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Chemical Society Reviews, ISSN 0306-0012, 11/2015, Volume 44, Issue 22, pp. 7929 - 7967
The transition metal-catalyzed allylic substitution of unactivated allylic substrates (allylic alcohols, allylic ethers and allylic amines) is rapidly becoming... 
Carbon-carbon composites | Amines | Byproducts | Substitution reactions | Wastes | Ethers | Substrates | Alcohols
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 11/2015, Volume 44, Issue 22, pp. 7929 - 7967
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 4, pp. 1498 - 1501
Reported herein is a copper‐catalyzed SN2′‐selective allylic substitution reaction using readily accessible allylic chlorides and 1,1‐diborylalkanes, a... 
regioselectivity | copper | boron | allylic compounds | N-heterocyclic carbenes | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | ALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | LIGANDS | DIBORYLMETHANE | CONSTRUCTION | PHOSPHATES | ARYL | Substitution reactions | Dichloropropane | Copper | Chlorides | Utilities | Accessibility | Imidazole | Chemical reactions | Activation | Catalysis | Chemical synthesis
Journal Article
by Guo, WS and Cai, AJ and Xie, JN and Kleij, AW
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 09/2017, Volume 56, Issue 39, pp. 11797 - 11801
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 38, pp. 11651 - 11655
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 4002 - 4005
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2007, Volume 129, Issue 48, pp. 14856 - 14857
A method for the synthesis of α-chiral allylboronates featuring the Cu(I)-catalyzed enantioselective substitution of readily available allylic carbonates with... 
ALCOHOLS | REARRANGEMENT | ACCELERATION | ASYMMETRIC-SYNTHESIS | REAGENTS | CROSS-COUPLING REACTION | BIS(PINACOLATO)DIBORON | ALLYLBORATION | ALDEHYDES | DIBORATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2012, Volume 51, Issue 14, pp. 3470 - 3473
The direct route: Iridium‐catalyzed direct conversion of branched allylic alcohols into enantioenriched branched primary allylic amines is highly regio‐ and... 
enantioselectivity | iridium | direct substitution | amination | sulfamic acid | SUBSTITUTION | PALLADIUM | ASYMMETRIC-SYNTHESIS | AMMONIA | COMPLEXES | ALLYLATION | RESOLUTION | PHOSPHORAMIDITE | ALKYLATIONS | CHEMISTRY, MULTIDISCIPLINARY | Amines | Branched | Direct conversion | Alcohols
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2013, Volume 2013, Issue 22, pp. 4903 - 4908
A perfectly γ‐selective copper(I)‐catalyzed allylic substitution of protected δ‐hydroxy allylic chlorides with a silicon nucleophile generated by Si–B bond... 
Silicon | Synthetic methods | Regioselectivity | Copper | Allylic substitution | Diastereoselectivity | ORGANIC-SYNTHESIS | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | B BOND ACTIVATION | CHEMISTRY, ORGANIC | CLAISEN REARRANGEMENTS | SI-H INSERTION | STEREOSELECTIVE SYNTHESIS | BETA-HYDROXYALLYLSILANES | FORMAL ALPHA-HYDROXYALLYLATION | STEREOCONTROLLED SYNTHESIS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2008, Volume 47, Issue 40, pp. 7652 - 7655
A final tweak: A new phosphoramidite iridium catalyst (see scheme) allows allylic substitutions to be run with a higher degree of regioselectivity than with... 
iridium | allylic amines | allylic substitution | asymmetric catalysis | cyclization | Allylic amines | Iridium | Cyclization | Asymmetric catalysis | Allylic substitution | LIGANDS | COMPLEXES | ETHERIFICATION | AMINATIONS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article