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Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 29, pp. 8444 - 8447
A chemoselective C−O bond cleavage of the ester alkyl side‐chain of α‐acyloxy ketones was realized for the first time by a highly efficient palladium‐catalyzed... 
kinetic resolution | palladium | hydrogenolysis | ketones | cleavage reactions | PHENACYL ESTERS | RESOLUTION | COMPLEXES | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC HYDROGENATION | PROTECTING GROUPS | PHOTOLYSIS | DERIVATIVES | EFFICIENT | CYCLIZATION
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 12/2014, Volume 50, Issue 99, pp. 15718 - 15721
A stable nickel(II) methyl complex containing a diphosphino-boryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond... 
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2017, Volume 58, Issue 2, pp. 142 - 144
[Display omitted] •Transition-metal-catalyzed asymmetric hydrogenolysis of hemiaminal is developed.•Molecular hydrogen is used as hydride source.•Chiral... 
Hemiaminal | Asymmetric hydrogenolysis | Iridium | CATALYZED ASYMMETRIC HYDROGENATION | CHIRAL PHOSPHORUS LIGANDS | COMPLEXES | CHEMISTRY, ORGANIC | Enantiomers | Hydrogenation
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2017, Volume 82, Issue 9, pp. 4737 - 4743
A straightforward strategy for the syntheses of curcumene and ar-himachalene is reported. Synthetic highlights include a catalytic and asymmetric vinylogous... 
SESQUITERPENES | KETONES | CROSS-COUPLING REACTIONS | ASYMMETRIC-SYNTHESIS | BENZYLIC ETHERS | ENANTIOSELECTIVE SYNTHESIS | VINYLOGOUS MUKAIYAMA REACTIONS | CHEMISTRY, ORGANIC | ALDEHYDES | COMPONENT | Substitution reactions | Asymmetric induction (Stereochemistry) | Research | Chemical properties | Metal catalysts | Lactones | Organic chemistry | Chemical Sciences
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 05/2017, Volume 2017, Issue 19, pp. 2842 - 2847
The hydrogenolysis of enantioenriched donor–acceptor (D–A) cyclopropanes using H2 (1 atm) and a catalytic amount of palladium on charcoal gave... 
Deuterium | Small ring systems | Asymmetric synthesis | Hydrogenation | Donor‐acceptor systems | Ring opening | Donor-acceptor systems | Synthesis | Cyclopropane compounds | Palladium | Enantiomers | Organic compounds | Lactones
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2006, Volume 45, Issue 7, pp. 1092 - 1095
Split and run: A study of the asymmetric hydrogenolysis of an aryl‐carbon–bromine bond in a naphthalene chromiumtricarbonyl complex shows the use of a new... 
P ligands | palladium | chromium | asymmetric synthesis | hydrogenolysis | Chromium | Palladium | Asymmetric synthesis | Hydrogenolysis | PLANAR CHIRALITY | CHEMISTRY, MULTIDISCIPLINARY | DESYMMETRIZATION | MODULAR APPROACH | CYCLIZATIONS | LIGANDS | ARENE CHROMIUM COMPLEXES | ASYMMETRIC INDUCTION | METHOXYCARBONYLATION | CONJUGATE ADDITION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2013, Volume 52, Issue 50, pp. 13365 - 13368
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 04/2018, Volume 59, Issue 16, pp. 1592 - 1595
[Display omitted] •Employing SPINOL-derived phosphoric acid as catalyst.•Using a high steric demand Hantzsch ester as the hydrogen source.•The corresponding... 
Hydrogenolysis | Asymmetric catalysis | Hantzsch ester | Chiral phosphoric acid | ISOINDOLINONES | FORMIC-ACID | BENZYLIC ALCOHOLS | IONIC HYDROGENATION | CHEMISTRY, ORGANIC | PHSCF2SIME3 | TRIETHYLSILANE | FLUORIDE | TERTIARY ALCOHOLS | SYNTHETIC METHODS | EFFICIENT
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 7, pp. 2778 - 2785
Rhodium bis­(diazaphospholane) (BDP) catalyzed hydroformylation of styrene is sensitive to CO concentration, and drastically different kinetic regimes are... 
ASYMMETRIC HYDROFORMYLATION | VINYL-ACETATE | ALLYL CYANIDE | RHODIUM(I) COMPLEXES | HETEROCYCLIC OLEFINS | DEUTERIOFORMYLATION | H-2 NMR | DIAZAPHOSPHOLANE LIGANDS | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINE-PHOSPHITE LIGANDS | ENANTIOSELECTIVE HYDROFORMYLATION | Chemical properties | Research | Rhodium | Chemical reaction, Rate of | Styrene
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 11/2009, Volume 131, Issue 43, pp. 15606 - 15606
The modification of sp(3)-hybridized carbon centers through Pd-catalyzed reductive cleavage of unstrained carbon-carbon a bonds is described. From the... 
PALLADIUM | 5-(1-ARYLALKYLIDENE) MELDRUMS ACIDS | ACTIVATION | ASYMMETRIC-SYNTHESIS | HYDROGENATION | CATALYZED CONJUGATE ADDITION | DIALKYLZINC REAGENTS | INTRAMOLECULAR ARYLCYANATION | CLEAVAGE | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2004, Volume 69, Issue 8, pp. 2773 - 2784
Journal Article
Synlett, ISSN 0936-5214, 4/2006, Volume 2006, Issue 6, pp. 889 - 892
Abstract A practical, safe, high-yielding and efficient synthesis of (S)-pyrrolidin-2-yl-1H-tetrazole has been developed, which avoids the generation of... 
letter | Asymmetric | Synthesis | Hydrogenation | Organocatalysis | Tetrazole | Flow
Journal Article
ChemCatChem, ISSN 1867-3880, 05/2013, Volume 5, Issue 5, pp. 1205 - 1210
A stepwise catalytic reduction of ketone 1 to alcohol 2 and subsequently to aryl(imidazo[1,2‐b]pyridazinyl)methane 3 is described, which provides synthetically... 
ruthenium | palladium | heterogeneous catalysis | homogeneous catalysis | hydrogenation | Heterogeneous catalysis | Palladium | Ruthenium | Hydrogenation | Homogeneous catalysis | ASYMMETRIC TRANSFER HYDROGENATION | COMPLEXES | CHEMISTRY, PHYSICAL | RUTHENIUM(II) CATALYST | Methane | Physicians (General practice)
Journal Article
Chemical Communications, ISSN 1359-7345, 12/2014, Volume 50, Issue 99, pp. 15718 - 15721
A stable nickel(II) methyl complex containing a diphosphino-boryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond... 
HOMOGENEOUS HYDROGENATION | REACTIVITIES | 1-OCTENE | COMPLEXES | HYDROCHLORIDES | RUTHENIUM | ASYMMETRIC HYDROGENATION | PBP PINCER LIGAND | H-2 | CHEMISTRY, MULTIDISCIPLINARY | H ACTIVATION | Chemical bonds | Ligands | Nickel | Hydrides | Hydrogenolysis | Cooperation
Journal Article
Russian Journal of General Chemistry, ISSN 1070-3632, 9/2014, Volume 84, Issue 9, pp. 1656 - 1661
Aldehydes and ketones are found to be hydrogenated to alcohols with hydrogen at atmospheric pressure under the catalysis with nickel nanoparticles. The... 
Chemistry | nickel nanoparticles | Chemistry/Food Science, general | catalysis | hydrogenolysis | hydrogenation | carbonyl bond | SYSTEM | NANOPARTICLES | KETONES | ASYMMETRIC TRANSFER HYDROGENATION | PHASE HYDROGENATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | Catalysis | Ketones | Aldehydes | Hydrogen | Hydrogenation
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2013, Volume 54, Issue 24, pp. 3082 - 3084
The enantioselective hydrogenolysis of racemic 3-aryl-3-hydroxyisoindolin-1-ones catalyzed by BINOL-derived chiral phosphoric acid with benzothiazoline as the... 
Imine reduction | Hydrogenolysis | Asymmetric organocatalysis | Chiral phosphoric acid | CHEMISTRY, ORGANIC | CASCADE | HANTZSCH ESTERS | ENANTIOSELECTIVE TRANSFER HYDROGENATION | BENZOTHIAZOLINE | ALPHA-IMINO ESTERS | ORGANOCATALYTIC TRANSFER HYDROGENATION | EFFICIENT | REDUCTIVE AMINATION | CYCLIZATION | ACCESS | Tetrahedrons | Phosphoric acid | Hydrides | Asymmetry
Journal Article
Synfacts, ISSN 1861-1958, 04/2015, Volume 11, Issue 4, pp. 0394 - 0394
Journal Article