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Nature, ISSN 0028-0836, 12/2010, Volume 468, Issue 7327, pp. 1067 - 1073
Journal Article
Synthesis, ISSN 0039-7881, 12/2019, Volume 51, Issue 24, pp. 4582 - 4589
Abstract A simple gram-scale method for the preparation of esters and dialkylamides of 2-(fluoro/iodo)-2 H -azirine-2-carboxylic acids via the halogen exchange... 
paper | nucleophilic- substitution | 2H-AZIRINES | halogen exchange reaction | ISOMERIZATION | CHEMISTRY, ORGANIC | FLUORINATION | 2-HALO-2H-AZIRINES | ISOXAZOLES | HALOGEN EXCHANGE | I-124 | CHEMISTRY | iodine | azirines | fluorine
Journal Article
Synthesis (Germany), ISSN 0039-7881, 2017, Volume 49, Issue 19, pp. 4478 - 4488
A convenient gram-scale method for the preparation of 2-halo-2H-azirine-2-carboxylic acid esters, thioesters and amides via metal-catalyzed isomerization of... 
haloheterocycles | rhodium(II) carboxylates | iron(II) chloride | isomerization | catalysis | azirines | isoxazoles | RING EXPANSION | 2H-AZIRINES | REACTIVITY | CHEMISTRY, ORGANIC | PYRROLES | PYRIDINES | 2-HALO-2H-AZIRINES | 4-HALO-2-AZABUTA-1,3-DIENES | FACILE SYNTHESIS | SPONGE DYSIDEA-FRAGILIS | CHEMISTRY
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 11/2018, Volume 83, Issue 21, pp. 13473 - 13480
An effective and operationally simple method for the preparation of methyl 2-(di/tri/tetraazol-1-yl)-2H-azirine-2-carboxylates from accessible methyl... 
2-HALO-2H-AZIRINES | 2H-AZIRINES | ESTERS | ISOMERIZATION | REACTIVITY | CHEMISTRY, ORGANIC | INDOLES | ACCESS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2015, Volume 21, Issue 9, pp. 3562 - 3566
RhII‐catalyzed intermolecular [3+2] cycloaddition of 2 H‐azirines with N‐sulfonyl‐1,2,3‐triazoles is disclosed, in which a series of fully functionalized... 
triazoles | pyrroles | 2 H‐azirines | azavinyl carbenes | rhodium | Azavinyl carbenes | Rhodium | Triazoles | 2 H-azirines | Pyrroles
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 16, pp. 4093 - 4099
The chemoselective cyclization of isocyanates with 2H-azirine was achieved with AuBr as catalyst. This transfer sets the stage for the synthesis of aromatic... 
oxazoles | gold catalysis | 2H-azirines | heterocycles | isocyanates
Journal Article
by Shu, C and Wang, YH and Zhou, B and Li, XL and Ping, YF and Lu, X and Ye, LW
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 08/2015, Volume 137, Issue 30, pp. 9567 - 9570
The generation of a-imino gold carbenes via gold-catalyzed intermolecular reaction of azides and ynamides is disclosed. This new methodology allows for highly... 
AMINATION | CASCADE REACTIONS | 2H-AZIRINES | CONSTRUCTION | AMIDATION | OXAZOLES | TRANSANNULATION | SELECTIVE SYNTHESIS | AMINOCYCLOPROPANES | PYRIDINES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2015, Volume 71, Issue 13, pp. 1940 - 1951
The transition metal-catalyzed reaction of 2H-azirines with 1,2,4-tricarbonyl compounds leads to 3-(1,2-dioxoethyl)- and 2,3-dicarbonyl-pyrrole derivatives,... 
Metal catalysis | Cyclocondensation | Pyrrole | Azirine | DOMINO REACTION | AZIRINES | 2H-AZIRINES | ACID | VINYL AZIDES | ISOMERIZATION | CHEMISTRY, ORGANIC | STRUCTURAL-CHARACTERIZATION | 2-PHENYLAZIRINE | ESTERS | BIOLOGICAL EVALUATION | Transition metal compounds
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 11/2013, Volume 54, Issue 46, pp. 6157 - 6160
We report an application of FeCl2 as an inexpensive, nontoxic, and efficient catalyst in a clean ring expansion reaction of 2H-azirine derivatives, an... 
FeCl2-catalyzed ring expansion | One-pot synthesis | Isoxazoles | 2H-Azirine | Enaminones | FeCl | catalyzed ring expansion 2H-Azirine | 2-PHENYL-3-VINYL SUBSTITUTED 2H-AZIRINES | PHOTOCHEMICAL TRANSPOSITION | AZIRINES | OXAZOLES | CHEMISTRY, ORGANIC | ATOMS | Tetrahedrons | Synthesis (chemistry) | Cleaning | Derivatives | Catalysts
Journal Article
Tetrahedron, ISSN 0040-4020, 05/2018, Volume 74, Issue 20, pp. 2466 - 2474
New heterocyclic betaines, 4-aryl-5-(alkoxycarbonyl)-2-oxo-3-(pyridin-1-ium-1-yl)-2,3-dihydro-1H-pyrrol-3-ides, were synthesized in good yields by the reaction... 
Solvatochromism | Heterocyclic betaines | Pyridinium ylides | Azirines
Journal Article
Tetrahedron, ISSN 0040-4020, 07/2015, Volume 71, Issue 28, pp. 4616 - 4628
A wide range of electron-poor 4-bromo-/4-chloro-2-azabuta-1,3-dienes were synthesized by the Rh2(OAc)4-catalyzed reaction of diazo esters and diazo ketones... 
2,3-Dihydroazetes | 2-Azabutadienes | Diazo compounds | Heterocyclizations | Azirines | 2,5-Dihydrooxazoles | REAGENT | 2-AZA-1,3-DIENES | 2H-AZIRINES | CHEMISTRY, ORGANIC | CONVENIENT ROUTE | DBU | ESTERS | H INSERTION | EFFICIENT
Journal Article
Organic Letters, ISSN 1523-7060, 02/2015, Volume 17, Issue 3, pp. 395 - 397
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2012, Volume 48, Issue 33, pp. 3996 - 3998
Free carbenes generated from alpha-diazo oxime ethers by photolysis undergo facile N-O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent... 
2-HALO-2H-AZIRINES | CYCLOADDITION | MULTICOMPONENT | RING EXPANSION | 2H-AZIRINES | CARBENOIDS | HIGHLY SUBSTITUTED PYRROLES | CHEMISTRY | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ALKALOIDS
Journal Article
Organic Letters, ISSN 1523-7060, 07/2014, Volume 16, Issue 13, pp. 3432 - 3435
A new strategy to open the 2-allyl-2H-azirines by 1,8-diazabicyclo[5.4.0]­undec-7-ene (DBU) promotion in metal-free conditions affording 1-azatrienes that in... 
HIGHLY FUNCTIONALIZED PYRIDINES | ROUTE | DIELS-ALDER | 2H-AZIRINES | DE-NOVO SYNTHESIS | CONSTRUCTION | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | 2+2+2 CYCLOADDITION | ALKYNES | DERIVATIVES | Azirines - chemistry | Molecular Structure | Catalysis | Pyridines - chemistry | Pyridines - chemical synthesis
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 07/2013, Volume 78, Issue 14, pp. 6983 - 6991
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 05/2018, Volume 16, Issue 17, pp. 3248 - 3257
Various 2-oxygen-substituted 2H-azirine-2-carboxylic acid derivatives were synthesized in high yields under mild conditions from readily available precursors,... 
NUCLEOPHILES | CYCLOADDITION | AZIRINES | HALOGENATED IMINO COMPOUNDS | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | 3-DIAZOINDOLIN-2-IMINES | FUNCTIONALIZED 2H-AZIRINES | CYCLIZATION | CARBOXYLIC-ACIDS
Journal Article
Organic Letters, ISSN 1523-7060, 11/2008, Volume 10, Issue 22, pp. 5269 - 5271
A short, flexible synthesis of the marine natural product (2R)-(Z)-dysidazirine (−)-1 has been completed. (−)-1 shows significant antifungal activity across a... 
SPONGE DYSIDEA-FRAGILIS | CHEMISTRY, ORGANIC | AZACYCLOPROPENE | ASYMMETRIC-SYNTHESIS | 2H-AZIRINES | ESTERS | Antifungal Agents - pharmacology | Azirines - chemistry | Fungi - drug effects | Azirines - chemical synthesis | Stereoisomerism | Antifungal Agents - chemical synthesis | Antifungal Agents - chemistry | Azirines - pharmacology
Journal Article
Synthesis, ISSN 0039-7881, 07/2018, Volume 50, Issue 14, pp. 2784 - 2798
Abstract The iron(II)-catalyzed domino isomerization of 3-alkyl/aryl-4-arylisoxazoles provides a selective access to a wide range of structurally diverse... 
paper | indoles | iron(II) chloride catalysis | isoxazoles | domino reactions | isomerization | TRANSFORMATION | 2H-AZIRINES | ROUTES | CHEMISTRY, ORGANIC | 2-ARYL-2H-AZIRINES | REARRANGEMENT | RELAY CATALYSIS | CHEMISTRY | 2,3-DISUBSTITUTED INDOLES | DERIVATIVES
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2017, Volume 73, Issue 31, pp. 4663 - 4670
A copper(I)-NHC-catalyzed annulation of 5-membered cyclic enols of furan, thiophene and indene family with 3-aryl-2H-azirines has been developed to provide a... 
Synthetic methods | Azirines | Copper catalysis | Enols | DOMINO REACTION | 2H-AZIRINES | ACIDS | ANALOGS | CHEMISTRY, ORGANIC | INDOLES | RING | CHEMISTRY | STEREOSELECTIVE-SYNTHESIS | DERIVATIVES | Thiophene | Copper | Resveratrol | Chemical properties | Catalysis
Journal Article
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