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chemistry, multidisciplinary (7) 7
anionic dimetalloborylene complex (6) 6
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Angewandte Chemie International Edition, ISSN 1433-7851, 08/2014, Volume 53, Issue 35, pp. 9280 - 9283
...], which gave the corresponding conjugate acid and a chromium–borylene complex, respectively. Two oxazol‐2‐ylidene ligands effectively stabilize a phenylborylene fragment that features a lone pair of electrons on the boron atom... 
borylenes | carbenes | reactive species | boron | nucleophiles | FORM | DIBORENES | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | BULKY | TRANSITION-METAL BORYL | CHEMISTRY | ALKYL AMINO CARBENES | GENERATION | Chemical tests and reagents | Chromium | Boron | Conjugates | Computation | Ligands | Nucleophiles | Adducts | Fragmentation
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 05/2017, Volume 56, Issue 10, pp. 5586 - 5593
...) complexes toward main-group substrates have been systematically examined, which led to the construction of B–E (E = C, Ga, Cl, H, F, N) bonds... 
DICATION | SINGLE | SPONTANEOUS HALIDE EJECTION | TRANSITION-METAL | CENTERED NUCLEOPHILE | REACTIVITY | FRUSTRATED LEWIS PAIRS | METAL BORYL COMPLEXES | CHEMISTRY SYNTHESIS | ANIONIC DIMETALLOBORYLENE COMPLEX | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 1, pp. 436 - 440
An electron‐rich monovalent boron compound is used as a Lewis base to prepare adducts with Group 13 Lewis acids using both its boron and nitrogen sites. The... 
Lewis adducts | alanes | gallanes | boron | dative bonding | ELECTRON PI-BOND | DIBORENES | REACTIVITY | ANIONIC DIMETALLOBORYLENE COMPLEX | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | BORYL ANION | REDUCTION | RICH COORDINATION ENVIRONMENT | MULTIPLE BONDS | RADICAL-ANION | Nitrogen
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2015, Volume 51, Issue 47, pp. 9594 - 9607
Despite the widespread use of organoborane reagents in organic synthesis and catalysis, a major challenge still remains: very few boron-centered nucleophiles... 
BRIDGING GUANIDINATE LIGANDS | LEWIS-BASE ADDUCTS | SOLID-STATE NMR | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | COPPER(I) BORYL COMPLEXES | N-HETEROCYCLIC CARBENES | ALKOXY DIBORON REAGENTS | ANIONIC DIMETALLOBORYLENE COMPLEX | CATALYZED BETA-BORATION | METAL-FREE DIBORATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications, ISSN 1359-7345, 06/2014, Volume 50, Issue 43, pp. 5729 - 5732
The reaction of phenylmercuric chloride with an anionic dimanganese borylene (Li+[Cp-2(CO) 4Mn2B](-)) led to the formation of a trimetalloboride featuring the... 
TRANSITION-METAL-COMPLEXES | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURE | AB-INITIO | 2-ELECTRON VALENCE INDEXES | OXIDATION-STATE IV | CHEMICAL VALENCE | ANIONIC DIMETALLOBORYLENE COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | BORYLENE COMPLEXES | NATURAL ORBITALS | Synthesis | Mathematical analysis | Chlorides | Chemical bonds | Scalars | Joining | Bonding | Mercury (metal)
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 95, pp. 12734 - 12737
The addition of phenyl lithium (PhLi) to an aromatic 1,3,2,5-diazadiborinine (1) afforded isolable ionic species 2, which can be deemed as an inorganic analogue of a Janovsky complex... 
DIMETALLOBORYLENE COMPLEX | MEISENHEIMER COMPLEXES | HYDROGEN | BORYL ANION | REDUCTION | STRUCTURAL CHEMISTRY | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | AROMATIC-SUBSTITUTION REACTIONS | ANIONIC SIGMA-COMPLEXES | Gold | Lithium | Boron | Diffraction
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2017, Volume 53, Issue 95, pp. 12734 - 12737
The addition of phenyl lithium (PhLi) to an aromatic 1,3,2,5-diazadiborinine (1) afforded isolable ionic species 2, which can be deemed as an inorganic analogue of a Janovsky complex... 
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2018, Volume 54, Issue 65, pp. 9015 - 9018
A carbene-stabilised neutral boryl radical and a boryl anion are isolated via selective one- and two-electron reduction of a diamidocarbene (DAC) adduct of... 
BORYL ANION | TRIARYLBORON ANIONS | BORON-STABILIZED CARBANION | TRIMESITYLBORON | REACTIVITY | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANE | 1,3,2,5-DIAZADIBORININE | RADICAL-ANION | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
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