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chemistry, multidisciplinary (29) 29
chemistry, organic (27) 27
asymmetric silaboration (24) 24
palladium (23) 23
catalysis (19) 19
stereoselective-synthesis (16) 16
allenes (14) 14
alkynes (13) 13
asymmetric-synthesis (13) 13
complexes (13) 13
regioselective silaboration (13) 13
terminal alkynes (13) 13
silaboration (12) 12
silicon (12) 12
boron (11) 11
diboration (10) 10
asymmetric catalysis (9) 9
organic-synthesis (9) 9
activation (8) 8
allylsilanes (8) 8
copper (8) 8
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enantioselective synthesis (7) 7
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regioselectivity (7) 7
rhodium (7) 7
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chemistry, inorganic & nuclear (6) 6
hydroboration (6) 6
organoboron compounds (6) 6
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transition-metal-complexes (6) 6
additions (5) 5
aldehydes (5) 5
catalyzed regioselective silaboration (5) 5
chemistry, physical (5) 5
cross-coupling reactions (5) 5
derivatives (5) 5
esters (5) 5
hydrogenation (5) 5
hydrosilylation (5) 5
nickel (5) 5
oxidative addition (5) 5
platinum complexes (5) 5
reagents (5) 5
research (5) 5
silanes - chemical synthesis (5) 5
silanes - chemistry (5) 5
allene (4) 4
allylation (4) 4
bonds (4) 4
conjugate addition (4) 4
conjugate additions (4) 4
diels-alder reactions (4) 4
heteroatom bonds (4) 4
homogeneous catalysis (4) 4
intramolecular bis-silylation (4) 4
molecular structure (4) 4
si-b bond (4) 4
silylation (4) 4
silylboranes (4) 4
1,3-dienes (3) 3
1,4-addition (3) 3
alkadienes - chemistry (3) 3
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alkynylstannylation (3) 3
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ketones (3) 3
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organic chemistry (3) 3
organic iodides (3) 3
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Asian journal of organic chemistry, ISSN 2193-5815, 2019, Volume 8, Issue 7, pp. 1092 - 1096
An organocatalytic silaboration of terminal alkynes and allenes was established using pyridine‐based catalysts... 
organocatalysis | pyridines | organoboron compounds | organosilicon compounds | synthetic methods | B BOND | PALLADIUM | BORON | FREE BORYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | N-HETEROCYCLIC CARBENES | ALKENES | ASYMMETRIC SILABORATION | METAL-FREE DIBORATION | CONJUGATE ADDITIONS
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2018, Volume 8, Issue 2, pp. 1227 - 1230
Under catalysis by commercially available supported Au nanoparticles on TiO2 (1 mol %), terminal allenes undergo diboration and silaboration exclusively on the terminal double bond, in high yields and stereoselectivity... 
allenes | Au nanoparticles | catalysis | diboration | silaboration | ACTIVATION | ORGANIC IODIDES | MECHANISM | SUPPORTED GOLD NANOPARTICLES | COMPLEXES | STEREOCHEMISTRY | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | SELECTIVE HYDROSILYLATION | ASYMMETRIC SILABORATION | NANOPOROUS GOLD
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 1/2009, Volume 82, Issue 1, pp. 29 - 49
.... The silaborations proceed in highly regio- and stereoselective manners, leading to the formation of organic compounds bearing silyl and boryl groups... 
ORGANOBORON COMPOUNDS | C BOND-CLEAVAGE | TRANSITION-METAL-COMPLEXES | ASYMMETRIC SILABORATION | HETEROATOM BONDS | GEM-SILYLBORYLATION | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED REGIOSELECTIVE SILABORATION | PLATINUM COMPLEXES | INTRAMOLECULAR BIS-SILYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2011, Volume 133, Issue 19, pp. 7324 - 7327
The addition of silylboronic esters to pyridine takes place in toluene at 50 °C in the presence of a palladium catalyst to give... 
COMPLEXES | TERMINAL ALKYNES | NICKEL/LEWIS ACID CATALYSIS | IRON-SILICON BOND | ENANTIOSELECTIVE ADDITION | ASYMMETRIC HYDROGENATION | SELECTIVE ALKENYLATION | AROMATIC-COMPOUNDS | DERIVATIVES | SALTS | CHEMISTRY, MULTIDISCIPLINARY | Chemical reactions | Palladium | Pyridine | Analysis | Electric properties
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2013, Volume 355, Issue 5, pp. 853 - 856
The palladium‐catalyzed silaboration of ynamides is demonstrated. The silaboration proceeds in a highly regioselective manner to give the corresponding tri... 
palladium | ynamides | silicon | boron | metallation | C BOND-CLEAVAGE | N-ALLYL-YNAMIDES | REGIOSELECTIVE SILABORATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | CLAISEN REARRANGEMENT | PLATINUM COMPLEXES | RING-CLOSING METATHESIS | ASYMMETRIC SILABORATION | 2+2+2 CYCLOADDITIONS | STEREOGENIC CENTERS | CHEMISTRY, APPLIED | Palladium | Aromatic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2007, Volume 129, Issue 28, pp. 8766 - 8773
Journal Article
Organometallics, ISSN 0276-7333, 04/2008, Volume 27, Issue 8, pp. 1736 - 1742
A mechanism for the regioselective silaboration of terminal allene by a palladium catalyst has been studied theoretically... 
DENSITY | 1,2-DIENES | ACTIVATION | 1,3-DIENES | ASYMMETRIC SILABORATION | SI | COMPLEXES | CHEMISTRY, ORGANIC | ALKYNES | ORGANODISILANES | REDUCTIVE ELIMINATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Synfacts, ISSN 1861-1958, 7/2008, Volume 2008, Issue 7, pp. 0739 - 0739
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 22, pp. 7193 - 7202
A novel copper‐catalyzed, highly regio‐ and stereoselective borylcupration of substituted 2,3‐allenamides with bis(pinacolato)diboron producing Z‐β‐borylated... 
regioselectivity | allenes | copper | amides | stereoselectivity | boron | ORGANOBORON COMPOUNDS | HYDROBORATION | ASYMMETRIC-SYNTHESIS | REGIOSELECTIVE SILABORATION | BORONIC ESTERS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | BIS(PINACOLATO)DIBORON | STEREOSELECTIVE-SYNTHESIS | DIBORATION | Green chemistry | Green technology | Beta | Stereoselectivity | Amides | Catalysis | Catalysts
Journal Article
Organic letters, ISSN 1523-7060, 12/2019, Volume 21, Issue 24, pp. 9893 - 9897
Stereoselective synthesis of γ,δ-bifunctionalized homoallylic alcohols and ethers via chemoselective allylation is reported. Pd-catalyzed 1,2-diboration of... 
PALLADIUM | HYDROBORATION | REAGENTS | ENANTIOSELECTIVE SYNTHESIS | SELECTIVE DESILYLATION | ORGANIC IODIDES | ASYMMETRIC SILABORATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALLENES | CATALYZED REGIOSELECTIVE SILABORATION
Journal Article
Synfacts, ISSN 1861-1958, 1/2007, Volume 2007, Issue 1, pp. 0068 - 0068
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 25, pp. 6546 - 6549
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2008, Volume 130, Issue 5, pp. 1526 - 1527
Silylpinacolboranes bearing dialkylamino groups on the silicon atom served as synthetic equivalents of silylene in palladium-catalyzed reactions with terminal... 
CARBON UNSATURATED-COMPOUNDS | SILACYCLOPROPENE RINGS | MOLECULAR-STRUCTURE | 2 ATOM INSERTIONS | ASYMMETRIC SILABORATION | (PHENYLETHYNYL)POLYSILANES | 1-SILACYCLOPENTA-2,4-DIENES | ALKYNES | ALLENES | CHEMISTRY, MULTIDISCIPLINARY | PHENYL(TRIMETHYLSILYL)ACETYLENE | Silicon compounds | Research | Chemical properties | Catalysis
Journal Article
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