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1. Full Text Gold‐Catalyzed Highly Selective Photoredox C(sp2)−H Difluoroalkylation and Perfluoroalkylation of Hydrazones
by Xie, Jin and Zhang, Tuo and Chen, Fei and Mehrkens, Nina and Rominger, Frank and Rudolph, Matthias and Hashmi, A. Stephen K
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 8, pp. 2934 - 2938
The first gold‐catalyzed photoredox C(sp2)−H difluoroalkylation and perfluoroalkylation of hydrazones with readily available RF−Br reagents is reported. The... 
C−H functionalization | gold catalysis | photocatalysis | fluorine | C-H functionalization | PALLADIUM | VISIBLE-LIGHT PHOTOREDOX | FLUOROALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZATION | ALKENES | DIFLUOROMETHYLATION | ARYL BORONIC ACIDS | GEM-DIFLUOROALLYLATION | Phosphonates | Fluorides | Catalysis | Coupling (molecular) | Gold | Trapping | Reagents | Phosphonic acids | Hydrazones | Amino acids | Derivatives
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2. Full Text Visible‐Light Photoredox‐Catalyzed C−H Difluoroalkylation of Hydrazones through an Aminyl Radical/Polar Mechanism
by Xu, Pan and Wang, Guoqiang and Zhu, Yuchen and Li, Weipeng and Cheng, Yixiang and Li, Shuhua and Zhu, Chengjian
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 8, pp. 2939 - 2943
An unprecedented visible‐light‐induced direct C−H bond difluoroalkylation of aldehyde‐derived hydrazones was developed. This reaction represents a new way to... 
radical reactions | imines | photocatalysis | hydrazones | fluorine | ORGANIC-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | DIFLUOROMETHYLATION | HETEROARENES | ARYL BORONIC ACIDS | SYNTHETIC APPLICATIONS | BOND | DERIVATIVES | CYCLIZATION | Schiff bases | Fluorides | Catalysis | Analysis | Mathematical analysis | Electron transfer | Hydrazones | Cations | Transformations | Computing time | Chemical synthesis | Light effects
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3. Full Text Photocatalytic Generation of N‐Centered Hydrazonyl Radicals:  A Strategy for Hydroamination of β,γ‐Unsaturated Hydrazones
by Hu, Xiao‐Qiang and Chen, Jia‐Rong and Wei, Qiang and Liu, Feng‐Lei and Deng, Qiao‐Hui and Beauchemin, André M and Xiao, Wen‐Jing
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2014, Volume 53, Issue 45, pp. 12163 - 12167
A visible‐light photocatalytic generation of N‐centered hydrazonyl radicals has been accomplished for the first time. This approach allows efficient... 
ruthenium | radicals | photocatalysis | heterocycles | hydrazones | Hydrazones | Heterocycles | Ruthenium | Photocatalysis | Radicals | ORGANIC-SYNTHESIS | ACID | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | TRANSITION | FUNCTIONALIZATION | ALKENES | DUAL CATALYSIS | VISIBLE-LIGHT-PHOTOREDOX | C-H AMINATION | Amines - chemistry | Catalysis | Free Radicals | Hydrazones - chemistry | Photochemical Processes
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4. Full Text Hydrolytic Stability of Hydrazones and Oximes
by Kalia, Jeet and Raines, Ronald T
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2008, Volume 47, Issue 39, pp. 7523 - 7526
Watching C 'n' N: Hydrazones and oximes are common conjugates but are labile to hydrolysis. The hydrolytic stabilities of isostructural hydrazones and one... 
reaction mechanisms | oximes | hydrazones | hydrolysis | Hydrolysis | Oximes | Hydrazones | Reaction mechanisms | CARBONYL GROUP | EQUILIBRIUM-CONSTANTS | PROTEIN | MECHANISM | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | NUCLEOPHILIC CATALYSIS | SEMICARBAZONE FORMATION | ACID CATALYSIS | CHEMICAL-SYNTHESIS | SURFACES | Oximes - chemistry | Titrimetry | Hydrazones - chemical synthesis | Molecular Structure | Kinetics | Methylation | Hydrazones - chemistry | conjugates
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5. Full Text Catalytic Enantioselective Iodoaminocyclization of Hydrazones
by Tripathi, Chandra Bhushan and Mukherjee, Santanu
Organic Letters, ISSN 1523-7060, 06/2014, Volume 16, Issue 12, pp. 3368 - 3371
The first catalytic enantioselective iodoaminocyclization of β,γ-unsaturated hydrazones has been developed with the help of a... 
ALKENES | 1,3-DIPOLAR CYCLOADDITIONS | SPINDLE PROTEIN KSP | ASYMMETRIC BROMOLACTONIZATION | MITOTIC KINESIN KSP | PHASE-TRANSFER CATALYSIS | CHEMISTRY, ORGANIC | NITRILE IMINES | POTENT INHIBITORS | CARBOXYLIC-ACIDS | BIFUNCTIONAL ORGANOCATALYSTS | Pyrazoles - chemistry | Pyrazoles - chemical synthesis | Stereoisomerism | Cyclohexylamines - chemistry | Molecular Structure | Catalysis | Hydrocarbons, Iodinated - chemistry | Thiourea - chemistry | Hydrazones - chemistry
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6. Full Text LC–UV/MS methods for the analysis of prochelator—Boronyl salicylaldehyde isonicotinoyl hydrazone (BSIH) and its active chelator salicylaldehyde isonicotinoyl hydrazone (SIH)
by Bureš, Jan and Jansová, Hana and Stariat, Ján and Filipský, Tomáš and Mladěnka, Přemysl and Šimůnek, Tomáš and Kučera, Radim and Klimeš, Jiří and Wang, Qin and Franz, Katherine J and Kovaříková, Petra
Journal of Pharmaceutical and Biomedical Analysis, ISSN 0731-7085, 02/2015, Volume 105, pp. 55 - 63
Salicylaldehyde isonicotinoyl hydrazone (SIH) is an intracellular iron chelator with well documented potential to protect against oxidative injury both and .... 
Boronyl salicylaldehyde isonicotinoyl hydrazone | Stability | Aroylhydrazone | Pharmacokinetics | Prochelator salicylaldehyde isonicotinoyl hydrazone | ANTHRACYCLINE CARDIOTOXICITY | CHEMISTRY, ANALYTICAL | OXIDATIVE STRESS | IRON CHELATORS | Prochelator salicylaldehyde isonicotinoyl hydrazone Pharmacokinetics | INJURY | MASS-SPECTROMETRY | CELL-DEATH | PROTECTS | IN-VIVO | PHARMACOLOGY & PHARMACY | HYDROGEN-PEROXIDE | RABBIT PLASMA | Chelating Agents - analysis | Hydrazones - blood | Isonicotinic Acids - blood | Rats, Wistar | Drug Stability | Male | Aldehydes - blood | Isonicotinic Acids - analysis | Reference Standards | Animals | Aldehydes - analysis | Boronic Acids - analysis | Spectrophotometry, Ultraviolet - methods | Sensitivity and Specificity | Molecular Structure | Chromatography, Liquid - methods | Culture Media - chemistry | Mass Spectrometry - methods | Hydrazones - analysis | Boronic Acids - blood | pharmacokinetics | prochelator salicylaldehyde isonicotinoyl hydrazone | aroylhydrazone | boronyl salicylaldehyde isonicotinoyl hydrazone
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7. Full Text Oximes and Hydrazones in Bioconjugation: Mechanism and Catalysis
by Kölmel, Dominik K and Kool, Eric T
Chemical Reviews, ISSN 0009-2665, 08/2017, Volume 117, Issue 15, pp. 10358 - 10376
The formation of oximes and hydrazones is employed in numerous scientific fields as a simple and versatile conjugation strategy. This imine-forming reaction is... 
PICTET-SPENGLER LIGATION | SEMICARBAZONE FORMATION | BUILDING-BLOCKS | CONTAINING AMINO-ACID | NEUTRAL PH | PROTEIN MODIFICATION | BIOORTHOGONAL CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | DYNAMIC COMBINATORIAL LIBRARIES | CHAIN CROSS-LINKS | NUCLEOPHILIC CATALYSIS | Biocompatible Materials - chemical synthesis | Oximes - chemistry | Biocompatible Materials - chemistry | Imines - chemistry | Molecular Structure | Catalysis | Imines - chemical synthesis | Hydrazones - chemistry
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8. Full Text AgOTf-catalyzed reaction of sulfonyl hydrazones with ynamides led to stereoselective synthesis of α-amino alkenyl-substituted hydrazone derivatives
by Cao, Ziping and Yan, Shikun and Zhao, Changyin and Sun, Xuejun and Tian, Laijin and Meng, Xin
Tetrahedron, ISSN 0040-4020, 09/2019, Volume 75, Issue 39, p. 130534
A novel method for the synthesis of -amino alkenyl-substituted hydrazone derivatives was disclosed through silver-catalyzed reaction of sulfonyl hydrazones... 
Ynamide | Enamide | Silver catalysis | Hydrazone | Alkenylation | DOMINO REACTION | 1,3-DIPOLAR CYCLOADDITIONS | CONJUGATED DIENES | CHEMISTRY, ORGANIC | DIAZO-COMPOUNDS | DIPHENYLDITHIOPHOSPHINIC ACID | N-TOSYLHYDRAZONES | ORTHO-ALKYNYLARYLALDEHYDES | REGIOSELECTIVE SYNTHESIS | CIS-HYDROARYLATION | VERSATILE REAGENTS
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9. Full Text Denitrogenative Hydrotrifluoromethylation of Benzaldehyde Hydrazones: Synthesis of (2,2,2‐Trifluoroethyl)arenes
by Zhao, Zhensheng and Ma, Kevin C. Y and Legault, Claude Y and Murphy, Graham K
Chemistry – A European Journal, ISSN 0947-6539, 08/2019, Volume 25, Issue 48, pp. 11240 - 11245
Reacting hydrazones of arylaldehydes with Togni's CF3‐benziodoxolone reagent, in the presence of potassium hydroxide and cesium fluoride, induces a... 
hypervalent iodine | Wolff–Kishner | trifluoromethylation | hydrazones | fluorine | NUCLEOPHILIC TRIFLUOROMETHYLATION | C-H TRIFLUOROETHYLATION | MOLECULAR CALCULATIONS | Wolff-Kishner | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | CROSS-COUPLING REACTIONS | COPPER-CATALYZED TRIFLUOROMETHYLATION | METAL-FREE TRIFLUOROMETHYLATION | ORGANIC HALIDES | ARYL IODIDES | BASIS-SETS | Transition metal compounds | Hydroxides | Fluorides | Transition metals | Potassium hydroxide | Benzaldehyde | Hydrazones | Substitution reactions | Cesium | Potassium hydroxides | Substrates | Cesium fluorides | Fluoride | Aromatic compounds | Reagents | Potassium | Functional groups
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10. Full Text Extending the Scope of the B(C6F5)3‐Catalyzed CN Bond Reduction: Hydrogenation of Oxime Ethers and Hydrazones
by Mohr, Jens and Porwal, Digvijay and Chatterjee, Indranil and Oestreich, Martin
Chemistry – A European Journal, ISSN 0947-6539, 12/2015, Volume 21, Issue 49, pp. 17583 - 17586
The B(C6F5)3‐catalyzed hydrogenation is applied to aldoxime triisopropylsilyl ethers and hydrazones bearing an easily removable phthaloyl protective group. The... 
Lewis acids | homogeneous catalysis | reduction | boron | hydrogenation
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11. Full Text Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update
by Kobayashi, Shu̅ and Mori, Yuichiro and Fossey, John S and Salter, Matthew M
Chemical Reviews, ISSN 0009-2665, 04/2011, Volume 111, Issue 4, pp. 2626 - 2704
AZA-HENRY REACTION | DIELS-ALDER REACTIONS | BOC-PROTECTED IMINES | MANNICH-TYPE REACTIONS | N-SULFONATED IMINES | ASYMMETRIC ALDOL REACTIONS | BAYLIS-HILLMAN REACTION | ALPHA-AMINO-ACIDS | CHIRAL BRONSTED ACID | FRIEDEL-CRAFTS REACTION | CHEMISTRY, MULTIDISCIPLINARY | Catalysis | Isomerism | Hydrazones - chemistry | Imines - chemistry | Analysis | Organometallic compounds | Chemical bonds | Acid-base chemistry | Chemical properties | Structure | Nucleophiles | Carbon
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12. Full Text Nickel‐Catalyzed Asymmetric Transfer Hydrogenation of Hydrazones and Other Ketimines
by Xu, Haiyan and Yang, Peng and Chuanprasit, Pratanphorn and Hirao, Hajime and Zhou, Jianrong (Steve)
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 17, pp. 5112 - 5116
We report the use of nickel catalysts for the catalytic transfer hydrogenation of hydrazones and other ketimines with formic acid. Strongly donating... 
nickel | transfer hydrogenation | asymmetric catalysis | hydrazones | hydride insertion | Hydrazones | Hydride insertion | Transfer hydrogenation | Nickel | Asymmetric catalysis | BRONSTED ACID | ENANTIO-DIFFERENTIATING HYDROGENATION | NONCOVALENT INTERACTIONS | CHIRAL PHOSPHORIC-ACID | CHEMISTRY, MULTIDISCIPLINARY | DYNAMIC KINETIC RESOLUTION | BETA-AMINO ACIDS | HIGHLY ENANTIOSELECTIVE HYDROGENATION | COOPERATIVE CATALYSIS | IMINE HYDROGENATION | REDUCTIVE AMINATION | Phosphines - chemistry | Nickel - chemistry | Formates - chemistry | Stereoisomerism | Molecular Conformation | Imines - chemistry | Nitriles - chemistry | Crystallography, X-Ray | Catalysis | Hydrogenation | Hydrazones - chemistry | Enzymes | Analysis | Formic acid | Organic acids | Asymmetry | Catalysts | Aromatic compounds
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