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chemistry, organic (9) 9
index medicus (4) 4
molecular structure (4) 4
alcohols (3) 3
article (3) 3
asymmetric-synthesis (3) 3
bioactive macrolides (3) 3
chemical synthesis (3) 3
chemistry, multidisciplinary (3) 3
dinoflagellate (3) 3
enantioselective total-synthesis (3) 3
macrolide (3) 3
macrolides - chemistry (3) 3
synthetic methods (3) 3
absolute stereochemistry (2) 2
amphidinium sp (2) 2
amphidinolide (2) 2
catalysis (2) 2
derivatives (2) 2
macrolides - chemical synthesis (2) 2
magnetic resonance spectroscopy (2) 2
organic chemistry (2) 2
ring-closing metathesis (2) 2
synthesis (2) 2
-gymnodimine (1) 1
1,4 additions (1) 1
14-membered diene unit (1) 1
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6-pi-2-azatriene electrocyclization (1) 1
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amphidinolide e stereoisomers (1) 1
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biochemistry & molecular biology (1) 1
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1. Full Text Synthesis of the C3−C18 Fragment of Amphidinolides G and H
by Petri, Andreas F and Schneekloth, John S and Mandal, Amit K and Crews, Craig M
Organic Letters, ISSN 1523-7060, 08/2007, Volume 9, Issue 16, pp. 3001 - 3004
A synthesis of an amphidinolides G and H C3−C18 subunits is reported. The C10−C18 segment 4 was prepared by a Negishi cross-coupling, whereas the synthesis of... 
SEGMENT | MOIETY | STEREOCHEMISTRY | DINOFLAGELLATE | CHEMISTRY, ORGANIC | CYTOTOXIC AGENTS AMPHIDINOLIDES | POLYKETIDES | ALDEHYDES | BIOACTIVE MACROLIDES | ALPHA-ALLENIC ACETATES | GENERAL-METHOD | Molecular Structure | Catalysis | Macrolides - chemistry | Macrolides - chemical synthesis
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2. Amphidinolide C3, a new cytotoxic 25-membered macrolide from marine dinoflagellate Amphidinium sp
by Kubota, Takaaki and Suzuki, Akiko and Yamada, Mika and Baba, Shigeyuki and Kobayashi, Jun'ichi
Heterocycles, ISSN 0385-5414, 2010, Volume 82, Issue 1, pp. 333 - 338
A new cytotoxic 25-membered macrolide, amphidinolide C3 (1), has been isolated from marine dinoflagellate Amphidinium sp. (Y-56 strain), and the structure of 1... 
CARTERAE | TRUNCATED POLYHYDROXYL CHAIN | LUTEOPHANOL | Dinoflagellate | COMPOUND | CHEMISTRY, ORGANIC | ABSOLUTE STEREOCHEMISTRY | Macrolide | Amphidinium species | Amphidinolide C3 | KLEBSII | BIOACTIVE MACROLIDES | ANTIFUNGAL | LINGSHUIOL | METABOLITE
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3. Full Text Synthesis of amphidinolide Y precursors
by Mola, Laura and Olivella, Anna and Urpí, Fèlix and Vilarrasa, Jaume
Tetrahedron Letters, ISSN 0040-4039, 01/2014, Volume 55, Issue 4, pp. 900 - 902
The Negishi coupling between a chiral C3 synthon and an iodoalkene arising from 3-butyn-1-ol, which gave the C3–C9 fragment of amphidinolide Y, was the... 
Amphidinolides | Macrocyclizations | Formal total synthesis | Ring-closing metathesis (RCM) | ALCOHOLS | ACID | RING-CLOSING METATHESIS | ESTERS | CHEMISTRY, ORGANIC | EFFICIENT | Synthesis (chemistry) | Marine | Precursors | Tetrahedrons | Joining | Derivatives | Conversion | Fragmentation
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4. Synthesis of C1-C6 fragment of caribenolide I
by Seck, Matar and Seon-Meniel, Blandine and Jullian, Jean-Christophe and Franck, Xavier and Reynald, Hocquemiller and Figadère, Bruno
Letters in Organic Chemistry, ISSN 1570-1786, 05/2006, Volume 3, Issue 5, pp. 390 - 395
Stereoselective synthesis of C1-C6 fragment of caribenolide 1, a potent antitumour macrolide isolated from a marine dinoflagellate Amphidinium sp. is... 
Oxazolidinones | Antitumor | Oxazolidin-2-thiones | Amphidinolide | Macrolide | Aldolisation | Cytotoxic activity | antitumor | oxazolidin-2-thiones | ASYMMETRIC ALDOL ADDITIONS | DINOFLAGELLATE | CHEMISTRY, ORGANIC | aldolisation | cytotoxic activity | AMPHIDINIUM SP | oxazolidinones | amphidinolide | macrolide
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5. Full Text Synthesis of the C18–C26 tetrahydrofuran-containing fragment of amphidinolide C congeners via tandem asymmetric dihydroxylation and SN2 cyclization
by Su, Ye-Xiang and Dai, Wei-Min
Tetrahedron, ISSN 0040-4020, 03/2018, Volume 74, Issue 13, pp. 1546 - 1554
The C18–C26 fragment of amphidinolide C congeners has been synthesized starting from methyl acetoacetate in 14 steps in >17.0% overall yield. The C20... 
Tetrahydrofuran | Asymmetric dihydroxylation | Amphidinolide C | Enyne | Intramolecular SN2 reaction | Sonogashira cross-coupling | Intramolecular S | 2 reaction
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6. Full Text Total Synthesis of the Biphenyl Alkaloid (−)‐Lythranidine
by Gebauer, Konrad and Fürstner, Alois
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 25, pp. 6393 - 6396
A sequence comprising a ring‐closing alkyne metathesis of a propargyl alcohol derivative, followed by a ruthenium‐catalyzed redox isomerization of the derived... 
ruthenium | 1,4 additions | metathesis | alkynes | molybdenum | CLOSING ALKYNE METATHESIS | LYTHRACEOUS ALKALOIDS | LYTHRAMINE | ASYMMETRIC-SYNTHESIS | LYTHRANINE | FORMAL TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | CATALYZED REDOX ISOMERIZATION | LYTHRUM-ANCEPS MAKINO | AMPHIDINOLIDE-V | Alkaloids - chemical synthesis | Molecular Structure | Catalysis | Oxidation-Reduction | Ruthenium - chemistry | Alkaloids - chemistry | Alkaloids | Synthesis | Molybdenum | Isomerization | Organic compounds | Acetylene | Catalysts | Decomposition reactions | Metathesis | Derivatives | Alkynes
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7. Full Text Synthesis of the C1–C12 acid fragment of amphidinolide T marine macrolides via SmI 2-mediated enantioselective reductive coupling of aldehydes with a chiral crotonate
by Luo, Jialu and Li, Huoming and Wu, Jinlong and Xing, Xinglong and Dai, Wei-Min
Tetrahedron, ISSN 0040-4020, 2009, Volume 65, Issue 34, pp. 6828 - 6833
A new strategy for enantioselective assembly of the trisubstituted tetrahydrofuran ring has been established for synthesis of the C1–C12 acid fragment of... 
γ-Butyrolactone | Samarium | Amphidinolide | Macrolide | Allylation
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8. Full Text The Leiodolide B Puzzle
by Larivée, Alexandre and Unger, John B and Thomas, Mikaël and Wirtz, Conny and Dubost, Christophe and Handa, Shinya and Fürstner, Alois
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2011, Volume 50, Issue 1, pp. 304 - 309
Out of options? Even though a systematic approach was chosen, which led to a set of four diastereomeric macrolides modeled around the proposed structure of... 
marine natural products | structure elucidation | total synthesis | NMR spectroscopy | Homogeneous catalysis | ACIDS | NATURAL-PRODUCTS | AQUEOUS HYDROGEN-PEROXIDE | CATALYZED ASYMMETRIC EPOXIDATION | MACROLIDES | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | CROSS-COUPLING REACTIONS | AMPHIDINOLIDE-X | STRUCTURE REVISION | Marine Biology | Biological Products - chemistry | Oxazoles - metabolism | Macrolides - chemistry | Magnetic Resonance Spectroscopy | Oxazoles - analysis | Biological Products - metabolism | Biological Products - analysis | Macrolides - analysis | Molecular Structure | Macrolides - metabolism | Oxazoles - chemistry
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9. Full Text Multi‐Gram Scale Synthesis of Chiral 3‐Methyl‐2,5‐trans‐tetrahydrofurans
by Qin, Shuanglin and Cao, Yuting and Luo, Yunhao and Jiang, Shende and Clark, J. Stephen and Wang, Xiaoji and Yang, Guang
Helvetica Chimica Acta, ISSN 0018-019X, 07/2019, Volume 102, Issue 7, p. n/a
In this article, we report the rapid and facile synthesis of chiral 3‐methyl‐2,5‐trans‐tetrahydrofurans. This reaction utilizes cheap and easily available... 
gram-scale syntheses | diastereoselectivity | 3-methyl-2,5-trans-tetrahydrofurans | synthetic methods | ring closure | FORMAL SYNTHESIS | AMPHIDINOLIDES C | (-)-GYMNODIMINE | CHEMISTRY, MULTIDISCIPLINARY | 5-trans-tetrahydrofurans | BIOACTIVE MACROLIDES | 3-methyl-2 | ENANTIOSELECTIVE TOTAL-SYNTHESIS | C1-C9 FRAGMENT | Hydrolysis | Chemical synthesis | Furans | Stereoselectivity | Organic chemistry
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10. Full Text The Liebeskind–Srogl Cross‐Coupling Reaction and its Synthetic Applications
by Cheng, Hong‐Gang and Chen, Han and Liu, Yue and Zhou, Qianghui
Asian Journal of Organic Chemistry, ISSN 2193-5807, 03/2018, Volume 7, Issue 3, pp. 490 - 508
The Pd‐catalyzed, CuI−carboxylate‐mediated cross‐coupling reaction of organosulfur compounds with nucleophilic organometallic reagents is known as the... 
cross-coupling | copper | palladium | synthetic methods | organosulfur reagents | ROOM-TEMPERATURE | HYDROGEN SUBSTITUTION-REACTIONS | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | THIOL ESTERS | LIGHT-HARVESTING ARRAYS | CARBON BOND FORMATION | BORONIC ACIDS | AMPHIDINOLIDE-C | TRANSITION-METAL | ASYMMETRIC AUTOCATALYSIS
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11. Full Text Marine natural products: Synthetic aspects
by Morris, Jonathan C and Phillips, Andrew J
Natural Product Reports, ISSN 0265-0568, 2009, Volume 26, Issue 2, pp. 245 - 265
An overview of marine natural products synthesis during 2007 is provided. As with earlier installments in this series, the emphasis is on total syntheses of... 
CHEMISTRY, MEDICINAL | ASYMMETRIC-SYNTHESIS | 14-MEMBERED DIENE UNIT | BIOCHEMISTRY & MOLECULAR BIOLOGY | METHYL SARCOPHYTOATE | CHEMISTRY, ORGANIC | ABSOLUTE-CONFIGURATION | 1ST TOTAL-SYNTHESIS | AMPHIDINOLIDE-Y | HISTONE DEACETYLASE INHIBITORS | 6-PI-2-AZATRIENE ELECTROCYCLIZATION | ENANTIOSELECTIVE TOTAL-SYNTHESIS | PALMEROLIDE-A
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12. Full Text Synthesis of key fragments of amphidinolide Q - A cytotoxic 12-membered macrolide
by Kawa, Kohei and Hara, Akihiro and Ishikawa, Yuichi and Nishiyama, Shigeru
Molecules, ISSN 1420-3049, 07/2011, Volume 16, Issue 7, pp. 5422 - 5436
beta-Hydroxy aldehyde and alkyl ketone moieties were effectively synthesized as key intermediates of amphidinolide Q, a cytotoxic macrolide from the cultured... 
Macrolide synthesis | Amphidinolide Q | Cytotoxic marine natural product | Amphidinium sp | CHEMISTRY, ORGANIC | amphidinolide Q | macrolide synthesis | cytotoxic marine natural product | Ascorbic Acid | Macrolides - chemistry | Magnetic Resonance Spectroscopy | Macrolides - chemical synthesis | Stereoisomerism | Molecular Structure | Dinoflagellida - chemistry
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13. Full Text Total synthesis of amphidinolide E and amphidinolide E stereoisomers
by Va, Porino and Roush, William R
Tetrahedron, ISSN 0040-4020, 2007, Volume 63, Issue 26, pp. 5768 - 5796
Four amphidinolide E stereoisomers, amphidinolide E ( ), 2- -amphidinolide E ( ), 19- -amphidinolide E ( ), and 2- -19- -amphidinolide E ( ), have been... 
[3+2] Annulation reaction | Esterification of Fe(CO) 3-complexed dienoic acid | Amphidinolide E stereoisomers | Esterification of Fe(CO) | complexed dienoic acid | TETRAHYDROFURAN SYNTHESIS | CHEMISTRY, ORGANIC | CHIRAL ALLYLSILANES | [3+2] annulation reaction | amphidinolide E stereoisomers | 3+2 ANNULATION | RING-CLOSING METATHESIS | DIASTEREOSELECTIVE SYNTHESIS | CHLOROSULFONYL ISOCYANATE | STEREOSELECTIVE-SYNTHESIS | esterification of Fe(CO)-complexed dienoic acid | ENANTIOSELECTIVE TOTAL-SYNTHESIS | CATALYTIC ASYMMETRIC-SYNTHESIS | MARINE POLYHYDROXYLATED STEROIDS | Chemical synthesis | Carbonyl compounds | Chemical reactions | esterification of Fe(CO)3-complexed dienoic acid
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14. Full Text Recent Applications of Acyclic (Diene)iron Complexes and (Dienyl)iron Cations in Organic Synthesis
by Donaldson, William A and Chaudhury, Subhabrata
08/2009, Volume 2009, Issue 23, 13
Complexation of (tricarbonyl)iron to an acyclic diene serves to protect the ligand against oxidation, reduction, and cycloaddition reactions, whereas the... 
Iron | Synthetic methods | Regioselectivity | Diene ligands | Nucleophilic addition | MACROLACTIN-A | ORGANOIRON METHODOLOGY | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | TRICARBONYLIRON COMPLEXES | CHEMISTRY, ORGANIC | ABSOLUTE STEREOCHEMISTRY | AMPHIDINOLIDE-E | FREE-RADICAL CYCLIZATIONS | (3-METHYLPENTADIENYL)IRON(1+) CATIONS | HIGHLY STEREOSELECTIVE-SYNTHESIS | Regioselective nucleophilic addition
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