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anionic dimetalloborylene complex (5) 5
chemistry, multidisciplinary (5) 5
reactivity (4) 4
boron (2) 2
boryl anion (2) 2
boryllithium (2) 2
1,3,2,5-diazadiborinine (1) 1
2-electron valence indexes (1) 1
ab-initio (1) 1
adducts (1) 1
alkoxy diboron reagents (1) 1
alkyl amino carbenes (1) 1
alpha,beta-unsaturated carbonyl-compounds (1) 1
anionic sigma-complexes (1) 1
aromatic-substitution reactions (1) 1
bonding (1) 1
bor (1) 1
borane (1) 1
boranes (1) 1
boron-stabilized carbanion (1) 1
borylene complexes (1) 1
borylenes (1) 1
bridging guanidinate ligands (1) 1
bulky (1) 1
carben (1) 1
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centered nucleophile (1) 1
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chemistry, inorganic & nuclear (1) 1
chlorides (1) 1
chromium (1) 1
chromium-complex (1) 1
chromkomplex (1) 1
computation (1) 1
conjugates (1) 1
copper boryl complexes (1) 1
crystal-structure (1) 1
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dimetalloborylene complex (1) 1
electrons (1) 1
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lithium (1) 1
mathematical analysis (1) 1
meisenheimer complexes (1) 1
mercury (1) 1
metal boryl complexes (1) 1
metal-free diboration (1) 1
molecular-structure (1) 1
n-heterocyclic carbenes (1) 1
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ray crystal-structure (1) 1
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structural chemistry (1) 1
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transition-metal (1) 1
transition-metal boryl (1) 1
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triarylboron anions (1) 1
trimesitylboron (1) 1
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Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 35, pp. 9280 - 9283
...], which gave the corresponding conjugate acid and a chromium–borylene complex, respectively. Two oxazol‐2‐ylidene ligands effectively stabilize a phenylborylene fragment that features a lone pair of electrons on the boron atom... 
borylenes | carbenes | reactive species | boron | nucleophiles | FORM | DIBORENES | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | BULKY | TRANSITION-METAL BORYL | CHEMISTRY | ALKYL AMINO CARBENES | GENERATION | Chemical tests and reagents | Chromium | Boron | Conjugates | Computation | Ligands | Nucleophiles | Adducts | Fragmentation
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2015, Volume 51, Issue 47, pp. 9594 - 9607
Despite the widespread use of organoborane reagents in organic synthesis and catalysis, a major challenge still remains: very few boron-centered nucleophiles... 
BRIDGING GUANIDINATE LIGANDS | LEWIS-BASE ADDUCTS | SOLID-STATE NMR | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | COPPER(I) BORYL COMPLEXES | N-HETEROCYCLIC CARBENES | ALKOXY DIBORON REAGENTS | ANIONIC DIMETALLOBORYLENE COMPLEX | CATALYZED BETA-BORATION | METAL-FREE DIBORATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2017, Volume 53, Issue 95, pp. 12734 - 12737
The addition of phenyl lithium (PhLi) to an aromatic 1,3,2,5-diazadiborinine ( afforded isolable ionic species , which can be deemed as an inorganic analogue of a Janovsky complex... 
DIMETALLOBORYLENE COMPLEX | MEISENHEIMER COMPLEXES | HYDROGEN | BORYL ANION | REDUCTION | STRUCTURAL CHEMISTRY | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | AROMATIC-SUBSTITUTION REACTIONS | ANIONIC SIGMA-COMPLEXES | Gold | Lithium | Boron | Diffraction
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 05/2017, Volume 56, Issue 10, pp. 5586 - 5593
...) complexes toward main-group substrates have been systematically examined, which led to the construction of B–E (E = C, Ga, Cl, H, F, N) bonds... 
DICATION | SINGLE | SPONTANEOUS HALIDE EJECTION | TRANSITION-METAL | CENTERED NUCLEOPHILE | REACTIVITY | FRUSTRATED LEWIS PAIRS | METAL BORYL COMPLEXES | CHEMISTRY SYNTHESIS | ANIONIC DIMETALLOBORYLENE COMPLEX | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2018, Volume 54, Issue 65, pp. 9015 - 9018
A carbene-stabilised neutral boryl radical and a boryl anion are isolated via selective one- and two-electron reduction of a diamidocarbene (DAC) adduct of... 
BORYL ANION | TRIARYLBORON ANIONS | BORON-STABILIZED CARBANION | TRIMESITYLBORON | REACTIVITY | ANIONIC DIMETALLOBORYLENE COMPLEX | BORANE | 1,3,2,5-DIAZADIBORININE | RADICAL-ANION | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2014, Volume 50, Issue 43, pp. 5729 - 5732
The reaction of phenylmercuric chloride with an anionic dimanganese borylene (Li+[Cp-2(CO) 4Mn2B](-)) led to the formation of a trimetalloboride featuring the... 
TRANSITION-METAL-COMPLEXES | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURE | AB-INITIO | 2-ELECTRON VALENCE INDEXES | OXIDATION-STATE IV | CHEMICAL VALENCE | ANIONIC DIMETALLOBORYLENE COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | BORYLENE COMPLEXES | NATURAL ORBITALS | Synthesis | Mathematical analysis | Chlorides | Chemical bonds | Scalars | Joining | Bonding | Mercury (metal)
Journal Article
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