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Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 22, pp. 6552 - 6557
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 35, pp. 10202 - 10205
A new class of Janus‐like ambiphilic ligands is introduced. The rigid diferrocene backbone in heterocycles 4‐SnP and 4... 
planar chirality | Lewis acids | ferrocenes | ambiphilic ligands | redox activity | ELECTRONIC-PROPERTIES | FREE HYDROGEN ACTIVATION | ACID | BEHAVIOR | COMPLEXES | COORDINATION | FRUSTRATED LEWIS PAIRS | BORANE | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINE-LIGANDS | CHEMISTRY | Ligands | Backbone | Lewis acid | Binding | Anions | Images | Boranes | Fluorides
Journal Article
Journal Article
Canadian Journal of Chemistry, ISSN 0008-4042, 2018, Volume 96, Issue 5, pp. 484 - 491
...) with NaBH 4 yielded square planar [Rh(μ-H)(CO)(TXPB)] ( 2 ) in which the hydride ligand bridges between rhodium and the borane unit of TXPB. The Rh–H, Rh–B, and Rh... 
nickel | bridging ligands | ambiphilic ligands | pendant boranes | ligands pontants | ligands amphiphiles | boranes appendiculaires | rhodium | Nickel | Rhodium | Bridging ligands | Pendant boranes | Ambiphilic ligands | ACTIVATION | HYDROGENATION | UNIT | H BOND | APPROXIMATION | HYDRIDE MIGRATION | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | PLATINUM COMPLEXES | SCORPION
Journal Article
Beilstein journal of organic chemistry, ISSN 1860-5397, 2012, Volume 8, Issue 1, pp. 1554 - 1563
.... Here we propose that such a description is consistent with the behavior of many coordinatively unsaturated transition-metal species featuring metal-ligand multiple bonds, and we further demonstrate that the resultant reactivity may be a powerful tool for the functionalization of C-H and E-H bonds. 
Metal carbene | C-H activation | C-H functionalization | Frustrated Lewis pair | Ambiphilic reactivity | Multiple bond | IMIDO COMPLEXES | FREE HYDROGEN ACTIVATION | CARBON BONDS | SMALL-MOLECULE ACTIVATION | CHEMISTRY, ORGANIC | metal carbene | TERMINAL BORYLENE COMPLEXES | ambiphilic reactivity | multiple bond | ALKYLIDENE COMPLEXES | RUTHENIUM SILYLENE | IRIDIUM COMPLEXES | frustrated Lewis pair | TRAPPING REACTIONS | ALKYNE CROSS-METATHESIS | C–H activation | C–H functionalization
Journal Article
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 22, pp. 6148 - 6151
...–borane compound works as the effective ligand for palladium-catalyzed direct allylic amination of allylic alcohol... 
COORDINATION CHEMISTRY | COUPLING REACTIONS | CARBON-MONOXIDE | ACTIVE METHYLENE-COMPOUNDS | CHEMISTRY, ORGANIC | AMBIPHILIC LIGANDS | SELECTIVE SYNTHESIS | CHIRAL PHOSPHORIC-ACID | ALIPHATIC-ALDEHYDES | DUAL CATALYSIS | AMPHIPHILIC ALLYLATION
Journal Article