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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2014, Volume 53, Issue 1, pp. 260 - 264
A novel approach to produce diaryl sulfoxides from aryl benzyl sulfoxides is reported. Optimization of the reaction conditions was performed using... 
palladium | homogeneous catalysis | cross‐coupling | SO compounds | synthetic methods | cross-coupling | S-O compounds | Sulfoxides - chemistry | Molecular Structure | Catalysis | Palladium - chemistry | Bromides - chemistry | Palladium catalysts | Palladium | Organosulfur compounds | Relay | Catalysts | Aromatic compounds | Bromides | Byproducts | Cleavage | Bonding | Optimization
Journal Article
Journal of Chemical Sciences, ISSN 0974-3626, 7/2019, Volume 131, Issue 7, pp. 1 - 6
The chiral metal complex produced in situ from (R)-6,6$$^{\prime }$$ ′ -Diphenyl-BINOL and $$\mathrm{Ti}(\mathrm{O}-{} { i}-\mathrm{Pr})_{4}$$ Ti(O-i-Pr)4 as a... 
Chemistry | enantiopure sulfoxides | ( R )-6,6 $$^{\prime }$$ ′ -Diphenyl-BINOL | chiral ligand | Chemistry/Food Science, general | BINOL | COMPLEXES | (R)-6,6 '-Diphenyl-BINOL | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION | Sulfides | Oxidation-reduction reaction | Chemical tests and reagents | Enantiomers | Organosulfur compounds
Journal Article
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 18, pp. 5129 - 5133
The first example of PdII‐catalyzed enantioselective C−H olefination with non‐chiral or racemic sulfoxides as directing groups was developed. A variety of... 
palladium | desymmetrization | C−H activation | parallel kinetic resolution | sulfoxide | ACID | AROMATIC SULFOXIDES | SULFENATE ANIONS | ARYLATION | CHIRAL AUXILIARY | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC OXIDATION | C(SP)-H BOND ACTIVATION | C-H activation | LIGANDS | COUPLING REACTIONS | REGIODIVERGENT | Enantiomers | Palladium | Organosulfur compounds | Sulfoxides | Sulfur
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 06/2015, Volume 357, Issue 9, pp. 2011 - 2016
Journal Article
Dalton Transactions, ISSN 1477-9226, 03/2015, Volume 44, Issue 12, pp. 5323 - 5330
Reactions of alkyl aryl sulfoxides H-CRR'S(O) Ar with n-BuLi-TMEDA (TMEDA = N,N,N',N'-tetramethylethylenediamine) afforded alpha-sulfinyl functionalized alkyl... 
ASYMMETRIC-SYNTHESIS | ACIDITIES | BENZYL METHYL SULFOXIDE | CRYSTAL-STRUCTURE | STEREOCHEMISTRY | CARBONYL-COMPOUNDS | SULFONES | CHIRAL 2-(TRIALKYLSILYL)ETHYL SULFOXIDES | LITHIUM | SULFUR-STABILIZED CARBANIONS | CHEMISTRY, INORGANIC & NUCLEAR | Diffraction | Aromatic compounds | X-rays | Benzaldehyde | Crystals | NMR spectroscopy | Enantiomers | Lithium compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 44, pp. 14582 - 14585
We have developed metal-free regiocontrolled dehydrogenative C–H/C–H cross-coupling of aryl sulfoxides with phenols by means of trifluoroacetic anhydride.... 
CARBON BOND FORMATION | FUNCTIONALIZATION | PUMMERER REACTION | DIRECT ARYLATION | STRATEGY | VERSATILE CHIRAL REAGENT | AROMATIC-COMPOUNDS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | CLAISEN REARRANGEMENT SEQUENCE | ORTHO-PROPARGYLATION | Chemical bonds | Phenols | Sulfur compounds | Chemical properties | Metal ions
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 33, pp. 9571 - 9575
The enantioselective synthesis of isochroman motifs has been accomplished by palladium(II)‐catalyzed allylic C−H oxidation from terminal olefin precursors.... 
oxidation | palladium | asymmetric catalysis | C−H activation | S ligands | S ligands | ACTIVATION | ALKYLATION | ALLYLATION | INDOLINES | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | AMINATION | C-H activation | INHIBITION | HETEROCYCLES | LIGAND | METATHESIS | Oxidation-reduction reaction | Palladium | Chemical properties | Catalysis | Enantiomers | Olefins | Oxidation | Alkenes | Aromatic compounds | Sulfoxides | Chemical synthesis
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2018, Volume 2018, Issue 20-21, pp. 2518 - 2530
Diethylzinc was treated with 1 or 2 equiv. of AlkMgCl or PhMgBr (preferably) or with 1 equiv. of nBuLi (less efficiently) for forming species – plausibly... 
Enantioselectivity | Sulfinylation | Desymmetrization | Ephedrine | Sulfoxides | Organozincates | Exchange interactions | ORGANIC-SYNTHESIS | DIALKYLZINCS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALDEHYDES | ENANTIOPURE SULFOXIDES | ORGANOZINC REAGENTS | ORGANOMETALLIC REAGENTS | HIGHLY ENANTIOSELECTIVE ADDITION | CHEMISTRY | Organosulfur compounds
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2019, Volume 361, Issue 5, pp. 1084 - 1091
An unusual I2‐mediated triple C(sp3)−H functionalization reaction between aryl methyl ketones and dimethyl sulfoxide to form polysubstituted furans has been... 
dual synthon | 2,4,5-trisubstituted furans | ketones | DMSO | C(sp3)−H functionalization | H functionalization | C(sp | OXIDATION | ANNULATION | STRATEGY | SULFONYLATION | CHEMISTRY, ORGANIC | ALKENES | FACILE SYNTHESIS | C(sp)-H functionalization | CONSTRUCTION | CHEMISTRY, APPLIED | DERIVATIVES | Ketones | Furans | Dimethyl sulfoxide | Sulfoxides | Aromatic compounds | Iodine
Journal Article