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Synlett, ISSN 0936-5214, 10/2018, Volume 29, Issue 16, pp. 2147 - 2154
Abstract Triarylmethylium- o,o -dimers adopt a twisted geometry so that two diarylmethyliums are stacked in a slipped manner. Thus, chiral auxiliaries on the... 
cluster | axial chirality | dye | chiral induction | redox system | dication | electrochromism | exciton coupling | flow microreactor | SYSTEM | DYNAMIC REDOX PROPERTIES | BEHAVIOR | CHEMISTRY, ORGANIC | ELECTRON-DONORS | CATIONS | HELICITY | SWITCH | STRONG CHIROPTICAL SIGNALS | DERIVATIVES | BOND MAKING/BREAKING
Journal Article
ChemMedChem, ISSN 1860-7179, 03/2011, Volume 6, Issue 3, pp. 505 - 513
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2017, Volume 23, Issue 49, pp. 11955 - 11960
The idea of anion‐π catalysis is to stabilize anionic transition states by anion‐π interactions on aromatic surfaces. For asymmetric anion‐π catalysis,... 
axial chirality | atropisomers | catalysis | anion-π interactions | enolate chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 48, pp. 15862 - 15865
Consecutive thermal and metal‐catalyzed dehydro‐Diels–Alder (DDA) reactions of sulfur‐tethered tetraynes, possessing a 1,3‐diyne moiety, proceeded efficiently,... 
axial chirality | enantioselectivity | cycloaddition | heterocycles | rhodium | ASYMMETRIC-SYNTHESIS | NATURAL-PRODUCTS | CARBAZOLES | 2+2+2 CYCLOADDITION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | YNAMIDES | CYCLOISOMERIZATION | DERIVATIVES | DIARYLACETYLENES | DIYNES | Enantiomers | Diels-Alder reaction | Rhodium | Chirality | Chemical reactions | Catalysis | Sulfur | Chemical synthesis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2016, Volume 138, Issue 16, pp. 5202 - 5205
Herein we disclose a scalable organocatalytic direct arylation approach for the regio- and atroposelective synthesis of non-C 2-symmetric... 
ACID | ENANTIOSELECTIVE SYNTHESIS | AXIAL CHIRALITY | KINETIC RESOLUTION | NATURAL-PRODUCTS | BIARYL SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | Arylation | Chemical compounds | Analysis
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 5/2013, Volume 42, Issue 12, pp. 548 - 5424
Circular dichroism (CD) spectroscopy is one of the most useful techniques for the stereochemical analysis of chiral biopolymers and fine chemicals. It has... 
SECONDARY ALCOHOLS | ENANTIOMERIC EXCESS | HELICAL CHIRALITY | INDUCED AXIAL CHIRALITY | ABSOLUTE CONFIGURATIONAL ASSIGNMENTS | ALPHA-AMINO-ACID | STEREOCHEMICAL DETERMINATION | ZINC PORPHYRIN HOST | CHEMISTRY, MULTIDISCIPLINARY | BIPHENYL CORE | CARBOXYLIC-ACIDS | Binding | Cadmium | Fine chemicals | Circularity | Dichroism | Electronics | Sensors | Information dissemination
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2018, Volume 83, Issue 3, pp. 1106 - 1115
A highly stereoselective asymmetric intermolecular conjugate addition of α-amino ester derivatives to cyclic enones via the memory of chirality (MOC) concept... 
IMINO-ALDOL REACTION | ACID-DERIVATIVES | CONTIGUOUS QUATERNARY | AXIAL CHIRALITY | ENANTIOSELECTIVE CONJUGATE ADDITION | COMPLEXES | TERTIARY STEREOCENTERS | CHEMISTRY, ORGANIC | ALDEHYDES | 1,4-ADDITION | GRIGNARD-REAGENTS | Usage | Chirality | Analysis | Chemical reactions | Amino acids | Esters | Chemical properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 6, pp. 2140 - 2143
For the first time, enantiomerically enriched atropoisomeric furans have been accessed using a central-to-axial chirality conversion strategy. Hence, oxidation... 
CATALYSIS | ASYMMETRIC-SYNTHESIS | HYDROGENATION | LIGANDS | ATROPOSELECTIVE SYNTHESIS | BIARYL COMPOUNDS | CONSTRUCTION | ALDOL CONDENSATION SYNTHESIS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | DYNAMIC KINETIC RESOLUTION | Oxidation-reduction reaction | Usage | Furans | Chemical properties | Chirality | Analysis | Organic chemistry | Chemical Sciences
Journal Article
Chirality, ISSN 0899-0042, 11/2017, Volume 29, Issue 11, pp. 663 - 669
Journal Article
Free Radical Research: EU COST Action Special Supplementary - Biomimetic Radical Chemistry, ISSN 1071-5762, 11/2016, Volume 50, Issue sup1, pp. S102 - S111
The effects of memory of chirality (MoC) in reactions involving monoradical species are reviewed here. Reactions involving a nonracemic chiral starting... 
atropisomers | Free radicals | asymmetric synthesis | chirality | stereochemistry | conformation | racemization | RETENTION | BIOCHEMISTRY & MOLECULAR BIOLOGY | CONFIGURATION | DECOMPOSITION | REARRANGEMENT | REDUCTIONS | AXIAL CHIRALITY | CYCLOPROPYL HALIDES | RADICAL CYCLIZATIONS | LITHIUM METAL | PYRAZOLINES | Molecular Structure | Chimerism | Free Radicals | Stereoisomerism
Journal Article
International Journal of Non-Linear Mechanics, ISSN 0020-7462, 08/2019, Volume 114, pp. 9 - 20
When an elastic tube reinforced with helical fibres is inflated, its ends rotate. In large deformations, the amount and chirality of rotation is highly... 
Probability | Stochastic hyperelastic models | Chirality | Aeolotropy | Axial stress | Deformation | Statistical analysis | Parameters | Independent variables | Probability density functions | Elastic anisotropy | Flux density | Mathematical analysis | Tubes | Random variables | Torsion | Internal pressure
Journal Article