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Angewandte Chemie International Edition, ISSN 1433-7851, 11/2012, Volume 51, Issue 48, pp. 12090 - 12094
Owing to their unique properties, molecules containing the difluoromethyl group (CF2H) are of great interest. Tributyl(difluoromethyl)stannane has now been... 
stannanes | density functional calculations | copper | difluoromethylation | CC coupling | C-C coupling | SULFIDES | FLUOROALKYLATION | CARBONYL-COMPOUNDS | SULFONES | FLUORINATION | CHEMISTRY, MULTIDISCIPLINARY | SULFOXIDES | ARYL | BOND | DERIVATIVES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2013, Volume 135, Issue 12, pp. 4648 - 4651
This communication describes a mild copper-mediated fluorination of aryl stannanes and aryl trifluoroborates with N-fluoro-2,4,6-trimethylpyridinium triflate.... 
PALLADIUM | CATALYSIS | ACIDS | FUNCTIONALIZED ARYL | FORMING REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | PET | Copper - chemistry | Tin Compounds - chemistry | Borates - chemistry | Pyridinium Compounds - chemistry | Halogenation | Chemical reaction, Rate of | Analysis | Methyl groups | Copper compounds | Chemical properties | Structure | Fluorination
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 13, pp. 3147 - 3155
Journal Article
Helvetica Chimica Acta, ISSN 0018-019X, 11/2012, Volume 95, Issue 11, pp. 2231 - 2236
(Trifluoromethyl)stannane reagents such as Bu3SnCF3 are effective in CuI‐mediated trifluoromethylation reactions of aryl iodides. The reactions proceed via the... 
Trifluoromethylation | Stannane, tributyl(trifluoromethyl) | Aryl iodides | tributyl(trifluoromethyl) | Stannane | ASYMMETRIC FLUORINATION | COMPLEXES | ARENES | COPPER | REDUCTIVE ELIMINATION | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | IODIDES | ARYL | RADICALS | BOND-FORMATION | Communication
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2018, Volume 57, Issue 46, pp. 15081 - 15085
The transmetalation is a key elementary step in cross-coupling reactions. Yet, the precise nature of its mechanism and transition state geometry are frequently... 
COMPLEXES | silanes | stannanes | FORMING REDUCTIVE ELIMINATION | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | reaction mechanism | COMPUTATIONAL CHARACTERIZATION | FLUORINE | trifluoromethylation | ARYL | STILLE REACTION | transmetalation | TRANSMETALATION STEP | BOND-FORMATION
Journal Article
Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 2, pp. 385 - 388
An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common... 
ORGANOZINC REAGENTS | AZOLES | O BOND ACTIVATION | MEDIATED FLUORINATION | C-O | NICKEL | ALPHA-ARYLATION | ARYL ESTERS | STANNYLATION | CHEMISTRY, ORGANIC | PHENOL DERIVATIVES
Journal Article
Synlett, ISSN 0936-5214, 02/2011, Volume 2011, Issue 3, pp. 345 - 348
Abstract Aryl stannanes are easily accessible from O-silylated aryl triflates in the presence of KF and Bu 3 SnH. The corresponding arynes are formed in situ,... 
letter | hydrostannation | arynes | Stille coupling | aryl stannanes | one-pot reaction | ORGANIC-SYNTHESIS | CHEMISTRY, ORGANIC | PALLADIUM-CATALYZED REACTION | REGIOSELECTIVE HYDROSTANNATIONS | ARYLSTANNANES | EFFICIENT CATALYST | ARYLTRIBUTYLTIN | AMINO-ACIDS | DISTANNYLATION | HEXABUTYLDITIN | ELECTROPHILES
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2014, Volume 751, pp. 201 - 212
The S 1 reactions of trimethylstannyl and triphenylstannyl anions, and other tin nucleophiles with haloarenes are quite versatile. Thus, the S 1 mechanism can... 
Vinylstannanes | Triarylphosphines | Stille | SRN1 | Triarylarsines | Stannanes | PALLADIUM | S(RN)1 | CHEMISTRY, ORGANIC | TRIMETHYLSTANNYL ANIONS | BOND FORMATION | LIQUID-AMMONIA | CHEMISTRY, INORGANIC & NUCLEAR | ARYLSTANNANES | CROSS-COUPLING REACTIONS | ARYL HALIDES | CATALYZED AMINATION | S(RN)1 MECHANISM | PHOTOSTIMULATED REACTIONS | Tin compounds | Aromatic compounds
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 2005, Volume 126, Issue 5, pp. 797 - 801
A Barbier-type reaction of fluorinated alkyl, aryl or vinyl halides with tri- -butylstannane mediated by zinc to yield the corresponding stannanes is... 
Tri- n-butyltin chloride | 119Sn NMR spectra | Aryl and alkyl stannanes | Fluorinated vinyl | Barbier reactions | Nitrites
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2009, Volume 694, Issue 21, pp. 3425 - 3430
The Pd-catalyzed cross-coupling reaction of organoheteroatom stannanes containing elements of the groups 15 (P, As) and 16 (Se) with perfluoroalkyl iodides (R... 
Perfluoroalkylphosphines | Organoheteroatom stannanes | Perfluoroalkylarsines | Pd-catalyzed reactions | NUCLEOPHILIC TRIFLUOROMETHYLATION | COORDINATION CHEMISTRY | PALLADIUM | GROUP-6A 15 | COMPLEXES | CHEMISTRY, ORGANIC | ALKYL-HALIDES | CHEMISTRY, INORGANIC & NUCLEAR | LIGANDS | ARYL HALIDES | HOMOGENEOUS CATALYSIS | STILLE REACTION
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 6/2007, Volume 40, Issue 6, pp. 453 - 463
Journal Article
Organometallics, ISSN 0276-7333, 02/2009, Volume 28, Issue 3, pp. 933 - 936
We have studied the Pd-catalyzed cross-coupling reaction of organoheteroatom stannanes containing elements of groups 15 (P, As, Sb) and 16 (Se) with 1-naphthyl... 
IODIDES | DIENE SYSTEMS | MECHANISM | ARYL HALIDES | COMPLEXES | AMINOSTANNANES | CHEMISTRY, ORGANIC | ORGANOSTANNANES | OXIDATIVE ADDITION | BOND | STILLE REACTION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 05/2005, Volume 126, Issue 5, pp. 797 - 801
Fluorinated stannanes are valuable synthons in synthetic organofluorine chemistry. Fluorinated vinyl, alkyl and aryl halides reacted efficiently with... 
Tri-n-butyltin chloride | Aryl and alkyl stannanes | Barbier reactions | Fluorinated vinyl | Sn NMR spectra | tri-n-butyltin chloride | PERFLUOROALKYL | Sn-119 NMR spectra | REAGENTS | CHEMISTRY, ORGANIC | METAL | fluorinated vinyl | aryl and alkyl stannanes | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2009, Volume 48, Issue 34, pp. 6201 - 6204
On course for a C1 source: Highly functionalized carboxylic acids can be conveniently prepared from the carboxylation of organometallic reagents using carbon... 
carboxylation | carbon dioxide | sustainable chemistry | homogeneous catalysis | organometallics | Carboxylation | Organometallics | Sustainable chemistry | Homogeneous catalysis | Carbon dioxide | INSERTION | COMPLEX | CROSS-COUPLING REACTION | ACIDS | CO2 | CHEMISTRY, MULTIDISCIPLINARY | ZINC | 1-ALKENYL HALIDES | ALLYL STANNANES | ALKENYLBORONIC ESTERS | ARYL CHLORIDES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2004, Volume 45, Issue 41, pp. 7573 - 7576
Tributyl(3,3,3-trifluoro-1-propynyl)stannane was readily synthesized from 2-bromo-3,3,3-trifluoropropene in one step. The 1,3-dipolar cycloaddition of the... 
1,3-Dipolar cycloaddition | Triazole | Stannyl acetylene | Cross-coupling reaction | Isoxazole | Pyrazole | Trifluoromethyl compounds | ALCOHOLS | stannyl acetylene | cross-coupling reaction | CROSS-COUPLING REACTIONS | trifluoromethyl compounds | ARYL HALIDES | pyrazole | CHEMISTRY, ORGANIC | isoxazole | triazole | 1,3-dipolar cycloaddition
Journal Article
Organic Process Research & Development, ISSN 1083-6160, 04/2014, Volume 18, Issue 4, pp. 474 - 480
In this brief account, we review work from our lab with a focus on late-stage introduction of fluorine and fluorinated functional groups into small molecules.... 
PALLADIUM | COPPER-MEDIATED FLUORINATION | MECHANISM | ARYL STANNANES | F BOND | CHEMISTRY | CHEMISTRY, ORGANIC | BETA-FLUORIDE ELIMINATION | BOND FORMATION | CHEMISTRY, APPLIED | REDUCTIVE ELIMINATION | TRIFLUOROMETHYL TRIFLATE | Review
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/1995, Volume 36, Issue 29, pp. 5247 - 5250
A PdCl (PPh ) /LiCl catalyst effectively promoted the cross-coupling reaction of trimethyl(4-pyridyl)stannane and aromatic polybromides to offer easy access to... 
CHEMISTRY, ORGANIC | IONS | COMPLEX | LIGANDS | ARYL HALIDES
Journal Article
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