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chemistry, multidisciplinary (132) 132
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Angewandte Chemie - International Edition, ISSN 1433-7851, 09/2009, Volume 48, Issue 38, pp. 7083 - 7086
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 21, pp. 3078 - 3081
Enantioselective synthesis of SiMe3/SiPh2Me-substituted crotyl geminal bis(silane) has been developed. This compound is a useful reagent for Ph3C+B(C6F5)(4)... 
LEWIS-ACID CATALYSTS | DIELS-ALDER | SILICON-CONTAINING COMPOUNDS | TRITYL PERCHLORATE | ENANTIOSELECTIVE SYNTHESIS | NATURAL-PRODUCTS | SILYL ENOL ETHERS | CLAISEN REARRANGEMENT | CHEMISTRY, MULTIDISCIPLINARY | MUKAIYAMA ALDOL | TRIARYLCARBENIUM IONS | Chemical reactions | Synthesis | Asymmetry | Allyl compounds | Chirality | Reagents
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 2018, Volume 22, Issue 24, pp. 2413 - 2417
A series of new ester-substituted alkoxysilanes has been prepared. These bifunctional silanes were gently synthesized via hydrosilylation of carbon-carbon... 
alkoxysilanes | platinum | homogeneous catalysis | allyl esters | SILSESQUIOXANES | silyl ethers | silanes | CHEMISTRY, ORGANIC | OLEFINS | Hydrosilylation
Journal Article
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, ISSN 1600-5368, 02/2012, Volume 68, Issue 2, pp. O452 - U1084
In the title compound, C21H18Si, the coordination geometry around the Si atom is a slightly distorted tetrahedron with C-Si-C angles in the range 106.05 (11)... 
ALLYL VINYL ETHERS | CLAISEN REARRANGEMENT | CRYSTALLOGRAPHY
Journal Article
Tetrahedron, ISSN 0040-4020, 12/2018, Volume 74, Issue 50, pp. 7228 - 7236
The first oxidative cross-coupling of allylsilanes with aryl boronic acids has been developed by palladium catalysis. The reaction between β-substituted... 
Oxidative cross-coupling | Aryl boronic acid | Palladium catalysis | Allyl(trimethyl)silane | TRANSFORMATION | COMPLEX | ALLYLATION | SILICON | CHEMISTRY, ORGANIC | ALLYLSILANES | ALCOHOLS | TRIFLUOROMETHYLTHIOLATION | GENERATION | ORGANOSILICON COMPOUNDS | CYCLIZATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2018, Volume 59, Issue 52, pp. 4557 - 4561
A ligand-free Pd-catalyzed cross-coupling of substituted allyl(trimethyl)silanes with aryl iodides enabled by silver salts was developed. This reaction... 
Cross-coupling | Silver salt | Palladium catalysis | Allyl(trimethyl)silane | REAGENTS | LEWIS-ACID | ALLYLATION | ARYLATION | CHEMISTRY, ORGANIC | ALLYLTRIFLUOROSILANES | ALLYLSILANES | ETHERS | TRIFLUOROMETHYLTHIOLATION | GENERATION | ENANTIOSELECTIVE TOTAL-SYNTHESIS
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 04/2012, Volume 51, Issue 15, pp. 3663 - 3667
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2017, Volume 73, Issue 26, pp. 3707 - 3713
Enantioselective synthesis of crotyl geminal bis(silane) has been developed by an asymmetric [1, 5]-hydride shift of allylic hydrazine. SnCl -promoted Sakurai... 
Allyl silanes | Chirality transfer | [1, 5]-hydride shift | Acetals | Sakurai allylation | CHEMISTRY, ORGANIC | [1,5]-hydride shift | Enantiomers | Silane
Journal Article
Organic Letters, ISSN 1523-7060, 03/2011, Volume 13, Issue 5, pp. 864 - 867
The scope of the (4 + 3) cycloaddition using epoxy enol silanes has been examined. Unhindered and nucleophilic dienes react to give the highest yields, but... 
ALLYL CATIONS | ROUTE | FURAN | DIENES | STEREOSELECTIVITY | 7-MEMBERED RINGS | CHEMISTRY, ORGANIC | OXYALLYL CATIONS | Alkenes - chemistry | Silanes - chemistry | Cyclization | Stereoisomerism | Epoxy Compounds - chemistry | Molecular Structure | Catalysis | Index Medicus
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 12/2018, Volume 8, Issue 12, pp. 11513 - 11523
Unambiguous examples of eta(3)-H2SiH(R) complexes featuring a terminal Si H bond have been prepared and examined as possible intermediates in olefin... 
ORGANIC-SYNTHESIS | CHEMISTRY, PHYSICAL | sigma complex | catalysis | silylene | CROSS-COUPLING REACTIONS | DFT | silane | SI-H | SILYLENE COMPLEXES | hydrosilation | HOMOGENEOUS CATALYSIS | ENHANCED REACTIVITY | BOND METATHESIS REACTIONS | mechanism | ALLYL CHLORIDE | ALKENE HYDROSILATION | C-H
Journal Article