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chemistry, organic (98) 98
chemistry, multidisciplinary (54) 54
index medicus (39) 39
bioactive macrolides (38) 38
amphidinolides (32) 32
macrolides - chemistry (31) 31
stereoselective-synthesis (31) 31
molecular structure (30) 30
dinoflagellate (28) 28
macrolides (28) 28
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macrolide (24) 24
enantioselective synthesis (21) 21
aldehydes (19) 19
animals (18) 18
ring-closing metathesis (18) 18
dinoflagellida - chemistry (17) 17
stereochemistry (17) 17
fragment (16) 16
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natural products (16) 16
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total synthesis (16) 16
absolute stereochemistry (15) 15
amphidinium sp (15) 15
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synthesis (15) 15
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letter (14) 14
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cytotoxic agents amphidinolides (13) 13
organic-synthesis (13) 13
amphidinolide (12) 12
amphidinolide-a (12) 12
amphidinolide-x (12) 12
organic compounds (12) 12
19-membered macrolide (11) 11
alcohols (11) 11
chemistry, medicinal (11) 11
macrolides - isolation & purification (11) 11
magnetic resonance spectroscopy (11) 11
moiety (10) 10
amphidinolide b (9) 9
caribenolide-i structures (9) 9
cross-coupling reactions (9) 9
humans (9) 9
marine dinoflagellate (9) 9
pharmacology & pharmacy (9) 9
segment (9) 9
-amphidinolide-a (8) 8
amphidinolide-h (8) 8
cytotoxic (8) 8
cytotoxic macrolide (8) 8
enantioselective total-synthesis (8) 8
lactones - chemistry (8) 8
stereoselective synthesis (8) 8
26-membered macrolide (7) 7
aldol reaction (7) 7
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antineoplastic agents - chemical synthesis (7) 7
article (7) 7
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bridged bicyclo compounds, heterocyclic - chemical synthesis (7) 7
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ketones (7) 7
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cell line, tumor (6) 6
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esters (6) 6
furans - chemistry (6) 6
lactones - chemical synthesis (6) 6
macrolide antibiotics (6) 6
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ruthenium (6) 6
stille coupling (6) 6
top-half (6) 6
alkenes (5) 5
alkynes (5) 5
amphidinium (5) 5
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anticancer agents (5) 5
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The Journal of Organic Chemistry, ISSN 0022-3263, 08/2018, Volume 83, Issue 15, pp. 7694 - 7713
A straightforward protocol integrating a sustainable approach for the synthesis of new 2,5-trans-THF nitrile derivatives enabling an easy diversification of... 
ACTIVATION | ENERGY | AMPHIDINOLIDES | TETRAHYDROFURANS | APPROXIMATION | CHEMISTRY, ORGANIC | OXIDATIVE CYCLIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 03/2014, Volume 16, Issue 6, pp. 1660 - 1663
Rhodium­(II) acetate catalyzes the denitrogenative transformation of 5-substituted and 4,5-disubstituted 1-sulfonyl-1,2,3-triazoles with pendent allyl and... 
AZAVINYL CARBENES | REARRANGEMENT | SULFONYL AZIDES | CATALYZED TRANSANNULATION | NATURAL-PRODUCTS | AMPHIDINOLIDES C | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | INTRAMOLECULAR GENERATION | OXONIUM YLIDES
Journal Article
Journal of Natural Products, ISSN 0163-3864, 03/2007, Volume 70, Issue 3, pp. 451 - 460
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2016, Volume 57, Issue 30, pp. 3334 - 3338
Aryl -disubstituted conjugated alkenols underwent oxidative cyclization affording 2,5,5-trisubstituted tetrahydrofurans in reasonable yields and good... 
2,5,5-Trisubstituted tetrahydrofuran | Metal catalysis | Mukaiyama oxidative cyclization | CONCISE | AMPHIDINOLIDES | CHEMISTRY, ORGANIC | STEREOSELECTIVE TOTAL-SYNTHESIS | MACROLIDES | Enols
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 11/2008, Volume 41, Issue 11, pp. 1500 - 1511
Transition metal catalysts, particularly those derived from the group VIII−X metals, display remarkable efficiency for the formation of carbon−carbon and... 
MECHANISTIC ASPECTS | ARYL GRIGNARD-REAGENTS | ALKENYL HALIDES | NITROGEN NUCLEOPHILES | COMPLEXES | EFFICIENT SYNTHESIS | AMPHIDINOLIDE-X | ORGANIC HALIDES | BETA-HYDROGENS | SECONDARY ALKYL-HALIDES | CHEMISTRY, MULTIDISCIPLINARY | Iron | Catalysis | Chemical properties | Ketones | Analysis | Acylation
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2013, Volume 69, Issue 15, pp. 3192 - 3196
Journal Article
Heterocycles, ISSN 0385-5414, 2013, Volume 87, Issue 12, pp. 2615 - 2623
Two new macrolides, iriomoteolides-4a (1) and -5a (2), have been isolated from a marine benthic dinoflagellate Amphidinium sp. (strain HYA024), and the... 
20-MEMBERED MACROLIDE | AMPHIDINOLIDES | Dinoflagellate | CHEMISTRY, ORGANIC | Cytotoxicity | BIOACTIVE MACROLIDES | Macrolide
Journal Article
Tetrahedron, ISSN 0040-4020, 03/2018, Volume 74, Issue 13, pp. 1546 - 1554
The C18–C26 fragment of amphidinolide C congeners has been synthesized starting from methyl acetoacetate in 14 steps in >17.0% overall yield. The C20... 
Tetrahydrofuran | Asymmetric dihydroxylation | Amphidinolide C | Enyne | Intramolecular SN2 reaction | Sonogashira cross-coupling | Intramolecular S | 2 reaction
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 08/2019, Volume 84, Issue 15, pp. 9584 - 9602
Two stereoselective routes to the C7-C22 subunit of amphidinolide K are disclosed. Jacobsen's hydrolytic kinetic resolution and Sharpless' asymmetric... 
ALCOHOLS | MECHANISM | ALLYLIC SULFOXIDES | MACROLIDE | ALLYLATION | CHEMISTRY, ORGANIC | FORMAL TOTAL-SYNTHESIS | AMPHIDINOLIDE-H | ALDEHYDES | RELAY CYCLIZATIONS | EFFICIENT
Journal Article
Heterocycles, ISSN 0385-5414, 2015, Volume 91, Issue 2, pp. 265 - 274
The first 23-membered macrolide, iriomoteolide-2a (1), was isolated from cultivated algal cells of a marine benthic dinoflagellate Amphidinium species. The... 
Amphidinium | NMR | AMPHIDINOLIDES | NATURAL-PRODUCTS | Marine Dinoflagellate | CONFIGURATION | CHEMISTRY, ORGANIC | Macrolide | Cytotoxic Acitivity
Journal Article
Chemical and Pharmaceutical Bulletin, ISSN 0009-2363, 2016, Volume 64, Issue 7, pp. 979 - 981
The biogenetic origins of amphidinin A (1) and amphidinolide P (2) were investigated by feeding experiments with 13C-labeled acetates. 13C-NMR data of... 
Journal Article
Organic Letters, ISSN 1523-7060, 07/2018, Volume 20, Issue 13, pp. 3810 - 3814
A chiral phosphoric acid catalyzed allenylboration reaction is reported. Homopropargyl alcohols with an internal alkyne unit were obtained in good yields with... 
CARBON BOND FORMATION | MACBECIN-I | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTION | PROPARGYLATION | PRACTICAL REAGENT | CHEMISTRY, ORGANIC | AMPHIDINOLIDE-X | TRANSFER HYDROGENATION | ALDEHYDES | STEREOSELECTIVE-SYNTHESIS
Journal Article
Helvetica Chimica Acta, ISSN 0018-019X, 07/2019, Volume 102, Issue 7, p. n/a
Journal Article
by Bi, HP and Chen, WW and Liang, YM and Li, CJ
ORGANIC LETTERS, ISSN 1523-7060, 08/2009, Volume 11, Issue 15, pp. 3246 - 3249
A novel iron-catalyzed intermolecular decarboxylative Csp(3)-Csp(2) coupling reaction using proline derivatives as starting materials is developed. In this... 
ARYL GRIGNARD-REAGENTS | ORGANIC-SYNTHESIS | OXIDATIVE DECARBOXYLATION | NITROGEN ATOM | CHEMISTRY, ORGANIC | ALPHA-AMINO-ACIDS | AMPHIDINOLIDE-X | REARRANGEMENT REACTIONS | C-H BONDS | BEARING BETA-HYDROGENS | ALKYL-HALIDES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 11/2016, Volume 57, Issue 47, pp. 5240 - 5242
An enantio- and diastereoselective synthesis of the C17–C29 fragment of amphidinolide N, an extremely potent macrocyclic cytotoxin of marine origin, has been... 
Polyketide | Amphidinolide | Cytotoxic | Macrolide | Partial synthesis | 7,10-EPIMER | CARIBENOLIDE-I STRUCTURES | DINOFLAGELLATE | CHEMISTRY, ORGANIC | PROPOSED STRUCTURE | SUBUNIT
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2018, Volume 59, Issue 51, pp. 4496 - 4499
A new 12-membered macrolide, symbiodinolactone A, was isolated from the culture broth of symbiotic marine dinoflagellate sp. The gross structure of... 
Symbiodinium sp | Symbiotic | Symbiodinolactone A | Macrolide | Dinoflagellate | ZOOXANTHELLATOXIN-A | STEREOCHEMISTRY | CONFIGURATION | CHEMISTRY, ORGANIC | POLYOL | COUPLING-CONSTANTS | AMPHIDINOLIDE Q | BIOACTIVE MACROLIDES | LACTONE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2007, Volume 46, Issue 48, pp. 9265 - 9270
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 41, pp. 13575 - 13581
Journal Article
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