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Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 8/2016, Volume 113, Issue 32, pp. 8916 - 8920
Metallic nanoparticles with strong optically resonant properties behave as nanoscale optical antennas, and have recently shown extraordinary promise as... 
Catalysis|aluminum | Plasmon | Nanoparticle | Photocatalysis | 1ST-PRINCIPLES ANALYSIS | HYDROGENATION | ACETYLENE | MULTIDISCIPLINARY SCIENCES | nanoparticle | catalysis | aluminum | plasmon | H-2 | NANOANTENNAS | ALUMINUM NANOCRYSTALS | INDUCED DISSOCIATION | photocatalysis | METAL NANOPARTICLES | Physical Sciences
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 32, pp. 10304 - 10316
Polarized aluminum K-edge X-ray absorption near edge structure (XANES) spectroscopy and first-principles calculations were used to probe electronic structure... 
LOW-VALENT ALUMINUM | ORGANOALUMINUM | ACTIVATION | LIGANDS | LEWIS-ACID | MAIN-GROUP | CHEMISTRY | REACTIVITY | GROUP-13 METALS | SPECTRA | CHEMISTRY, MULTIDISCIPLINARY | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2015, Volume 54, Issue 23, pp. 6842 - 6846
The super acidity of the unsolvated Al(C6F5)3 enabled isolation of the elusive silane–alane complex [SiH⋅⋅⋅Al], which was structurally characterized by... 
Lewis acids | silanes | alanes | X‐ray diffraction | structure elucidation | X-ray diffraction | MECHANISM | OLEFIN POLYMERIZATION | IONS | BORANES | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | ALUMINUM | SIMPLE ACCESS | SILYLIUM | HYDROSILATION | B(C6F5)-CATALYZED HYDROSILYLATION | Silanes | Alanes | Structure elucidation | Catalysis | Spectroscopy | Diffraction | Alkenes | X-rays | Activation | Joining
Journal Article
Organometallics, ISSN 0276-7333, 06/2001, Volume 20, Issue 12, pp. 2533 - 2544
Several diorganoscandium complexes stabilized by the β-diketiminato ligands (Ar)NC(R)CHC(R)N(Ar) (Ar = 2,6-iPr-C6H3; R = CH3 (ligand a), R = tBu (ligand b))... 
ANSA-YTTROCENE | DIKETINIMATO LIGANDS | SCANDIUM | POLYMERIZATION CATALYSTS | CHEMISTRY, ORGANIC | METAL | PERMETHYLSCANDOCENE | CATIONIC ALUMINUM | DERIVATIVES | ALKYL COMPLEXES | M = TI | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2018, Volume 57, Issue 26, pp. 7815 - 7819
Formal nickelate(−I) complexes bearing Group 13 metalloligands (M=Al and Ga) were isolated. These 17 e− complexes were synthesized by one‐electron reduction of... 
nickel | metalates | Group 13 elements | radicals | EPR spectroscopy | OXIDATION | STATES | MAIN-GROUP | CHEMISTRY, MULTIDISCIPLINARY | ELEMENTS | ALKALI-METAL | TRANSITION-METAL | BONDS | COBALT | Spectroscopy | Gallium | Quantum chemistry | Aluminum | X-ray diffraction | Molecular orbitals | Molecular chains | Organic chemistry | Reduction | Computer applications | Chemical bonds | Nickel | Bonding
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 18, pp. 4956 - 4959
A general and operationally convenient method for intermolecular amination of C(sp3)−H bonds is described. This technology allows for efficient... 
reaction mechanisms | C−H oxidation | amination | sulfamates | rhodium | BOND AMINATION | NITRENE TRANSFER-REACTIONS | CATALYST | RH-2(ESP) | CHEMISTRY, MULTIDISCIPLINARY | CHALLENGES | FUNCTIONALIZATION | C-H oxidation | CARBOXYLATE | AZIRIDINATION | ASSIGNMENT | C-H AMINATION | Oxidation | Amination | Substrates | Molecular chains | Aluminum oxide
Journal Article
Journal Article
Macromolecules, ISSN 0024-9297, 12/2017, Volume 50, Issue 23, pp. 9188 - 9195
A series of iron­(III) chloride complexes based upon Schiff base framework have been synthesized and characterized by mass spectra, elemental analysis, and... 
RACEMIC LACTIDE | POLYMER SCIENCE | ALUMINUM COMPLEXES | LIGANDS | ALKOXIDE INITIATOR | POLY(LACTIC ACID) | RING-OPENING POLYMERIZATION | RAC-LACTIDE | CHAIN-END CONTROL | PROPYLENE-OXIDE | SELECTIVITY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2014, Volume 53, Issue 51, pp. 14132 - 14134
The synthesis of two four‐coordinate and square planar (SP) complexes of aluminum(III) is presented. Reaction of a phenyl‐substituted bis(imino)pyridine ligand... 
Lewis acids | N ligands | aluminum | square‐planar geometry | redox‐active ligands | Square-planar geometry | Redox-active ligands | Aluminum | CARBON | AMMONIA | IRON | BORANE | CHEMISTRY, MULTIDISCIPLINARY | square-planar geometry | FRUSTRATED LEWIS PAIR | REDUCTION | LIGANDS | redox-active ligands | CATALYSTS | Aluminum compounds | Pyridine | Pictures | Synthesis | Diethyl ether | Chlorides | Benzene | Ligands | Hydrides | Crystallography | Aluminum hydrides
Journal Article