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1. Full Text Mn-Catalyzed Highly Efficient Aerobic Oxidative Hydroxyazidation of Olefins: A Direct Approach to β‑Azido Alcohols
by Sun, Xiang and Li, Xinyao and Song, Song and Zhu, Yuchao and Liang, Yu-Feng and Jiao, Ning
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 18, pp. 6059 - 6066
An efficient Mn-catalyzed aerobic oxidative hydroxyazidation of olefins for synthesis of β-azido alcohols has been developed. The aerobic oxidative generation... 
SELECTIVE OXIDATION | AMINO-ALCOHOLS | C-H AZIDATION | KINETIC RESOLUTION | VICINAL DIFUNCTIONALIZATION | CLICK-CHEMISTRY | BOND-CLEAVAGE | IODINE(III) REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | TRANSITION-METAL-FREE | UNACTIVATED ALKENES | Alcohols - chemistry | Alkenes - chemistry | Oxidation-Reduction | Alcohols - chemical synthesis | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Manganese - chemistry | Azides - chemical synthesis | Azides - chemistry | Research | Chemical properties | Heterocyclic compounds | Olefins
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2. Full Text Kinetic Resolution of 1,1′‐Biaryl‐2,2′‐Diols and Amino Alcohols through NHC‐Catalyzed Atroposelective Acylation
by Lu, Shenci and Poh, Si Bei and Zhao, Yu
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2014, Volume 53, Issue 41, pp. 11041 - 11045
We present here a highly efficient NHC‐catalyzed kinetic resolution of a wide range of 1,1′‐biaryl‐2,2′‐diols and amino alcohols to provide them in uniformly... 
axial chirality | enantioselectivity | kinetic resolution | N‐heterocyclic carbene | acylation | N-heterocyclic carbene | Enantioselectivity | Kinetic resolution | Axial chirality | Acylation | Heterocyclic Compounds - chemistry | Nitrogen - chemistry | Methane - analogs & derivatives | Stereoisomerism | Methane - chemistry | Naphthols - chemistry | Catalysis | Kinetics | Amino Alcohols - chemistry | ASYMMETRIC CATALYSIS | BINAM DERIVATIVES | ACID | ENANTIOSELECTIVE SYNTHESIS | SMALL-MOLECULE | N-HETEROCYCLIC CARBENES | CHEMISTRY, MULTIDISCIPLINARY | SECONDARY ALCOHOLS | NUCLEOPHILIC CARBENES | AXIALLY CHIRAL BIARYLS | 2-NAPHTHOLS | Backbone | Catalysts | Reaction kinetics | Derivatives | Aldehydes | Alcohols
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3. Full Text Directed β C–H Amination of Alcohols via Radical Relay Chaperones
by Wappes, Ethan A and Nakafuku, Kohki M and Nagib, David A
Journal of the American Chemical Society, ISSN 0002-7863, 08/2017, Volume 139, Issue 30, pp. 10204 - 10207
A radical-mediated strategy for β C–H amination of alcohols has been developed. This approach employs a radical relay chaperone, which serves as a traceless... 
CATALYTIC FUNCTIONALIZATION | TRANSLOCATION | INSERTION | VICINAL AMINO-ALCOHOLS | BONDS | REMOTE OXIDATION | 1,5-HYDROGEN ATOM TRANSFER | 1,3-DIOL SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | AMIDINE MOIETY | Amines - chemistry | Alcohols - chemistry | Molecular Structure | Amines - chemical synthesis | Amination | Free Radicals - chemistry | Chemical bonds | Amines | Chemical properties | Research | Molecular chaperones | Analysis
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4. Full Text Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β‐Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes
by Srimani, Dipankar and Ben‐David, Yehoshoa and Milstein, David
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2013, Volume 52, Issue 14, pp. 4012 - 4015
Pyrroles were synthesized in one step by using the acceptorless dehydrogenative coupling of amino alcohols with secondary alcohols (equivalent amounts),... 
ruthenium | dehydrogenation | homogeneous catalysis | pyrroles | pincer complex | Pyrroles - chemical synthesis | Nitrogen - chemistry | Pyrroles - chemistry | Catalysis | Amino Alcohols - chemistry | Coordination Complexes - chemistry | Ruthenium - chemistry | Carbon - chemistry
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5. Full Text Chirality Sensing of Amines, Diamines, Amino Acids, Amino Alcohols, and α‑Hydroxy Acids with a Single Probe
by Bentley, Keith W and Nam, Yea G and Murphy, Jaslynn M and Wolf, Christian
Journal of the American Chemical Society, ISSN 0002-7863, 12/2013, Volume 135, Issue 48, pp. 18052 - 18055
A stereodynamic probe for determination of the absolute configuration and enantiomeric composition of chiral amines, diamines, amino alcohols, amino acids, and... 
ASYMMETRIC CATALYSIS | SECONDARY ALCOHOLS | STATIONARY-PHASE | ENANTIOMERIC EXCESS | ABSOLUTE-CONFIGURATION | RAPID-DETERMINATION | AXIAL CHIRALITY | CIRCULAR-DICHROISM PROTOCOL | ZINC PORPHYRIN | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACIDS | Amines - chemistry | Boron - chemistry | Stereoisomerism | Amino Acids - chemistry | Models, Molecular | Diamines - chemistry | Amino Alcohols - chemistry | Hydroxy Acids - chemistry | Zinc - chemistry | Coordination Complexes - chemistry | Amino acids | Chemical properties | Research | Chirality
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6. Full Text syn-1,2-Amino Alcohols via Diastereoselective Allylic C−H Amination
by Fraunhoffer, Kenneth J and White, M. Christina
Journal of the American Chemical Society, ISSN 0002-7863, 06/2007, Volume 129, Issue 23, pp. 7274 - 7276
A novel Pd/sulfoxide catalyzed diastereoselective allylic C−H amination reaction of chiral homoallylic N-tosyl carbamates is reported. Densely oxygenated... 
INTRAMOLECULAR DIAMINATION | ALKENES | FERROCENYLPHOSPHINE-PALLADIUM COMPLEXES | PALLADIUM(II)-CATALYZED CYCLIZATION | MANNICH-TYPE REACTION | OLEFINS | AMINO ALCOHOLS | HYDROCARBON OXIDATION | CATALYTIC ASYMMETRIC-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | ALLYLAMINES
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7. Full Text Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols
by Shi, Shi-Liang and Wong, Zackary L and Buchwald, Stephen L
Nature, ISSN 0028-0836, 04/2016, Volume 532, Issue 7599, pp. 353 - 356
The chirality, or 'handedness', of a biologically active molecule can alter its physiological properties. Thus it is routine procedure in the drug discovery... 
ALKENES | KETONES | DIASTEREOSELECTIVITY | MULTIDISCIPLINARY SCIENCES | ASYMMETRIC HYDROAMINATION | OLEFINS | ALDEHYDES | Chemistry Techniques, Synthetic | Copper - chemistry | Amination | Amino Alcohols - chemical synthesis | Stereoisomerism | Molecular Structure | Catalysis | Amino Alcohols - chemistry | Stereoisomers | Pharmaceutical research | Research | Alcohol | Ligands | Chemical synthesis | Copper | Chromatography | Pharmaceuticals
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8. Full Text Allylic C−H Amination for the Preparation of syn-1,3-Amino Alcohol Motifs
by Rice, Grant T and White, M. Christina
Journal of the American Chemical Society, ISSN 0002-7863, 08/2009, Volume 131, Issue 33, pp. 11707 - 11711
A highly selective and general Pd/sulfoxide-catalyzed allylic C−H amination reaction en route to syn-1,3-amino alcohol motifs is reported. Key to achieving... 
CATALYSIS | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | ENOL ETHERS | ACIDS | MANNICH REACTIONS | BETA-AMINO | HYDROCARBON OXIDATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | CONJUGATE ADDITION | Amino Alcohols - chemical synthesis | Safrole - analogs & derivatives | Stereoisomerism | Substrate Specificity | Hydrogen - chemistry | Carbamates - chemistry | Carbon - chemistry | Alkenes - chemistry | Amination | Safrole - chemistry | Catalysis | Amino Alcohols - chemistry | Palladium - chemistry | Electrons | Carbamates | Palladium | Amines | Chemical properties | Alcohols
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9. Full Text Iron/Amino Acid Catalyzed Direct N‐Alkylation of Amines with Alcohols
by Zhao, Yingsheng and Foo, Siong Wan and Saito, Susumu
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2011, Volume 50, Issue 13, pp. 3006 - 3009
Ironing it out: The straightforward N‐alkylation using alcohols and iron/amino acid catalysis is described (see scheme). The reaction does not proceed by the... 
iron | alcohols | N‐alkylation | homogeneous catalysis | amino acids | Amino acids | Iron | Homogeneous catalysis | Alcohols | N-alkylation | SUBSTITUTION | BORROWING HYDROGEN | TERTIARY-AMINES | SECONDARY | SULFONAMIDES | CHEMISTRY, MULTIDISCIPLINARY | BENZYL ALCOHOLS | DIRECT AMINATION | ALLYLIC ALCOHOLS | MONOALKYLATION | EFFICIENT | Amines - chemistry | Alcohols - chemistry | Stereoisomerism | Iron - chemistry | Amino Acids - chemistry | Molecular Structure | Amines - chemical synthesis | Catalysis | Alkylation
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10. Full Text A steric tethering approach enables palladium-catalysed C-H activation of primary amino alcohols
by Calleja, Jonas and Pla, Daniel and Gorman, Timothy W and Domingo, Victoriano and Haffemayer, Benjamin and Gaunt, Matthew J
Nature Chemistry, ISSN 1755-4330, 12/2015, Volume 7, Issue 12, pp. 1009 - 1016
Aliphatic primary amines are a class of chemical feedstock essential to the synthesis of higher-order nitrogen-containing molecules, commonly found in... 
C(SP)-H BONDS | PD(II)-CATALYZED OLEFINATION | MECHANISM | OXYGENATION | ARYLATION | ARENES | CONSTRUCTION | BOND FUNCTIONALIZATION | REACTIVITY | INTERMEDIATE | CHEMISTRY, MULTIDISCIPLINARY | Amines - chemistry | Models, Molecular | Molecular Structure | Catalysis | Amino Alcohols - chemistry | Palladium - chemistry | Chemical Sciences
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11. Full Text Synthesis and Applications of tert-Butanesulfinamide
by Robak, MaryAnn T and Herbage, Melissa A and Ellman, Jonathan A
Chemical Reviews, ISSN 0009-2665, 06/2010, Volume 110, Issue 6, pp. 3600 - 3740
CONCISE ASYMMETRIC-SYNTHESIS | HUMAN MELANOCORTIN-4 RECEPTOR | TRIFLUOROMETHYLATED ALLYLIC AMINES | UNSATURATED 1,2-AMINO ALCOHOLS | ALPHA-AMINO-ACIDS | DIFLUOROMETHYL PHENYL SULFONE | HIGHLY STEREOSELECTIVE-SYNTHESIS | RHODIUM-CATALYZED ADDITION | CHEMISTRY, MULTIDISCIPLINARY | N-SULFINYL IMINES | POTENT FUNCTIONAL AGONISTS | Amines - chemistry | Oxidation-Reduction | Sulfonamides - chemistry | Amino Alcohols - chemical synthesis | Stereoisomerism | Butanes - chemical synthesis | Amino Acids - chemistry | Amines - chemical synthesis | Amino Acids - chemical synthesis | Sulfonamides - chemical synthesis | Imines - chemistry | Diamines - chemistry | Organometallic Compounds - chemistry | Butanes - chemistry | Catalysis | Imines - chemical synthesis | Amino Alcohols - chemistry | Aziridines - chemistry | Diamines - chemical synthesis | Aziridines - chemical synthesis | Amines | Chemical properties | Tertiary butyl compounds | Structure | Chemical synthesis | Analysis
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12. Full Text Aqueous-phase asymmetric transfer hydrogenation of ketones - A greener approach to chiral alcohols
by Wu, Xiaofeng and Xiao, Jianliang
Chemical Communications, ISSN 1359-7345, 2007, Issue 24, pp. 2449 - 2466
Asymmetric transfer hydrogenation (ATH) has emerged as a practical, powerful alternative to asymmetric hydrogenation for the production of chiral alcohols, one... 
BETA-AMINO ALCOHOLS | BIPHASIC TRANSFER HYDROGENATION | TRANSITION-METAL-COMPLEXES | AROMATIC KETONES | TETHERED RUTHENIUM(II) CATALYST | SOLUBLE CARBONYL-COMPOUNDS | CATALYTIC TRANSFER-HYDROGENATION | ACID-TRIETHYLAMINE MIXTURE | CHEMISTRY, MULTIDISCIPLINARY | DEPENDENT TRANSFER HYDROGENATION | ENANTIOSELECTIVE TRANSFER HYDROGENATION | Alcohols - chemistry | Oxidation-Reduction | Stereoisomerism | Ketones - chemistry | Water - chemistry | Alcohols - chemical synthesis | Molecular Structure | Catalysis | Hydrogenation | Hydrogen-Ion Concentration
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13. Full Text Direct Organo‐Catalytic Asymmetric α‐Amination of Aldehydes—A Simple Approach to Optically Active α‐Amino Aldehydes, α‐Amino Alcohols, and α‐Amino Acids
by Bøgevig, Anders and Juhl, Karsten and Kumaragurubaran, Nagaswamy and Zhuang, Wei and Jørgensen, Karl Anker
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2002, Volume 41, Issue 10, pp. 1790 - 1793
L‐Proline as the catalyst: The first direct asymmetric α‐amination of aldehydes using L‐proline as the catalyst is presented (see scheme; Pg=protecting group).... 
aldehydes | asymmetric catalysis | amino alcohols | amino acids | amino aldehydes | Amino acids | Aldehydes | Amino aldehydes | Asymmetric catalysis | Amino alcohols | ENANTIOSELECTIVE SYNTHESIS | IMINES | ALKYLATION | ALDOL REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | STRATEGIES | ARYLGLYCINES | HYDROGEN-CYANIDE | ZIRCONIUM CATALYST | DERIVATIVES | STRECKER REACTION | Chemistry, Organic - methods | Alcohols - chemistry | Temperature | Models, Chemical | Nitrogen - chemistry | Esters - chemistry | Stereoisomerism | Catalysis | Carbon - chemistry | Aldehydes - chemistry | Proline - chemistry
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14. Full Text Identifying the Roles of Amino Acids, Alcohols and 1,2-Diamines as Mediators in Coupling of Haloarenes to Arenes
by Zhou, Shengze and Doni, Eswararao and Anderson, Greg M and Kane, Ryan G and MacDougall, Scott W and Ironmonger, Victoria M and Tuttle, Tell and Murphy, John A
Journal of the American Chemical Society, ISSN 0002-7863, 12/2014, Volume 136, Issue 51, pp. 17818 - 17826
Coupling of haloarenes to arenes has been facilitated by a diverse range of organic additives in the presence of KO t Bu or NaO t Bu since the first report in... 
SUPER-ELECTRON-DONORS | METAL-FREE SYNTHESIS | NUCLEOPHILIC TRIFLUOROMETHYLATION | ARYL BROMIDES | ORGANIC-SYNTHESIS | INTRAMOLECULAR ARYLATION | C-H-ARYLATION | POTASSIUM TERT-BUTOXIDE | UNACTIVATED ARENES | <