INSERTION | CHEMISTRY, MULTIDISCIPLINARY | H INSERTION REACTIONS | Azo Compounds - chemistry | Organometallic Compounds - chemistry | Molecular Structure | Copper - chemistry | Catalysis | Organometallic Compounds - chemical synthesis
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12. Full Text Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1,1‐Difluoroolefins
by Zhang, Zhikun and Yu, Weizhi and Wu, Chenggui and Wang, Chengpeng and Zhang, Yan and Wang, Jianbo
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 1, pp. 273 - 277
A transition‐metal‐free difluoromethylenation of diazo compounds that proceeds under mild conditions has been developed and is based on the use of TMSCF2Br as... 
carbenes | diazo compounds | difluorocarbene | hydrazones | fluorine | CIS-ALKENES | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | FLUORINATED CYCLOPROPANES | CATALYZED REACTIONS | GEM-DIFLUOROOLEFINATION | IN-SITU GENERATION | STEREOSELECTIVE DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | ALKENE FORMATION | FISCHER CARBENE COMPLEXES | Diazo compounds | Fluorides | Dimerization | Electronic properties | Tetrabutylammonium bromide
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13. Full Text Fluorinated diazoalkanes - a versatile class of reagents for the synthesis of fluorinated compounds
by Mertens, Lucas and Koenigs, Rene M
Organic and Biomolecular Chemistry, ISSN 1477-0520, 11/2016, Volume 14, Issue 45, pp. 1547 - 1556
Although diazoalkanes find regular application in organic synthesis, the synthesis and application of their fluorinated homologues was long neglected. First... 
ALKYLBORON COMPOUNDS | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | DIASTEREOSELECTIVE SYNTHESIS | BUILDING-BLOCKS | INSERTION REACTIONS | CHEMISTRY, ORGANIC | ION CATALYZED HOMOLOGATION | DIAZOACETIC ESTERS | IN-SITU GENERATION | TRIFLUOROMETHYL DIAZOMETHANE
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14. Full Text Efficient One‐Pot Synthesis of Multi‐Substituted Dihydrofurans by Ruthenium(II)‐Catalyzed [3+2] Cycloaddition of Cyclic or Acyclic Diazodicarbonyl Compounds with Olefins
by Xia, Likai and Lee, Yong Rok
Advanced Synthesis & Catalysis, ISSN 1615-4150, 08/2013, Volume 355, Issue 11‐12, pp. 2361 - 2374
Ruthenium(II)‐phosphine complexes‐catalyzed [3+2] cycloadditions were conducted to synthesize a variety of dihydrofurans by reactions of cyclic or acyclic... 
ruthenium | cycloaddition | ionic liquids | diazo compounds | microwave chemistry | Ionic liquids | Diazo compounds | Cycloaddition | Microwave chemistry | Ruthenium | ALPHA-DIAZOCARBONYL COMPOUNDS | 1,3-DICARBONYL COMPOUNDS | MEDIATED DIPOLAR CYCLOADDITION | COPPER-CATALYZED REACTIONS | MODERN ORGANIC-SYNTHESIS | CHEMISTRY, ORGANIC | PROTECTED ENOL DIAZOACETATES | ACETATE PROMOTED ADDITIONS | CARBONYL YLIDE FORMATION | CHEMISTRY, APPLIED | MICROWAVE-ASSISTED SYNTHESIS | C-H INSERTION | Furans | Fluorides | Olefins | Reaction time | Synthesis | Catalysis | Chlorides
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